Geochemical response of magmas to Neogene–Quaternary continental collision in the Carpathian–Pannonian region: A review

The Carpathian–Pannonian Region contains Neogene to Quaternary magmatic rocks of highly diverse composition (calc-alkaline, shoshonitic and mafic alkalic) that were generated in response to complex microplate tectonics including subduction followed by roll-back, collision, subducted slab break-off, rotations and extension. Major element, trace element and isotopic geochemical data of representative parental lavas and mantle xenoliths suggests that subduction components were preserved in the mantle following the cessation of subduction, and were reactivated by asthenosphere uprise via subduction roll-back, slab detachment, slab-break-off or slab-tearing. Changes in the composition of the mantle through time are evident in the geochemistry, supporting established geodynamic models.Magmatism occurred in a back-arc setting in the Western Carpathians and Pannonian Basin (Western Segment), producing felsic volcaniclastic rocks between 21 to 18 Ma ago, followed by younger felsic and intermediate calc-alkaline lavas (18–8 Ma) and finished with alkalic-mafic basaltic volcanism (10–0.1 Ma). Volcanic rocks become younger in this segment towards the north. Geochemical data for the felsic and calc-alkaline rocks suggest a decrease in the subduction component through time and a change in source from a crustal one, through a mixed crustal/mantle source to a mantle source. Block rotation, subducted roll-back and continental collision triggered partial melting by either delamination and/or asthenosphere upwelling that also generated the younger alkalic-mafic magmatism.In the westernmost East Carpathians (Central Segment) calc-alkaline volcanism was simultaneously spread across ca. 100 km in several lineaments, parallel or perpendicular to the plane of continental collision, from 15 to 9 Ma. Geochemical studies indicate a heterogeneous mantle toward the back-arc with a larger degree of fluid-induced metasomatism, source enrichment and assimilation on moving north-eastward toward the presumed trench. Subduction-related roll-back may have triggered melting, although there may have been a role for back-arc extension and asthenosphere uprise related to slab break-off.Calc-alkaline and adakite-like magmas were erupted in the Apuseni Mountains volcanic area (Interior Segment) from15–9 Ma, without any apparent relationship with the coeval roll-back processes in the front of the orogen. Magmatic activity ended with OIB-like alkali basaltic (2.5 Ma) and shoshonitic magmatism (1.6 Ma). Lithosphere breakup may have been an important process during extreme block rotations (60°) between 14 and 12 Ma, leading to decompressional melting of the lithospheric and asthenospheric sources. Eruption of alkali basalts suggests decompressional melting of an OIB-source asthenosphere. Mixing of asthenospheric melts with melts from the metasomatized lithosphere along an east–west reactivated fault-system could be responsible for the generation of shoshonitic magmas during transtension and attenuation of the lithosphere.Voluminous calc-alkaline magmatism occurred in the Cãlimani-Gurghiu-Harghita volcanic area (South-eastern Segment) between 10 and 3.5 Ma. Activity continued south-eastwards into the South Harghita area, in which activity started (ca. 3.0–0.03 Ma, with contemporaneous eruption of calc-alkaline (some with adakite-like characteristics), shoshonitic and alkali basaltic magmas from 2 to 0.3 Ma. Along arc magma generation was related to progressive break-off of the subducted slab and asthenosphere uprise. For South Harghita, decompressional melting of an OIB-like asthenospheric mantle (producing alkali basalt magmas) coupled with fluid-dominated melting close to the subducted slab (generating adakite-like magmas) and mixing between slab-derived melts and asthenospheric melts (generating shoshonites) is suggested. Break-off and tearing of the subducted slab at shallow levels required explaining this situation.     

U–Pb geochronological constraints on the Triassic–Jurassic Ayú Complex,southern Mexico: Derivation from the western margin of Pangea-A

We present LA-ICP-MS (laser ablation inductively coupled plasma mass spectrometry) U–Pb detrital and igneous zircon data of poly-deformed metamorphic and igneous rocks of the Ayú area, southern Mexico. These rocks were previously inferred to be part of the Late Paleozoic Acatlán Complex, but new age data indicate that they formed in the Mesozoic and should be placed in the newly designated Ayú Complex. The Ayú Complex comprises polydeformed metasedimentary rocks (Chazumba Lithodeme) of a turbidite-like protolith that are intercalated with boudinaged ortho-amphibolites with transitional arc- to MORB tholeiitic geochemistry. In the south, the metasedimentary sequence is affected by a ca. 171 Ma partial melting which formed the Magdalena Migmatite. Migmatization was accompanied by 171–168 Ma intrusions of granodioritic, dioritic, and granitic dikes and sheets as well as pegmatite bodies, which are characterized by inherited zircon populations of ca. 260–290, 320–360, 420–480, 880–990, and 1080–1250 Ma that are also found in the Chazumba Lithodeme. U–Pb (detrital zircon) dating of seven metasedimentary samples from the migmatized and unmigmatized Chazumba Lithodeme yielded youngest detrital zircons and clusters of 192, 198, 214, 250, 266, and 291 Ma, and are interpreted to reflect the Late Triassic–Middle Jurassic deposition of turbiditic rocks. The transitional arc–tholeiitic geochemistry of the Chazumba amphibolites is consistent with turbidite sedimentation in a back-arc environment along a rifted passive margin, close to a contemporaneous magmatic arc. Inferred flattening of the subduction zone led to subduction erosion during the Early–Middle Jurassic and underthrusting of the Chazumba Lithodeme to depths equivalent to amphibolite facies metamorphism. Steepening of the subducting slab and diachronous rifting within the Gulf of Mexico contributed to extensional tectonics recorded on the Mexican mainland and facilitated the tectonic exhumation of the Chazumba Lithodeme by normal faulting along the reactivated Providencia shear zone during the Middle–Late Jurassic. More generally, the documentation of arc-back arc assemblages in the Ayú Complex requires deposition adjacent to a subducting ocean, and thus supports a Pangea-A reconstruction that was synchronous with the breakup of Pangea.     

Geochemical and isotopic variability in lavas from the eastern Trans-Mexican Volcanic Belt: Slab detachment in a subduction zone with varying dip

Strong compositional variations are observed in the late-Miocene to Quaternary volcanic rocks of the eastern Trans-Mexican Volcanic Belt. Geochemical and isotopic analyses of samples well constrained in age indicate an abrupt change in magma composition in the late-Miocene (∼ 7.5 Ma), when calc-alkaline, subduction-related magmatism was replaced by mafic, alkaline, OIB-like volcanism. Afterwards, volcanism migrated toward the trench and the erupted lavas showed increasing contributions of subduction components reflected in higher Th/Nb, La/Sm(n), Ba/Nb, and Ba/Th ratios. Lavas from volcanic fields located closer to the trench show clearer, although strongly variable, arc signatures as well as evidence of subducted sediment contributions. Farther from the trench, only lavas emplaced in late-Pliocene time appear to be slightly modified by subduction components, whereas the youngest Quaternary lavas can be regarded as intraplate lavas modified by crustal assimilation.The sudden change in magma composition in the late-Miocene is related to detachment of the subducting slab, which allowed the infiltration of enriched asthenospheric mantle into the mantle wedge. After detachment, the subducting plate started to increase its dip because of the loss of slab pull. This caused (1) the migration of the arc toward the trench, (2) convection of enriched asthenosphere into the mantle wedge, and (3) an increasing contribution of slab components to the melts, in a process that resulted in a highly heterogeneous source mantle. The variable contribution of subduction-related components to the magmas is controlled by the heterogeneous character of the source, the depth of the subducting plate, and the previous magmatic history of the areas.     

Late Mesozoic magmatism in the Jiaodong Peninsula,East China:Implications for crust-mantle interactions and lithospheric thinning of the eastern North China Craton

A section from the Linglong gold deposit on the northwestern Jiaodong Peninsula,East China,containing Late Mesozoic magmatic rocks from mafic and intermediate dikes and felsic intrusions,was chosen to investigate the lithospheric evolution of the eastern North China Craton(NCC).Zircon U-Pb data showed that low-Mg adakitic monzogranites and granodiorite intrusions were emplaced during the Late Jurassic(～145 Ma) and late Early Cretaceous(112-107 Ma),respectively;high-Mg adakitic diorite and mafic dikes were also emplaced during the Early Cretaceous at～139 Ma and ～118 Ma,and 125-145 Ma and 115-120 Ma,respectively.The geochemical data,including whole-rock major and trace element compositions and Sr-Nd-Pb isotopes,imply that the mafic dikes originated from the partial melting of a lithospheric mantle metasomatised through hydrous fluids from a subducted oceanic slab.Low-Mg adakitic monzogranites and granodiorite intrusions originated from the partial melting of the thickened lower crust of the NCC,while high-Mg adakitic diorite dikes originated from the mixing of mafic and felsic melts.Late Mesozoic magmatism showed that lithosphere-derived melts showed a similar source depth and that crust-derived felsic melts originated from the continuously thickened lower crust of the Jiaodong Peninsula from the Late Jurassic to Early Cretaceous.We infer that the lower crust of the eastern NCC was thickened through compression and subduction of the Palaeo-Pacific plate beneath the NCC during the Middle Jurassic.Slab rollback of the plate from ～160 Ma resulted in lithospheric thinning and accompanied Late Mesozoic magmatism.     

Source and tectonic implications of tonalite-trondhjemite magmatism in the Klamath Mountains

 In the Klamath Mountains, voluminous tonalite-trondhjemite magmatism was characteristic of a short period of time from about 144 to 136 Ma (Early Cretaceous). It occurred about 5 to 10 m.y. after the ∼165 to 159 Ma Josephine ophiolite was thrust beneath older parts of the province during the Nevadan orogeny (thrusting from ∼155 to 148 Ma). The magmatism also corresponds to a period of slow or no subduction. Most of the plutons crop out in the south-central Klamath Mountains in California, but one occurs in Oregon at the northern end of the province. Compositionally extended members of the suite consist of precursor gabbroic to dioritic rocks followed by later, more voluminous tonalitic and trondhjemitic intrusions. Most plutons consist almost entirely of tonalite and trondhjemite. Poorly-defined concentric zoning is common. Tonalitic rocks are typically of the low-Al type but trondhjemites are generally of the high-Al type, even those that occur in the same pluton as low-Al tonalite. The suite is characterized by low abundances of K₂O, Rb, Zr, and heavy rare earth elements. Sr contents are generally moderate (∼450 ppm) by comparison with Sr-rich arc lavas interpreted to be slab melts (up to 2000 ppm). Initial ⁸⁷Sr/⁸⁶Sr, δ ¹⁸O, and ɛ _Nd are typical of mantle-derived magmas or of crustally-derived magmas with a metabasic source. Compositional variation within plutons can be modeled by variable degrees of partial melting of a heterogeneous metabasaltic source (transitional mid-ocean ridge to island arc basalt), but not by fractional crystallyzation of a basaltic parent. Melting models require a residual assemblage of clinopyroxene+garnet±plagioclase±amphibole; residual plagioclase suggests a deep crustal origin rather than melting of a subducted slab. Such models are consistent with the metabasic part of the Josephine ophiolite as the source. Because the Josephine ophiolite was at low T during Nevadan thrusting, an external heat source was probably necessary to achieve significant degrees of melting; heat was probably extracted from mantle-derived basaltic melts, which were parental to the mafic precursors of the tonalite-trondhjemite suite. Thus, under appropriate tectonic and thermal conditions, heterogeneous mafic crustal rocks can melt to form both low- and high-Al tonalitic and trondhjemitic magmas; slab melting is not necessary. Received: 1 September 1994 / Accepted: 28 August 1995     

Geochronology and geochemistry of early Paleozoic granitic and coeval mafic rocks from the Tannuola terrane (Tuva,Russia): Implications for transition from a subduction to post-collisional setting in the northern part of the Central Asian Orogenic Belt

Early Paleozoic magmatism of the Tannuola terrane located in the northern Central Asian Orogenic Belt is important to understanding the transition from subduction to post-collision settings. In this study, we report in situ zircon U-Pb ages, whole rock geochemistry, and Sr-Nd isotopic data from the mafic and granitic rocks of the eastern Tannuola terrane to better characterize their petrogenesis and to investigate changing of the tectonic setting and geodynamic evolution. Zircon U-Pb ages reveal three magmatic episodes for about 60 Ma from ∼510 to ∼450 Ma, that can be divided into the late Cambrian (∼510–490 Ma), the Early Ordovician (∼480–470 Ma) and the Middle-Late Ordovician (∼460–450 Ma) stages. The late Cambrian episode emplaced the mafic, intermediate and granitic rocks with volcanic arc affinity. The late Cambrian mafic rocks of the Tannuola terrane may originate from melting of mantle source that contain asthenosphere and subarc enriched mantle metasomatized by melts derived from sinking oceanic slab. Geochemical and isotopic compositions indicate the late Cambrian intermediate-granitic rocks are most consistent with an origin from a mixed source including fractionation of mantle-derived magmas and crustal-derived components. The Early Ordovician episode reveal bimodal intrusions containing mafic rocks and adakite-like granitic rocks implying the transition from a thinner to a thicker lower crust. The Early Ordovician mafic rocks are formed as a result of high degree melting of mantle source including dominantly depleted mantle and subordinate mantle metasomatized by fluid components while coeval granitic rocks were derived from partial melting of the high Sr/Y mafic rocks. The latest Middle-Late Ordovician magmatic episode emplaced high-K calc-alkaline ferroan granitic rocks that were formed through the partial melting the juvenile Neoproterozoic sources.These three episodes of magmatism identified in the eastern Tannuola terrane are interpreted as reflecting the transition from subduction to post-collision settings during the early Paleozoic. The emplacement of voluminous magmatic rocks was induced by several stages of asthenospheric upwelling in various geodynamic settings. The late Cambrian episode of magmatism was triggered by the slab break-off while subsequent Early Ordovician episode followed the switch to a collisional setting with thickening of the lower crust and the intrusion of mantle-induced bimodal magmatism. During the post-collisional stage, the large-scale lithospheric delamination provides the magma generation for the Middle-Late Ordovician granitic rocks.     

An integrated zircon geochronological and geochemical investigation into the Miocene plutonic evolution of the Cyclades, Aegean Sea, Greece: part 2—geochemistry

Zircons from 14 compositionally variable granitic rocks were examined in detail using CL image-guided micro-analysis to unravel the complex magmatic history above the southward retreating Hellenic subduction zone system in the Aegean Sea. Previously published U–Pb ages document an episodic crystallisation history from 17 to 11?Ma, with peraluminous (S-type) granitic rocks systematically older than closely associated metaluminous (I-type) granitic rocks. Zircon O- and Hf isotopic data, combined with trace element compositions, are highly variable within and between individual samples, indicative of open-system behaviour involving mantle-derived melts and evolved supracrustal sources. Pronounced compositional and thermal fluctuations highlight the role of magma mixing and mingling, in accord with field observations, and incremental emplacement of distinct melt batches coupled with variable degrees of crustal assimilation. In the course of partial fusion, more fertile supracrustal sources dominated in the earlier stages of Aegean Miocene magmatism, consistent with systematically older crystallisation ages of peraluminous granitic rocks. Differences between zircon saturation and crystallisation temperatures (deduced from zircon Ti concentrations), along with multimodal crystallisation age spectra for individual plutons, highlight the complex and highly variable physico-compositional and thermal evolution of silicic magma systems. The transfer of heat and juvenile melts from the mantle varied probably in response to episodic rollback of the subducting lithospheric slab, as suggested by punctuated crystallisation age spectra within and among individual granitic plutons.     

冈底斯东段加查县丝波绒曲早侏罗- 始新世复式岩体成因及其对构造演化的启示

本文选取冈底斯带东段加查县东北部丝波绒曲复式岩体为对象,对其进行了岩相学、地质年代学、岩石地球化学以及Sr-Nd-Hf同位素组成的综合研究,据此探讨了该复式岩体的成因及其对构造演化的启示。研究结果表明,该复式岩体由早侏罗世辉长岩-花岗岩杂岩(188～185Ma)和始新世花岗质岩石(～47Ma)构成,两期花岗质岩石中普遍发育塑变形态的镁铁质包体。早侏罗世杂岩由角闪辉长岩和英云闪长岩组成,角闪辉长岩中的主要铁镁矿物为角闪石,它们为一套钙碱性弧岩浆岩组合,具有亏损的Sr-Nd-Hf同位素组成。始新世花岗质岩石主要为二长花岗岩-花岗闪长岩,它们较早侏罗世英云闪长岩更为富碱,属钙碱性-高钾钙碱性I型花岗岩,其同位素组成也较早侏罗世英云闪长岩富集。综合分析表明,该区早侏罗世复合辉长岩-花岗岩的形成受控于新特提斯洋板片北向俯冲的构造背景,角闪辉长岩起源于受俯冲板片脱水交代的上覆地幔楔的部分熔融,共生的英云闪长岩则为同期幔源岩浆底侵诱发初生地壳部分熔融产生的长英质岩浆与幔源岩浆不同程度混合的产物。始新世花岗岩的形成受控于新特提斯洋板片断离的构造背景,是由具"弧"型地球化学特征的初生地壳再造的产物,并有少量印度陆壳富集组分参与成岩。     

Origin and interaction of mafic and felsic magmas in an evolving late orogenic setting: the Early Paleozoic Terra Nova Intrusive Complex, Antarctica

The Abbott Unit (∼508 Ma) and the Vegetation Unit (∼475 Ma) of the Terra Nova Intrusive Complex (northern Victoria Land, Antarctica) represent the latest magmatic events related to the Early Paleozoic Ross Orogeny. They show different emplacement styles and depths, ranging from forcible at 0.4–0.5 GPa for the Abbott Unit to passive at ∼0.2 GPa for the Vegetation Unit. Both units consist of mafic, felsic and intermediate facies which collectively define continuous chemical trends. The most mafic rocks from both units show different enrichment in trace element and Sr-Nd isotopic signatures. Once the possible effects of upper crustal assimilation-fractional crystallisation (AFC) and lower crustal coupled AFC and magma refilling processes have been taken into account the following features are recognised: (1) the modelled primary Abbott Unit magma shows a slightly enriched incompatible element distribution, similar to common continental arc basalts and (2) the modelled primary Vegetation Unit magma displays highly enriched isotope ratios and incompatible element patterns. We interpreted these major changes in magmatic affinity and emplacement style as linked to a major change in the tectonic setting affecting melt generation, rise and emplacement of the magmas. The Abbott Unit mafic melts were derived from a mantle wedge above a subduction zone, with subcontinental lithospheric mantle marginally involved in the melting column. The Vegetation Unit mafic melts are regarded as products of a different source involving an old layer of subcontinental lithospheric mantle. The crustal evolution of both types of mafic melts is marked by significant compositional contrasts in Sr and Nd isotopes between mafic and associated felsic rocks. The crustal isotope signature showed an increase with felsic character. Geochemical variations for both units can be accounted for by a similar two-stage hybridisation process. In the first stage, the most mafic magma evolved mainly by fractional crystallisation coupled with assimilation of metasedimentary rocks having crustal time-integrated Sr and Nd compositions similar to those of locally exposed metamorphic basement. The second stage involves contaminated products mixing with independently generated crustal melts. Petrographic, geochemical and isotope data also provide evidence of significant compositional differences in the felsic end-members, pointing to the involvement of metaigneous and metasedimentary source rocks for the Abbott granite and Vegetation leucogranite, respectively. Received: 31 March 1998 / Accepted: 3 May 1999     

太行山和华北其它地区中生代岩浆作用的锆石U-Pb年代学和地球化学特征及其岩浆成因和地球动力学意义

华北克拉通东部中生代岩浆岩的主要特征是岩石类型复杂(从辉长质到二长花岗质),显示高钾钙碱性、高Sr-Ba、高Sr/Y和La/Yb比值和高度富集的Sr-Nd同位素成分。锆石SHRIMP定年表明,太行山地区岩浆作用发生在138-127Ma之间。该年代结果与东亚其它地区已经发表的锆石年代数据揭示了中生代岩浆作用的发展具有从日本岛(和朝鲜半岛;210Ma),到胶辽半岛(180Ma),再到大别山-太行山(138Ma)的年轻化趋势。这暗示华北中生代岩浆作用可能与古太平洋板块的俯冲有关,但华北中生代岩浆岩似乎没有明显的向内陆方向的成分变化极性,可能与古太平洋板块在地幔过渡带的水平俯冲有关。地球化学数据表明,华北中生代岩浆岩可能主要形成于壳幔岩浆混合作用和随后的分离结晶过程,而不是形成于基性下地壳部分熔融作用。     

Revisiting Early–Middle Jurassic igneous activity in the Nanling Mountains,South China: Geochemistry and implications for regional geodynamics

Early–Middle Jurassic igneous rocks (190–170 Ma) are distributed in an E–W-trending band within the Nanling Tectonic Belt, and have a wide range of compositions but are only present in limited volumes. This scenario contrasts with the uniform but voluminous Middle–Late Jurassic igneous rocks (165–150 Ma) in this area. The Early–Middle Jurassic rocks include oceanic-island basalt (OIB)-type alkali basalts, tholeiitic basalts and gabbros, bimodal volcanic rocks, syenites, A-type granites, and high-K calc–alkaline granodiorites. Geochemical and isotopic data indicate that alkaline and tholeiitic basalts and syenites were derived from melting of the asthenospheric mantle, with asthenosphere-derived magmas mixing with variable amounts of magmas derived from melting of metasomatized lithospheric mantle. In comparison, A-type granites in the study area were probably generated by shallow dehydration-related melting of hornblende-bearing continental crustal rocks that were heated by contemporaneous intrusion of mantle-derived basaltic magmas, and high-K calc-alkaline granodiorites resulted from the interaction between melts from upwelling asthenospheric mantle and the lower crust. The Early–Middle Jurassic magmatic event is spatially variable in terms of lithology, geochemistry, and isotopic systematics. This indicates that the deep mantle sources of the magmas that formed these igneous rocks were significantly heterogeneous, and magmatism had a gradual decrease in the involvement of the asthenospheric mantle from west to east. These variations in composition and sourcing of magmas, in addition to the spatial distribution and the thermal structure of the crust–mantle boundary during this magmatic event, indicates that these igneous rocks formed during a period of rifting after the Indosinian Orogeny rather than during subduction of the paleo-Pacific oceanic crust.     

Crust–mantle interaction triggered by oblique subduction of the Pacific plate: geochronological,geochemical, and Hf isotopic evidence from the Early Cretaceous volcanic rocks of Zhejiang Province,southeast China

Large-scale volcanism in the late Mesozoic was a prominent geological event in southeast China. The late Mesozoic volcanic sequences, named the Moshishan Group, are exposed in Zhejiang Province and are predominantly felsic in composition with subordinate mafic magma and rare andesites. To understand the late Mesozoic tectonic evolution of southeast China, we present zircon U–Pb dating, major and trace element analyses, and Hf isotopic compositions from felsic volcanic rocks of the Moshishan Group. Zircon U–Pb dating shows that the Moshishan Group formed between 145 and 129 Ma. The ε_Hf(t) of the analysed zircons ranges from ?16.58 to +6.89, and the T_DM2 age ranges from 753 to 2238 Ma with a major peak at ca. 1870 Ma. Hf isotopic compositions of zircons in Early Cretaceous volcanic rocks are more radiogenic than that of the metamorphic basement rocks, indicating a juvenile component in these magmas. Major element concentrations show that the volcanic rocks mainly belong to the high-K calc-alkaline series. Both zircon saturation temperatures and the ε_Hf(t) values of zircons gradually increased with the evolution of the magma. Trace element data indicates that neither magmatic differentiation of mantle-derived magma nor mixing of magmas from different sources were the predominant magmagenetic processes. Earlier studies suggest that contemporaneous underplating contributed to the heat source that induced crustal melting and to the material origin that inconsistently mixed with the local crustal melts. Magmatic underplating is likely to have occurred because of the southwestward subduction of the Pacific plate with episodic slab rollback. The data obtained in this study suggest that the crust–mantle interaction under the influence of slab rollback played a progressive role in the formation of Early Cretaceous felsic volcanic rocks in southeast China.     

High-temperature–low-pressure metamorphism and the production of S-type granites of the Hillgrove Supersuite,southern New England Orogen,NSW, Australia

The high-temperature–low-pressure Wongwibinda Metamorphic Complex of the southern New England Orogen is bound by S-type granite plutons of the Hillgrove Supersuite to the north, east and south. New U–Pb geochronology of five samples of the Hillgrove Supersuite demonstrates that plutonism in the complex involved two pulses: ca 300 Ma and ca 292 Ma. This indicates that plutonism partially overlaps the age of high-T–low-P metamorphism (296.8 ± 1.5 Ma), but also postdates it. Zircon grains identified as xenocrysts based on age (≥310 Ma) have U–Pb–Hf isotopic character that largely overlaps detrital grains in the host Girrakool Beds, indicating that accretionary complex crust is the likely source of these xenocrysts. The ¹⁷⁶Hf/¹⁷⁷Hf initial character for zircon for the ca 300 Ma plutons (three samples) is less radiogenic than those in the ca 292 Ma plutons (two samples). The progression in ¹⁷⁶Hf/¹⁷⁷Hf initial character for zircon infers an increasing mantle component in the Hillgrove Supersuite with time. These data are evidence of a rift tectonic setting, where mantle-derived magmas are predicted to more readily migrate to shallower crustal levels as the crust thins and becomes hotter. Additionally, early episodes of partial melting in the system melt-depleted the metasedimentary sources, thus reducing the S-type component as anatexis progressed. The evolution of the Hillgrove Supersuite coincides with a period of early Permian slab roll back and extension accompanied by crustal rifting and thinning, leading to high-T–low-P metamorphism, anatexis and S-type granite production and the development of rift basins such as the Sydney–Gunnedah–Bowen system.     

Proterozoic VanDieland in Central Victoria: ages,compositions and source depths for late devonian silicic magmas

The Proterozoic to Cambrian VanDieland microcontinent was accreted to mainland Australia at ca 400?Ma, and its northern tip, the Selwyn Block, forms the basement in central Victoria. Here, mainly Late Devonian, silicic magmas were derived from the Selwyn Block and intruded into the shallow crust. We use the phase petrology of Late Devonian, S-type rhyolitic ignimbrites and a xenolith of pelitic migmatite, together with Nd-model ages for the silicic magmatic rocks to constrain the lithological characteristics of the metasedimentary component of the Selwyn Block, to infer minimum depths and temperature conditions here in the Late Devonian, and the likely ages of the source rocks for the S-type magmas. The most abundant source rocks are inferred to be volcaniclastic metagreywackes, with minor metadacites, meta-andesites and metapelites. The metapelitic xenolith cannot have been the source for any of the silicic magmas but constrains the upper amphibolite-facies part of the Selwyn Block to depths around 17?km, where temperatures reached ～775?°C. The older ignimbrite magma was formed by partial melting at perhaps 770?°C and a depth of at least 33?km, while the younger ignimbrite magma formed at ～23?km and 900?°C. These depths suggest source rocks in the Paleoproterozoic to Mesoproterozoic lower parts of the Selwyn Block. Nd-model ages of the silicic magmatic rocks confirm a dominance of Mesoproterozoic to Paleoproterozoic sources. If the inferred rock types in the Mesoproterozoic formations were as current correlations suggest, the sources for the Late Devonian silicic magmas would have to lie in the undocumented Paleoproterozoic basement of the Selwyn Block. Rock types here must include andesitic to dacitic volcanic components as well as volcaniclastic greywackes and minor pelites, which suggests a continental arc setting. The Late Devonian magmatism in the region may record the progression from amphibolite- to granulite-facies conditions during post-orogenic extension, with heat advected to the crust by mantle-derived mafic magmas. These processes would have resulted in mafitisation of the deep Selwyn Block.     

Composition and geochronology of the deep-seated xenoliths from the southeastern margin of the North China Craton

A variety of deep-seated xenoliths occur within the Mesozoic Jiagou dioritic porphyry in the southeastern margin of the North China Craton (NCC). In this study we present a combined petrologic, geochronological, Hf isotope and geochemical study on the different types of xenoliths and use these data to better constrain the composition and age of the deep crust beneath the area. Most of the xenoliths are mafic meta-igneous rocks, among which garnet-bearing lithologies are common. The xenoliths can be classified into three broad petrographic groups: spinel-bearing garnet clinopyroxenite/phlogopite clinopyroxenite/spinel pyroxenite (Group 1), garnet amphibolite or hornblendite/garnet granulite/mafic gneiss lacking pyroxene (Group 2), and garnet-bearing felsic (intermediate-acid) gneiss (Group 3). Among these, the mafic–ultramafic rocks constitute the dominant category. The protoliths of the studied xenoliths range from basalt through andesite to dacite. Geochemical and Hf-isotope data indicate that most xenoliths belonging to Groups 2 and 3 resemble magmatic rocks formed at convergent continental margin arc setting. A few of them (mostly belonging to Group 1) represent mantle-derived products. Multiple metasomatic imprints, with contribution from subduction-related or mantle-derived fluids or melts have been recognized from the multistage mineral assemblages and ages.SHRIMP zircon U–Pb dating, Hf isotope and geochemical data offer evidence for subduction-related adakite-like and arc-related rocks in the southeastern margin of the NCC at ca. 2.5 Ga and 2.1 Ga, and confirm the occurrence of high-pressure granulite-facies metamorphism at ca. 1.8 Ga. These data suggest an episodic growth of Precambrian lower crust beneath this region in response to two stages of subduction–accretion and one vertical accretion of mantle-derived basaltic magma at the base of the lower crust. Additionally, a previously unknown late mantle-derived basaltic magmatism at 393 ± 7 Ma has also been recognized. The data presented in this paper demonstrate that the deep crust beneath the southeastern margin of the NCC is composed of hybrid protoliths derived from Paleozoic, Paleoproterozoic and late Neoarchean sources.     

Spatial-temporal relationships of late Mesozoic granitoids in Zhejiang Province,Southeast China: constraints on tectonic evolution

ABSTRACT

Late Mesozoic granitoids in South China are generally considered to have been generated under the Palaeo–Pacific tectonic regime, however, the precise subduction mechanism remains controversial. Detailed zircon U–Pb geochronological, major and trace element, and Sr–Nd–Hf isotopic data are used to document the spatiotemporal distribution of the granitoids in Zhejiang Province. Three periods of late Mesozoic magmatism, including stage 1 (170–145 Ma), stage 2 (145–125 Ma), and stage 3 (125–90 Ma), can be distinguished based on systematic zircon U–Pb ages that become progressively younger towards the SE. Stage 1 granitic rocks are predominantly I-type granitoids, but minor S- or A-type rocks also occur. Sr–Nd–Hf isotopic data suggest that these granitoids were generated from hybrid magmas that resulted from mixing between depleted mantle-derived and ancient crust-derived magmas that formed in an active continental margin environment related to the low-angle subduction of the Palaeo–Pacific plate beneath Southeast China mainland. Stage 2 granitic rocks along the Jiangshan–Shaoxing Fault are predominantly I- and A-type granitoids with high initial ⁸⁷Sr/⁸⁶Sr, low ε_Nd(t), ε_Hf(t) values and Mesoproterozoic Nd–Hf model ages. These results suggest that stage 2 granitoids were derived from mixing between enriched mantle-derived mafic magmas and ancient crust-derived magmas in an extensional back-arc setting related to rollback of the Palaeo–Pacific slab. Stage 3 granitic rocks along the Lishui–Yuyao Fault comprise mainly A- and I-type granitoids with high initial ⁸⁷Sr/⁸⁶Sr ratios, and low ε_Nd(t) and ε_Hf(t) values, again suggesting mixing of enriched mantle-derived mafic magmas with more ancient crustal magmas in an extensional back-arc setting, related in this case to the continued rollback the Palaeo–Pacific plate and the outboard retreat of its subduction zone.     

西藏措勤麦嘎岩基的锆石U-Pb年代学、地球化学和锆石Hf同位素:对中部拉萨地块早白垩世花岗岩类岩石成因的约束

西藏中部拉萨地块大规模早白垩世花岗岩类的岩浆源区和岩石成因迄今尚未得到很好约束,对这些问题的深入理解将有助于揭示拉萨地块白垩纪时期的岩浆作用过程及成矿背景。本文报道了中部拉萨地块代表性花岗岩基——措勤麦嘎岩基的锆石U-Pb年代学、全岩元素地球化学、Sr-Nd同位素和锆石Hf同位素数据。本文锆石U-Pb定年结果表明,麦嘎岩基花岗质岩主要侵位于122±1Ma和113±2Ma,闪长质包体与后者同期(113±2Ma)。122±1Ma花岗质岩属I型弱过铝质高钾钙碱性系列,(87Sr/86Sr)i值高(0.7147),全岩εNd(t)(-12.0)和锆石εHf(t)(-15.7～-11.1)为较大的负值,表明其很可能来源于古老下地壳物质的重熔。113±2Ma寄主花岗质岩为I型偏铝质-弱过铝质高钾钙碱性系列,相对于122±1Ma花岗质岩石,其(87Sr/86Sr)i比值偏低(0.7094～0.7156)、全岩εNd(t)值(-12.1～-7.3)和锆石εHf(t)值(-11.1～0.1)较高,很可能来源于古老下地壳物质的部分熔融,并含有更多幔源物质。闪长质包体(113±2Ma)为偏铝质中-高钾钙碱性系列,以变化范围大的(87Sr/86Sr)i(0.7058～0.7105)、负的全岩εNd(t)值(-10.7～-9.8)及负的锆石εHf(t)值(-14.0～-5.6)为特征,可能是古老富集岩石圈地幔物质部分熔融的产物或亏损地幔物质经历强烈地壳混染作用的结果。在目前已有资料条件下(缺乏同期基性岩石的相关数据),本文暂将麦嘎岩基113±2Ma寄主花岗质岩及同期闪长质包体解释为镁铁质岩浆与长英质岩浆发生不同程度岩浆混合作用的产物,这一解释可能对中部拉萨地块同期花岗类的岩石成因具普遍意义。麦嘎岩基及中部拉萨地块同期岩浆岩约113Ma幔源物质增加现象,可能是南向俯冲的班公湖-怒江洋壳岩石圈板片断离的结果。     

Spatial, temporal and geochemical characteristics of Silurian collision-zone magmatism, Newfoundland Appalachians: An example of a rapidly evolving magmatic system related to slab break-off

Silurian plutonic suites in the Newfoundland Appalachians include abundant gabbro, monzogabbro and granite to granodiorite and lesser quartz diorite and tonalite. Most are medium- to high-K, but included are some low-K and shoshonitic mafic compositions. Felsic rocks are of both alkaline (A-type or within-plate granite (WPG)) and calc-alkaline volcanic arc granite (VAG) affinity. Mafic rocks include both arc-like (Nb/Th < 3) calc-alkaline and non-arc-like (Nb/Th > 3) transitional calc-alkaline basalt to continental tholeiitic affinity compositions. ε_Nd(T) values range from − 9.6 to + 5.4 and δ¹⁸O (VSMOW) values range from + 3.1 to + 13.2‰.

A rapid progression from exclusively arc-type to non-arc-like mafic and then contemporaneous WPG plus VAG magmatism has been documented using precise U–Pb zircon dating. Earlier arc-like plutonism indicates subduction, while asthenosphere-derived mafic magmas support slab break-off, due to subduction of a young, warm back-arc basin. Contemporaneous mafic magmas with arc and non-arc geochemical signatures may reflect tapping of asthenospheric and subcontinental lithospheric mantle (SCLM) sources and/or contamination of asthenosphere-derived magmas by SCLM or crust.

The brevity (< 5 Ma) of the mafic magmatic pulse agrees with the transient nature of magmatism associated with slab break-off. The subsequent ca. 1 to 2 m.y. period of voluminous WPG and VAG plutonism likely reflects mafic magma-driven partial melting of both SCLM and crustal sources, respectively. Continuation of VAG-like magmatism for an additional 2 to 5 m.y. may reflect lower solidus temperatures of crustal materials, enabling anatexis to continue after mantle melting ceased. East to west spatial variation of ε_Nd and (La/Yb)_CN in Silurian plutons suggests a transition from shallow melting of juvenile sources proximal to the collision zone to deeper melting of old source materials in the garnet-stability field further inboard.

Previous work has demonstrated that geochemical discriminaton of post-collisional granitoid magmatism (PCGM) is difficult in the absence of other constraints. Our example should contribute to the understanding and identification of PCGM if it can be employed as a ‘fingerprint’ for slab break-off-related PCGM within the Paleozoic geological record.     

Commingling and mixing of S-type peraluminous, ultrapotassic and basaltic magmas in the Cayconi volcanic field, Cordillera de Carabaya, SE Peru

The Cayconi district of the Cordillera de Carabaya, SE Peru, exposes a remnant of an upper Oligocene–Lower Miocene (22.2–24.4 Ma) volcanic field, comprising a diverse assemblage of S-type silicic and calc-alkaline basaltic to andesitic flows, members of the Picotani Group of the Central Andean Inner Arc. Basaltic flows containing olivine, plagioclase, clinopyroxene, ilmenite and glass, and glassy rhyolitic agglutinates with phenocrystic quartz, cordierite, plagioclase, sanidine, ilmenite and apatite, respectively exhibit mineralogical and geochemical features characteristic of medium-K mafic and Lachlan S-type silicic lavas. Cordierite-bearing dacitic agglomerates and lavas, however, are characterized by dispersed, melanocratic micro-enclaves and phenocrysts set in a fine-grained quartzo-feldspathic matrix. They contain a bimodal mica population, comprising phlogopite and biotite, as well as complexly zoned, sieve-textured plagioclase grains, sector-zoned cordierite, sanidine, quartz, irregular patches of replaced olivine, clinopyroxene and orthopyroxene and accessory phases including zircon, monazite, ilmenite and chromite. The coexistence of minerals not in mutual equilibrium and the growth/dissolution textures exhibited by plagioclase are features indicative of magmatic commingling and mixing. Trachytic-textured andesite flows interlayered with olivine+plagioclase–glomerophyric, calc-alkaline basalts have a phenocrystic assemblage of resorbed orthopyroxene and plagioclase and exhibit melanocratic groundmass patches of microphenocrystic phlogopite, Ca-rich sanidine, ilmenite and aluminous spinel. The mineralogical and mineral chemical relationships in both the dacites and the trachytic-textured andesites imply subvolcanic mixing between distinct ultrapotassic mafic melts, not represented by exposed rock types, and both the S-type silicic and calc-alkaline mafic magmas. Such mixing relationships are commonly observed in the Oligo-Miocene rocks of the Cordillera de Carabaya, suggesting that the S-type rocks in this area and, by extension, elsewhere derive their unusually high K₂O, Ba, Sr, Cr and Ni concentrations from commingling and mixing with diverse, mantle-derived potassic mafic magmas.     

Chronological and genetic relationships between intrusive rocks of the Berdyaush pluton,South Urals,in light of new U-Pb and Sm-Nd isotopic data

Geological observations in combination with previously published and new isotopic data allowed us to reconstruct the history of geological events that eventually gave rise to the formation of the Berdyaush pluton situated on the western slope of the South Urals: (1) emplacement of gabbro into Lower Riphean sedimentary rocks (1410–1390 Ma); an enriched mantle source of gabbro arising in the Archean or Paleoproterozoic; (2) formation of granitic melt in the lower crust; Archean TTG association subsequently enriched in K and correlative elements as a result of interaction with enriched mantle-derived magmas and related fluids was a magma source; mixing of mantle and crustal magmas in the course of their synchronous ascent with formation of hybrid intrusive rocks; injections of mafic and hybrid melts into incompletely solidified granite; fragmentation of such injections with the formation of melanocratic nodules; emplacement of basic dikes into the cooled granite—all these events took place 1410–1360 Ma ago; (3) discrete episodes of partial melting of enriched mantle source with waning intensity; formation of minor volumes of melt, which solidified under auto- and paraautochthonous conditions as local domains highly enriched in incompatible elements (1360–1270 Ma); (4) partial melting of those domains resulting in the formation of minor nepheline syenite intrusions (915–800 Ma), containing relict zircon grains dated at >1270 Ma; (5) injections of mantle-derived alkaline melt contaminated with crustal granitic material as microsyenite and syenite porphyry dikes (700–500 Ma ?). Thus, the Berdyaush pluton is a projection of a local domain of mantle and crustal magma generation, which periodically resumed its activity over almost a billion years.