The effects of a nitrification inhibitor on leaching losses and recovery of mineralized nitrogen by a wheat crop after ploughing-in temporary leguminous pastures

The effect of a nitrification inhibitor on the accumulation of ammonium (NH ₄ ⁺ -N) and nitrate (NO ₃ ^- -N) in the profile was investigated in two field experiments in Canterbury, New Zealand after the ploughing of a 4-year old ryegrass/white clover pasture in early (March) and late autumn (May). Nitrate leaching over the winter, and yield and N uptake of a following wheat crop were also assessed.The accumulation of N in the soil profile by the start of winter was greater in the March fallow (76–140 kg N ha^–1) than in the May fallow treatment (36–49 kg N ha^–1). The nitrification inhibitor dicyandiamide (DCD) did not affect the extent of net N mineralization, but it inhibited nitrification when applied to pasture before ploughing, especially at its depth of incorporation (100–200 mm). Nitrification inhibition in spring was greater when DCD was applied in May rather than in March due to its reduced degradation over the winter.Cumulative nitrate leaching losses were substantial from the March fallow treatment in both years (about 100 kg N ha^–1). A delay in the cultivation of pasture and the application of DCD both reduced nitrate leaching losses. When leaching occurred early in the winter (in 1991), losses were less when pasture was cultivated in May (2 kg N ha^–1) than when DCD was applied to pasture cultivated in March (68 kg N ha^–1). When leaching occurred late in the winter (in 1992), similar losses were measured from pasture cultivated in May (49 kg N ha^–1) and from DCD-treated pasture cultivated in March (57 kg N ha^–1).Grain harvest yield and N uptake of the following spring wheat crop were generally unaffected by the size of the N leaching loss over the winter. This was due to the high N fertility of the soil after four years of a grazed leguminous pasture.     

Nitrogen use efficiency by maize as affected by a mucuna short fallow and P application in the coastal savanna of West Africa

Maize is the primary food crop grown by farmers in the coastal savanna region of Togo and Benin on degraded (rhodic ferralsols), low in soil K-supplying capacity, and non-degraded (plinthic acrisols) soils. Agronomic trials were conducted during 1999–2002 in southern Togo on both soil types to investigate the impact of N and P fertilization and the introduction of a mucuna short fallow (MSF) on yield, indigenous N supply of the soil, N recovery fraction and internal efficiency of maize. In all plots, an annual basal dose of 100 kg K ha^–1 was applied to the maize crop. Maize and mucuna crop residues were incorporated into the soil during land preparation. Treatment yields were primarily below 80% of CERES-MAIZE simulated weather-defined maize yield potentials, indicating that nutrients were more limiting than weather conditions. On degraded soil (DS), maize yields increased from 0.4 t ha^–1 to 2.8 t ha^–1 from 1999 to 2001, without N or P application, in the absence of MSF, with annual K application and incorporation of maize crop residues. Application of N and P mineral fertilizer resulted in yield gains of 1–1.5 t ha^–1. With MSF, additional yield gains of between 0.5 and 1.0 t ha^–1 were obtained at low N application rates. N supply of the soil increased from 10 to 42 kg ha^–1 from 1999 to 2001 and to 58 kg N ha^–1 with MSF. Application of P resulted in significant improvements in N recovery fraction, and greatest gains were obtained with MSF and P application. MSF did not significantly affect internal N efficiency, which averaged 45 kg grain (kg N uptake)^–1. On non-degraded soils (NDS) and without N or P application, in the absence of MSF, maize yields were about 3 t ha^–1 from 1999 to 2001, with N supply of the soil ranging from 55 to 110 kg N ha^–1. Application of 40 kg P ha^–1 alone resulted in significant maize yield gains of between 1.0 (1999) and 1.5 (2001) t ha^–1. Inclusion of MSF did not significantly improve maize yields and even reduced N recovery fraction as determined in the third cropping year (2001). Results illustrate the importance of site-specific integrated soil fertility management recommendations for the southern regions of Togo and Benin that consider indigenous soil nutrient-supplying capacity and yield potential. On DS, the main nutrients limiting maize growth were N and probably K. On NDS, nutrients limiting growth were mainly N and P. Even on DS rapid gains in productivity can be obtained, with MSF serving as a means to allow farmers with limited financial means to restore the fertility of such soils. MSF cannot be recommended on relatively fertile NDS.     

Nitrogen management in organic farming: comparison of crop rotation residual effects on yields,N leaching and soil conditions

After 3 years of different crop rotations in an organic farming experiment on a sandy soil in northwest Germany, spring triticale was cultivated on all plots in the fourth year to investigate residual effects on yield, nitrogen (N) leaching and nutrient status in the soil. Previous crop rotations differed in the way N was supplied, either by farmyard manure (FYM, 100 and 200 kg N ha⁻¹ year⁻¹) or by arable legumes like grass-red clover and field beans, or as a control with no N. Other crops in the rotations were maize, winter triticale and spring barley. Additional plots had a 3-year grass-clover ley, that was ploughed-in for spring triticale in the fourth year. Yields of spring triticale were moderate and largest for ploughed-in grassland leys and grass-red clover and plots that had previously received farmyard manure. The former crop rotation, including grassland break-up, had a significant effect on most yield and environmental parameters like residual soil mineral nitrogen (SMN) and N leaching and on the level of available K in the soil. The single crop harvested in the year before spring triticale had a significant effect on yield parameters of spring triticale, less so on SMN and N leaching in the fourth year and no effect on available nutrients (P, K, Mg) and pH in the soil. We conclude that the effects of arable legumes were rather short lived while ploughing of 3-year grassland leys had a profound influence on mineralization processes and subsequently on yield and N losses.     

Use of nitrification inhibitors (neem and DCD) to increase N efficiency in maize-wheat cropping system

A 2-year field experiment was conducted to study the effects of the nitrification inhibitors dicyandiamide (DCD) and neem cake on the efficiency of applied prilled urea nitrogen in a maize-wheat cropping system. Prilled urea (PU), neem cake coated urea (NCU) and DCD blended urea (DCDU) were applied to maize at two levels (60 and 120 Kg N ha^–1) and two methods (all preplant and split) of N application along with a no-nitrogen control and their relative residual effect was studied on succeeding wheat grown with three levels of N as PU.In 1990 maize responded well to N up to 60 kg N ha^–1; at this level PU increased maize yield by 1.03 t ha^–1, whereas NCU and DCDU increased maize yield by 1.55 and 1.18 t ha^–1 over the control, which was equivalent to an application of 127 and 94 kg N ha^–1 as PU, respectively. Furthermore, when the results were averaged over two years of study, residual N from the application of NCU and DCDU at 60 kg N ha^–1 left after maize cropping increased the grain yield of the succeeding wheat crop grown with 60 kg N ha^–1 as PU by 1.97 and 1.68 t ha^–1, respectively, over a no nitrogen control or 60 kg N ha^–1 as PU applied to the maize. This was equal to an application of 96 and 82 kg N ha^–1 as PU to wheat.Thus, neem cake increased the efficiency of urea N applied to maize and benefits were also seen in the succeeding wheat yield in the maize-wheat cropping system.     

N application to winter wheat at tillering and shooting: N balance at different growth stages

At two sites, microplots under winter wheat were given 140 kg N ha^–1 as labelled ammonium nitrate split in 80 kg N ha^–1 at tillering and 60 kg N ha^–1 at shooting. Soil and plant samples were analyzed at shooting, after anthesis and at grain harvest and a¹⁵N balance was established. The average recovery rate of 95% indicates that there were no marked N losses due to leaching and denitrification, which is attributed to the low rainfall in the two months after fertilizer application. Between 19 and 23% of the fertilizer N remained in the 0–30 cm soil layer as organically bound soil N. Up to 64% was taken up by the above-ground crop. On the loamy sand, 4% of the fertilizer N at harvest remained in the roots in the 0–30 cm layer and only 3% was found as inorganic N in the 0–90 cm soil layer. The fertilizer N applied diminished plant uptake of soil N in the period between fertilizer application and harvest. As compared with the control, the fertilized plants extracted 25 and 28% less soil N from loamy sand and loess soil, respectively. The results show that application of mineral N fertilizer helps to maintain the mineralizable N content of the soil, which has been accumulated in the course of long-term intensive crop production, by adding N to the soil organic pool and simultaneously reducing the supply of soil N to the plants.     

Effects of type and amount of applied nitrogen fertilizer on nitrous oxide fluxes from intensively managed grassland

Five field experiments and one greenhouse experiment were carried out to assess the effects of nitrogen (N) fertilizer type and the amount of applied N fertilizer on nitrous oxide (N₂O) emission from grassland. During cold and dry conditions in early spring, emission of N₂O from both ammonium (NH ₄ ⁺ ) and nitrate (NO ₃ ^– ) containing fertilizers applied to a clay soil were relatively small, i.e. less than 0.1% of the N applied. Emission of N₂O and total denitrification losses from NO ₃ ^– containing fertilizers were large after application to a poorly drained sand soil during a wet spring. A total of 5–12% and 8–14% of the applied N was lost as N₂O and via denitrification, respectively. Emissions of N₂O and total denitrification losses from NH ₄ ⁺ fertilizers and cattle slurry were less than 2% of the N applied. Addition of the nitrification inhibitor dicyandiamide (DCD) reduced N₂O fluxes from ammonium sulphate (AS). However, the effect of DCD to reduce total N₂O emission from AS was much smaller than the effect of using NH ₄ ⁺ fertilizer instead of NO ₃ ^– fertilizer, during wet conditions. The greenhouse study showed that a high groundwater level favors production of N₂O from NO ₃ ^– fertilizers but not from NH ₄ ⁺ fertilizers. Inereasing calcium ammonium nitrate (CAN) application increased the emitted N₂O on grassland from 0.6% of the fertilizer application rate for a dressing of 50 kg N ha^–1 to 3.1% for a dressing of 300 kg N ha^–1. In another experiment, N₂O emission increased proportionally with increasing N rate. The results indicate that there is scope for reducing N₂O emission from grasslands by choosing the N fertilizer type depending on the soil moisture status. Avoiding excessive N application rates may also minimize N₂O emission from intensively managed grasslands.     

The effect of plant residues on plant uptake and leaching of soil and fertilizer nitrogen in a tropical red earth soil

Two field experiments, in which differing amounts and types of plant residues were incorporated into a red earth soil, were conducted at Katherine, N.T., Australia. The aim of the work was to evaluate the effect of the residues on uptake of soil and fertilizer N by a subsequent sorghum crop, on the accumulation and leaching of nitrate, and on losses of N.Stubble of grain sorghum applied at an exceptionally high rate (~ 18 000 kg ha^–1) reduced uptake of N by sorghum by 13% and depressed the accumulation of nitrate under a crop and particularly under a fallow.Loss of fertilizer N, movement of nitrate down the profile, and uptake by the crop was studied in another experiment after application of N as¹⁵NH₄ ¹⁵NO₃ to field microplots. By four weeks after fertilizer application 14% had been lost from the soil-plant system and by crop maturity 36 per cent had been lost. The pattern of¹⁵N distribution in the profile suggested that losses below 150 cm had occurred during crop growth. The recovery of¹⁵N by the crop alone ranged from 16 to 32 per cent. There was an apparent loss of N from the crop between anthesis and maturity. Residue levels common to sorghum crops in the region (~ 2000 kg ha^–1) did not significantly affect uptake by a subsequent sorghum crop, N losses, or distribution of nitrate in the profile.     

Nitrogen uptake by autumn sown sugar beet

The influence of N fertilizer rate on uptake and distribution of N in the plant,¹⁵N labelled fertilizer uptake and sugar yield were studied for 3 years on autumn sown sugar beet (Beta vulgaris L.) under Mediterranean (Southern Spain) rain-fed and irrigated conditions. Available average soil N prior to sowing was 69 kg N ha^–1, and net mineralisation in the soil during the growth period was 130 kg N ha^–1. Maximum N uptake occurred in the spring and increased with increasing fertilizer rates in the irrigated crop. There was no increase in N uptake in the sugar beet cropped under rain-fed conditions because of water shortage. Maximum average N uptake both by roots and tops was between 200 and 250 kg N ha^–1. When N fertilizer was not applied, average uptake from the soil was between 130 and 140 kg N ha^–1. At the end of the growth period there was a marked translocation of N from the leaves to the root which increased with the N fertilizer rate. The N ratio top/roots at harvest was 0.45–0.5 and 0.8- - 1 in the irrigated and rain-fed sugar beet, respectively. Maximum¹⁵N labelled fertilizer uptake took place in May-June, being larger in irrigated sugar beet or when spring rainfall was more abundant. Fertilizer use efficiency varied between 30% and 68%. Sugar yield response to N fertilizer rates depended on the N available in the soil and on the total water input to the crop, particularly in spring. The response was more constant in the irrigated crop, where optimum yield was obtained with a fertilizer rate of 160 kg N ha^–1. In the rain-fed crop, the optimum dose proved more erratic, with an estimated mean of 100 kg N ha^–1. The amount of N required to produce 1 t of root and of sugar ranged between 1.5 and 3.8 kg N and between 11.1 and 22.4 kg N respectively, and varied according to the N fertilizer rates applied.     

The effect of fertiliser type and application rate on denitrification losses from cut grassland in Northern Ireland

Denitrification losses were measured using the acetylene inhibition technique adapted for a coring procedure. Two soils under a cut ryegrass sward were used. One soil was a freely-drained clay loam receiving under 900 mm rainfall annually, the other soil being a poorly-drained silty clay receiving over 1100 mm rainfall annually. Swards at each site received up to 300 kg N ha^–1 yr^–1 of calcium ammonium nitrate (CAN), urea or a new fertiliser mixture GRANUMS (30% ammonium nitrate, 30% urea, 10% ammonium sulphate, 30% dolomite). For both soils the rate of denitrification exceeded 0.1 kg N ha^–1 day^–1 only when the air-filled porosity of the soil was < 30% v/v and soil nitrate was > 2 mg N kg^–1 in the top 10cm of the profile and when soil temperature at 10 cm was > 4°C. When the soils dried such that their air-filled porosity was > 30% v/v, denitrification rates decreased to < 0.08 kg N ha^–1 day^–1. Highest rates (up to 3.7 kg N ha^–1 day^–1) were observed on the clay soil following application of 94 kg N ha^–1 CAN to soil near field capacity in early summer 1986. Losses from CAN were approximately 3 times those from urea for a given application. Denitrification losses from the GRANUMS treatment were, overall, intermediate between those from CAN and urea but the daily losses more closely resembled those from the CAN treatment. The impeded drainage on the clay soil, where soil moisture contents remained close to field capacity throughout the year, showed denitrification losses roughly 3 times those observed on the more freely drained clay-loam for any given treatment. Over a 12-month period, N losses arising from denitrification were 29.0 and 10.0 kg N ha^–1 for plots receiving 300 kg N ha^–1 CAN and urea, respectively, on the well drained clay-loam and 79.0 and 31.1 kg N ha^–1 respectively, for identical plots on the poorly drained clay soil. Annual denitrification losses from control plots were < 1 kg N ha^–1 on both soils.     

Integrated soil management for the savanna zone of W. Africa: legume rotation and fertilizer N

Integrated soil management with leguminous cover crops was studied at two sites in the northern Guinea savanna zone of northern Nigeria, Kaduna (190 day growing season) and Bauchi (150 days). One-year planted fallows of mucuna, lablab, and crotalaria were compared with natural grass fallow and cowpea controls. All treatments were followed by a maize test crop in the second year with 0, 30, or 60 kg N ha^–1 as urea. Above ground legume residues were not incorporated into the soil and most residues were burned early in the dry season at the Kaduna site. Legume rotation increased soil total N, maize growth in greenhouse pots, and dry matter and N accumulation of maize. Response of maize grain yield to 30 kg N ha^–1 as urea was highly significant at both sites and much greater than the response to legume rotation. The mean N fertilizer replacement value from legume rotation was 14 kg N ha^–1 at Kaduna and 6 kg N ha^–1 at Bauchi. W ith no N applied to the maize test crop, maize grain yield following legume fallow was 365 kg ha^–1 higher than natural fallow at Bauchi and 235 kg ha^–1 higher at Kaduna. The benefit of specific legume fallows to subsequent maize was mostly related to above ground N of the previous legume at Bauchi, where residues were protected from fire and grazing. At Kaduna, where fallow vegetation was burned, maize yield was related to estimated below ground N. The results show that legume rotation alone results in small maize yield increases in the dry savanna zone.     

The effect of fertilizer placement on nitrogen uptake and yield of wheat and maize in Chinese loess soils

Field trials were carried out to study the fate of¹⁵N-labelled urea applied to summer maize and winter wheat in loess soils in Shaanxi Province, north-west China. In the maize experiment, nitrogen was applied at rates of 0 or 210 kg N ha^–1, either as a surface application, mixed uniformly with the top 0.15 m of soil, or placed in holes 0.1 m deep adjacent to each plant and then covered with soil. In the wheat experiment, nitrogen was applied at rates of 0, 75 or 150 kg N ha^–1, either to the surface, or incorporated by mixing with the top 0.15 m, or placed in a band at 0.15 m depth. Measurements were made of crop N uptake, residual fertilizer N and soil mineral N. The total above-ground dry matter yield of maize varied between 7.6 and 11.9 t ha^–1. The crop recovery of fertilizer N following point placement was 25% of that applied, which was higher than that from the surface application (18%) or incorporation by mixing (18%). The total grain yield of wheat varied between 4.3 and 4.7 t ha^–1. In the surface applications, the recovery of fertilizer-derived nitrogen (25%) was considerably lower than that from the mixing treatments and banded placements (33 and 36%). The fertilizer N application rate had a significant effect on grain and total dry matter yield, as well as on total N uptake and grain N contents. The main mechanism for loss of N appeared to be by ammonia volatilization, rather than leaching. High mineral N concentrations remained in the soil at harvest, following both crops, demonstrating a potential for significant reductions in N application rates without associated loss in yield.     

Leaching of nitrate,calcium and magnesium under maize cultivation on an oxisol in Togo

In tropical regions, crop yields generally decrease with time, partly due to a decline in the levels of exchangeable bases linked to acidification of the upper layers of the soil. Nitrogen, calcium and magnesium balances were studied on an oxisol in southern Togo under continuous maize cropping with mineral fertilization and crop residue return, by measuring inputs and outputs.The balance was near equilibrium for nitrogen (urea dressing, 120 kg N ha^–1 y^–1) and negative for calcium and magnesium. Leaching represented between 29% and 85% of the total output for nitrogen and accounted for practically all the calcium and magnesium outputs.In the upper horizons, nitrate, calcium and magnesium contents in the soil solution were correlated. This was interpreted as an exchange between the calcium and magnesium ions adsorbed on the soil and the protons released by the transformation of ammonium into nitrate. The nutrient content of the soil solution increased in the case of no potassium fertilization, probably because of a lower nitrogen immobilization by microorganisms, the crop residue yield being reduced by the induced deficiency. An insufficient potassium fertilization increases leaching losses of calcium, magnesium and nitrogen.In the deeper horizons, the nitrate content of the soil solution was not correlated with the calcium and magnesium contents. Nitrogen was probably taken up by roots and some calcium and magnesium ions exchanged during their transport through the soil.     

Soil N mineralization in a dairy production system with grass and forage crops

This paper describes the dynamics of soil N mineralization in the experimental intensive dairy farming system ‘De Marke’ on a dry sandy soil in the Netherlands. We hypothesized that knowledge of the effects of crop rotation on soil N mineralization and of the spatial and temporal variability of soil N mineralization in a farming system can be used to better synchronize N application with crop N requirements, and hence to increase the recovery of applied N and to reduce N losses. Soil N mineralization was recorded continuously in the soil layer 0–0.30 m, from 1992 to 2005, using a sequential in situ coring technique on six observation plots, of which two were located in permanent grassland and four in crop rotations with a 3 year grassland phase and an arable phase of 3 or 5 years, dominated by maize. Average annual soil N mineralization was highest under permanent grassland: 381 kg ha^?1 and lowest under ≥3rd years arable crops: 184 kg ha^?1. In temporary grassland, soil N mineralization increased in the order: 1st year, 2nd year, 3rd year grassland and in arable crops after grassland mineralization decreased in the order: 1st year, 2nd year, ≥3rd years. Total mineral N input, i.e. the sum of N mineralization and mineral N supply to soil, exceeded crop N requirements in 1st year maize and was lower than the requirements in 1st year temporary grassland. N mineralization in winter, outside the growing season, was 77 kg ha^?1 in maize and 60 kg ha^?1 in grassland. This points at the importance of a suitable catch crop to reduce the susceptibility to N leaching. Temporal and spatial variability of soil N mineralization was high and could not be related to known field conditions. This limits the extent to which N fertilization can be adjusted to soil N mineralization. Variability increased with the magnitude of soil N mineralization. Hence, situations with high soil N mineralization may be associated with high risks for N losses and to reduce these risks a strong build-up of soil organic N should be avoided. This might be achieved, for instance, by fermenting slurry before application on farmland to enhance the fraction mineral N in slurry at the expense of organic N.     

Comparing the effectiveness of radish cover crop, oilseed rape volunteers and oilseed rape residues incorporation for reducing nitrate leaching

The soil water and N dynamics have been studied during two long fallow periods (between wheat or oilseed rape and a spring crop) in a field experiment in Châlons-en-Champagne (eastern France, 48°50 N, 2°15 E). The experiment involved frequent measurements of soil water, soil mineral N, dry matter and N uptake by cover crops. Water and N budgets were established using Ritchie's model for calculating evapotranspiration in cropped soils and a model (LIXIM) for calculating water drainage, N leaching and N mineralisation in bare soils. During the first autumn and winter, a radish cover crop (grown from September 1994 to January 1995) was compared to a bare soil. During the second period (July 1995 to April 1996), a comparison was carried out between (i) oilseed rape volunteers, (ii) bare soil with two types of oilseed rape residues incorporated into the soil (R0 and R270 residues) and (iii) bare soil without residues incorporation. R0 and R270 residues came from two preceding oilseed rape crops which received two rates of N fertilizer (0 and 270 kg N ha^-1).Soil mineral N content was markedly reduced by the presence of radish cover crop or oilseed rape volunteers during autumn. The calculated actual evapotranspiration (AET) did not differ much between treatments, meaning that the transpiration by the cover crop or volunteers was relatively low (100–150 L kg^-1 of dry matter). Consequently, nitrate leaching was reduced during the rest of the winter and spring as well as nitrate concentration in the percolating water: 45 vs. 91 mg NO₃ ^- L^-1 for radish cover crop and bare soil, respectively. The incorporation of oilseed rape residues to soil also exerted a beneficial but smaller action on reducing the nitrate content in the soil. This effect was due to extra N immobilisation which reached a maximum of about 20 kg N ha^-1 in mid-autumn for both types of residues. Nine months after the incorporation of the oilseed rape residues, and comparing to the control soil without residues incorporation, N rich residues induced a significant positive N net effect (+ 9 kg N ha^-1) corresponding to 10% of N added whereas for N poor residues no net effect was still obtained at the end of experiment (–3 kg N ha^-1, not significantly different from 0).To reduce nitrate leaching during long fallow periods, it is necessary to promote techniques leading to decrease mineral-N contents in the soil during autumn before the drainage period, such as (i) residue incorporation after harvest (without fertiliser-N) and (ii) allowing volunteers to grow or sowing a cover crop just after the harvest of the last main crop.     

Direct and residual effect of liming on yield and nutrient uptake of maize (Zea mays L.) in moderately acid soils in the savanna zone of Nigeria

Field experiments were conducted during wet season of 1980, 1981 and 1982 to determine the direct and residual effect of liming on yield and nutrient uptake of maize in moderately acid soils (pH -H₂O; 5.0–5.4) at three locations viz Kontagora, Tumu and Yandev in the savanna zone of Nigeria. Maize crop was grown at five lime rates 0, 0.5, 1.0, 2.0 and 4.0 t ha^–1 and two N sources (calcium ammonium nitrate and urea). Liming at a rate of 2 t ha^–1 maintained high maize yield for three years after application at Kontagora and Yandev. At Tumu 1 t ha^–1 was sufficient to get high yield of maize for three years. Higher rates of lime significantly depressed yield. Uptake of N, P and K was increased significantly with lime application upto 2 t ha^–1 lime at Kontagora and Yandev but at Tumu it increased only upto 1 t ha^–1. The response of P uptake to liming was higher in comparison to N and K uptake. Calcium and magnesium uptake responded upto 4 t ha^–1 lime at Kontagora & Yandev and upto 2 t ha^–1 at Tumu. The residual effect of liming lasted longer than 2 years. High lime rates reduced maize yields and crop nutrient uptake.     

Effect of N-rates on dryland wheat in relation to mulching previous crop or fallow

In many rainfed areas a rainy season crop is followed by a post rainy season (rabi) crop and the yield of the latter is directly related to the profile-stored water at the time of its sowing. Mulching is known to help increase soil moisture storage. The yields of dryland crops are also limited by availability of nutrients, particularly nitrogen. We studied the effect of organic mulching in rainy season maize or fallow on the yield of maize and the yield and water use efficiency (WUE) of the following wheat fertilized with different rates of N.Mulching increased yield of maize by 9–12% and that of the following wheat by 25–28%. The increase in wheat yield with mulching in the previous crop of maize is attributable to greater residual moisture after maize particularly in the seed-zone and enrichment of soil with nutrients. In wheat following mulched maize, the yields with 0 and 40 kg N ha^–1 were comparable to those with 40 and 80 kg N ha^–1 in the absence of mulch. For a given N rate the yield of wheat was a function of available water supply. The yield increased with water supply up to a certain level beyond which it decreased with additional water supply. The threshold water supply and the corresponding yield increased with increase in N rate. Favourable effects of mulching in maize on the yield of wheat decreased with increase in water supply. The results suggest that to achieve optimum yield of wheat in double cropping the previous crop should be mulched and the N rate for wheat should be chosen in relation to available water supplies.     

Nitrogen response of maize under temporary flooding

The adverse effect of temporary flooding on maize (Zea mays L.) yields and the nitrogen management required to mitigate the effect of flooding were studied for five years in field experiments on Choa sandy loam soil.Maize yields decreased with increase in duration of flooding and with decrease in the age of the crop at the time of flooding. Flooding periods exceeding 48 hours caused significant crop damage. The loss in yield on account of flooding was, however, less in 40-day old crops. A 24 hours flooding decreased grain yield by 17.7 and 3.9 per cent in 20-day and 40-day old crops respectively. Maximum yield loss amounted to 1.23 t ha^–1 of grains with 72 hours of flooding of 20-day old crop indicating that a younger crop is more prone to the deleterious effect of flooding.The nitrogen content of grains decreased significantly with increase in flooding period. A supplemental dose of 7 kg N ha^–1 as urea spray significantly increased grain yield. Soil application of supplemental nitrogen at the rate of 14 or 20 kg N ha^–1 enhanced the maize yield by 0.7 to 0.9 t ha^–1 under temporary flooded conditions. Spraying with urea solution increased nitrogen removed by the crop.Successive increments of 60 kg N ha^–1 gave an additional yields of 1.23, 1.01 and 0.41 t ha^–1 over the crop that received no nitrogen. Flooded maize responded to even higher rates of N fertilization than the dose of 120 kg N ha^–1 which is recommended in this region.     

Nitrogen application and underground water contamination in some agricultural soils of South Western Nigeria

The effect of nitrogen fertilizer application on nitrate leaching and contamination of underground and surface waters in a continuously cropped lowland area of South Western Nigeria has indicated a high potential for nitrate leaching.It was estimated that with 100 kg N ha^–1 applied, as much as 29.5 kg N ha^–1 could be lost through leaching below the root zone of a maize crop, Over a 3 year period the applied nitrogen contributed to nitrate pollution of underground water significantly in excess of the maximum level accepted for potable water. This was particularly high in valley bottoms where the nitrate nitrogen content ranged from 12.8 to 24.6 mg L^–1. Contribution to adjacent stream was, however, not significant.     

Effect of climate change on greenhouse gas emissions from arable crop rotations

The DAISY soil–plant–atmosphere model was used to simulate crop production and soil carbon (C) and nitrogen (N) turnover for three arable crop rotations on a loamy sand in Denmark under varying temperature, rainfall, atmospheric CO₂ concentration and N fertilization. The crop rotations varied in proportion of spring sown crops and use of N catch crops (ryegrass). The effects on CO₂ emissions were estimated from simulated changes in soil C. The effects on N₂O emissions were estimated using the IPCC methodology from simulated amounts of N in crop residues and N leaching. Simulations were carried out using the original and a revised parameterization of the soil C turnover. The use of the revised model parameterization increased the soil C and N turnover in the topsoil under baseline conditions, resulting in an increase in crop N uptake of 11 kg N ha^–1 y^–1 in a crop rotation with winter cereals and a reduction of 16 kg N ha^–1 y^–1 in a crop rotation with spring cereals and catch crops. The effect of increased temperature, rainfall and CO₂ concentration on N flows was of the same magnitude for both model parameterizations. Higher temperature and rainfall increased N leaching in all crop rotations, whereas effects on N in crop residues depended on use of catch crops. The total greenhouse gas (GHG) emission increased with increasing temperature. The increase in total GHG emission was 66–234 kg CO₂-eq ha^–1 y^–1 for a temperature increase of 4°C. Higher rainfall increased total GHG emissions most in the winter cereal dominated rotation. An increase in rainfall of 20% increased total GHG emissions by 11–53 kg CO₂-eq ha^–1 y^–1, and a 50% increase in atmospheric CO₂ concentration decreased emissions by 180–269 kg CO₂-eq ha^–1 y^–1. The total GHG emissions increased considerably with increasing N fertilizer rate for a crop rotation with winter cereals, but remained unchanged for a crop rotation with spring cereals and catch crops. The simulated increase in GHG emissions with global warming can be effectively mitigated by including more spring cereals and catch crops in the rotation.     

Uptake of fertilizer and soil nitrogen by ryegrass swards during spring and mid-season

Double-labelled¹⁵N ammonium nitrate was used to determine the uptake of fertilizer and soil N by ryegrass swards during spring and mid-season. The effects of water stress (40% of mean rainfall v 25 mm irrigation per 25 mm soil water deficit) and the rate of application of N in the spring (40 v 130 kg ha^–1) on the recovery of 130 kg N ha^–1 applied in mid-season were also evaluated. Apparent recovery of fertilizer N (uptake of N in the fertilized plot minus that in the control expressed as a percentage of the N applied) was 95 and 79% for fertilizer N applied in the spring at rates of 40 and 130 kg ha^–1, respectively. Actual recovery of the fertilizer N assessed from the uptake of¹⁵N was only 31 and 48%, respectively. The uptake of soil N by the fertilized swards was substantially greater than that by the control. However, the increased uptake of soil N was always less than the amount of fertilizer N retained in or lost from the soil. Broadly similar patterns for the uptake of fertilizer and soil N were observed during mid-season. Uptake of N in mid-season was highest for swards which received 40 kg N ha^–1 in the spring and suffered minimal water stress during this period. Application of 130 kg N ha^–1 in spring reduced the uptake of N in mid-season to an extent similar to that arising from water stress. Only 1.8 to 4.2 kg ha^–1 (3 to 10%) of the N residual from fertilizer applied in the spring was recovered during mid-season. Laboratory incubation studies suggested that only a small part of the increased uptake of soil N by fertilized swards could be attributed to increased mineralisation of soil N induced by addition of fertilizer. It is considered that the increased uptake of soil N is partly real but mostly apparent, the latter arising from microbially mediated exchange of inorganic¹⁵N in the soil.