共查询到19条相似文献,搜索用时 265 毫秒
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磺酸盐阴离子表面活性剂具有原料来源广、合成成本低、粘弹性能好等优点,是油田广泛使用的表面活性剂。通过分析磺酸盐阴离子表面活性剂的影响因素,研究了无机盐、浓度、温度、助剂对于该表面活性剂的影响。利用实验分析了质量分数为4%磺酸盐阴离子表面活性剂DS10-2-10溶液在不同温度下的粘度、不同浓度下表面活性剂的粘度、加入1%和4%的NaCl时表面活性剂粘度的随着温度的变化和加入不同助剂,表面活性剂的粘度变化。通过研究不同因数对磺酸盐阴离子表面活性剂粘度的影响,为矿场中使用该表面活性剂提供实验指导。 相似文献
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表面活性剂对二氧化硅溶胶稳定性的影响 总被引:5,自引:3,他引:2
研究了表面活性剂对二氧化硅溶胶粘度和稳定性的影响.在二氧化硅溶胶中添加不同表面活性剂,测定了该混合体系的粘度变化和稳定性,结果表明阴离子表面活性剂可以降低硅溶胶的粘度,其CMC大约在4.6×10~(-3) mol/L左右,阴离子表面活性剂可以提高硅溶胶稳定性,极值为1.43×10~(-3) mol/L.表面活性剂SDBS对溶胶粘度的影响与其在溶胶颗粒上的包覆有关,SDBS对溶胶的稳定作用是由于SDBS胶束的形成,溶胶颗粒对SDBS的吸附会降低溶胶的稳定性.阴离子和非离子表面活性剂能提高二氧化硅溶胶稳定性,而阳离子表面活性剂会降低溶胶稳定性. 相似文献
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彭虹 《中国石油和化工标准与质量》2013,(11):41
制备了一种两性聚合物,利用粘度法、界面张力法研究了两性聚合物与阴离子表面活性剂在溶液中的相互作用。实验结果表明:随着表面活性剂的增加,聚合物溶液粘度先增加、再降低;同时,聚合物对阴离子表面活性剂的界面性能也有较大影响,聚合物的加入使表面活性剂降低油/水界面张力的能力增大,油/水界面张力达到平衡所需时间缩短。 相似文献
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本文通过实验方法,研究了碱、表面活性剂、聚合物三者浓度变化对界面张力、三元体系粘度、吸附量的影响规律和影响机理。研究表明,碱浓度的增加可以有效降低聚合物和表面活性剂的吸附量;随着碱浓度的不断增大,界面张力呈现出先增大后减小的趋势;随着碱浓度的增大,聚合物粘度呈现出先减小后增大的趋势,表面活性剂浓度的增大会使聚合物粘度不断增大,但两者对于溶液粘度的影响十分微小,基本可以忽略。 相似文献
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表面活性剂/大分子混合溶液的流变性 总被引:1,自引:0,他引:1
本报道了不同表面活性剂/大分子混合体系流变性随表面活性剂浓度的变化规律。离子型表面活性剂使非离子大分子表现出聚电解质的粘度行为,大分子的存在也可使棒状胶束转化为球状胶束,从而使粘度降低。 相似文献
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This study considered the stability and rheology of a type of high internal phase water-in-oil emulsions (W/O) emulsion. The aqueous phase of the emulsions is a super-cooled inorganic salt solution. The oil phase is a mixture of industrial grade oils and stabilizer. Instability of these systems manifests as crystallization of the metastable dispersed droplets with time. This work focused on the effects of oil polarity and oil viscosity on the stability of these emulsions. Ten types of industrial oils, covering the viscosity range 1.4–53.2?cP, and with varying polarity, were used in combination with polymeric poly(isobutylene) succinic anhydride (PIBSA) and sorbitan monooleate (SMO)-based surfactants. The effect of oil relative polarity on rheological parameters of the emulsion was evident mainly in the emulsions stabilized using polymeric surfactant, whereas the oil viscosity did not show any significant effect. The optimum stability of the emulsions stabilized with SMO was achieved using high polar oils with a viscosity of 3?±?0.5?cP. However, when using the PIBSA surfactant, the best emulsion stability was achieved with low polar, high viscosity oils. 相似文献
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Viscosity Reduction of Indian Heavy Crude Oil by Emulsification to O/W Emulsion Using Polysorbate-81
Pipeline transportation is the most convenient means of transportation of crude oil continuously and economically from production site to refinery. However, transportation of heavy crude oil (HCO) through pipelines is difficult due to its high viscosity. The high viscosity of heavy crude oil is mainly due to the presence of poly-aromatic compounds like resins and asphaltenes. Emulsification of HCO using surfactant is believed to be the most favorable technique to reduce the viscosity of HCO for efficient pipeline transport. In the present study, oil-in-water (O/W) emulsion has been formulated using a non-ionic surfactant Polyoxyethylene (5) sorbitan monooleate (PS-81) at different pH, surfactant concentration, and oil content. Box–Behnken response surface method has been used to optimize two responses, apparent viscosity and emulsion stability index (ESI). The optimal values of the parameters found are 75%v/v oil content, 2.5%w/v surfactant concentration, and pH value of 7 at which experimental value of emulsion viscosity is 0.2162 Pa·s, at 150 RPM, with a reduction of viscosity by 95.8% and having ESI of 98.16 after 24 h at 30°C. 相似文献
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Tomoko Sekine Katsunori Yoshida Fumiaki Matsuzaki Toshio Yanaki Michihiro Yamaguchi 《Journal of surfactants and detergents》1999,2(3):309-315
A stable formula using oil-in-water-in-oil (O/W/O) type multiple emulsions was investigated. The components consisted of hydrophilic
nonionic surfactant (HCO-60), organophilic montmorillonite, and lipophilic nonionic surfactant (DIS-14). O/W/O emulsions were
prepared by a double-step procedure in which an O/W emulsion was prepared in the first step, and then the O/W emulsion was
“re-emulsified” in an oil phase with organophilic montmorillonite. The diameter of the innermost oil droplets decreased with
increasing HCO-60 content (0.1–3%), while the viscosity showed a maximum at 1% of HCO-60, indicating that the yiel of re-emulsification
is highest at this condition. Viscosity of the O/W/O emulsion increased with increasing organophilic montmorillonite and DIS-14.
According to the results of a phase ratio study, viscosity and stability of the O/W/O emulsion decreased at high weight fraction
of inner oil phase (0.4–0.5), indicating that the excess amount of inner oil phase is absorbed by the outer oil phase. These
results revealed that the weight fraction of inner oil phase should be kept below 0.3 for a stable O/W/O emulsion. A similar
study on the weight fraction of O/W phase [фO/W)/O] suggested that the O/W/O emulsion is stable at ϕ(O/W)/O=0.65–0.70. 相似文献
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Surfactant is extensively used as chemicals during chemical enhanced oil recovery (CEOR) process. Effectiveness of surfactant CEOR process depends on several parameters like formation of micro emulsion, ultra-low interfacial tension (IFT) and adsorption of surfactant. First two parameters enhance the effectiveness while the last parameter reduces the effectiveness. Micro emulsions are highly desirable for CEOR due to its low interfacial tension (IFT) value and higher viscosity. In this research the size of the emulsions were studied with particle size analyzer to study the liquid–liquid absorption process and the entrapment of oil drops inside surfactant drop. Initially, the average surfactant drop size was found to be 100 nm, after mixing the surfactant slug with reservoir crude, the size was increase up to 10 times. It signifies the formation of micro emulsion between surfactant and oil. Another attempt was done in this research to study the adsorption mechanism of surfactant on reservoir rock. The process of adsorption was studied by Langmuir and Freundlich isotherm to understand the adsorption phenomena. In this study, it was found that the adsorption follows Freundlich isotherm and the adsorption phenomena was chemical for surfactant flooding process. In chemical adsorption phenomena, the rate of adsorption is high because, surfactant molecules are adsorbed layer after layer by the rock surface. Use of alkali along with surfactant reduces adsorption of surfactant since, alkali blocked the active clay sites before interacting with surfactant and hence the adsorption isotherm was found to be Langmuir and phenomena was physical adsorption. 相似文献
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The phase inversion of polymeric water‐in‐oil emulsions has been systematically studied by employing nonylphenol and alcohol ethoxylates with various chemistries as well as physical chemical characteristics. A combination of thermodynamics, phase diagrams, and rheometry were used to investigate the behavior of the inverting surfactants as well as the inverted, acrylamide‐based, cationic emulsions. Polymeric inverse‐emulsions containing the inverting surfactant showed no evidence of low‐shear thinning, though they did thin as hydrodynamic forces increased (0.01 to 100 s?1) prior to reaching a chemistry‐ and concentration‐independent plateau, as is typical for emulsions. The viscosity of emulsions containing inverting surfactants reached a minimum at 1.2% of the “emulsion breaker”. The efficiency of inversion was optimized at 2 wt % of nonylphenols, expressed as a percentage of the total emulsion mass, and increased with the degree of ethoxylation. Interestingly, the viscosity of the polymer inverted in water was maximized at an inverting‐surfactant level corresponding to the CMC of the pure surfactant in water. The alcohol ethoxylates required a higher concentration for inversion (3 wt %), though they provided a higher ultimate inverse viscosity of the polymeric emulsion in water. Therefore, while the inversion process was less efficient with alcohol ethoxylates, the ultimate dilution solution properties of the polyelectrolytes liberated were improved relative to the nonylphenols. Overall, the process of adding a water‐in‐oil emulsion, containing an emulsion breaker, to an excess of water involves a catastrophic inversion mechanism. To be effective under such circumstances, an inverting surfactant should have a partition coefficient between the aqueous an organic phases greatly exceeding unity as well as a hydrophilic–lipophilic balance (HLB) above 12. Effectiveness increases linearly with the partition coefficient. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 103: 3567–3584, 2007 相似文献