Time‐transgressive tunnel‐valley infill revealed by a three‐dimensional sedimentary model,Hamburg, north‐west Germany

Deep, elongated incisions, often referred to as tunnel valleys, are among the most characteristic landforms of formerly glaciated terrains. It is commonly thought that tunnel valleys were formed by meltwater flowing underneath large ice sheets. The sedimentary infill of these features is often highly intricate and therefore difficult to predict. This study intends to improve the comprehension of the sedimentology and to establish a conceptual model of tunnel‐valley infill, which can be used as a predictive tool. To this end, the densely sampled, Pleistocene tunnel valleys in Hamburg (north‐west Germany) were investigated using a dataset of 1057 deep wells containing lithological and geophysical data. The stratigraphic correlations and the resulting three‐dimensional lithological model were used to assess the spatial lithological distributions and sedimentary architecture. The sedimentary succession filling the Hamburg area tunnel valleys can be subdivided into three distinct units, which are distinguished by their inferred depositional proximity to the ice margin. The overall trend of the succession shows a progressive decrease in transport energy and glacial influence through time. The rate of glacial recession appears to have been an important control on the sedimentary architecture of the tunnel‐valley fill. During periods of stagnation, thick ice‐proximal deposits accumulated at the ice margin, while during rapid recession, only a thin veneer of such coarse‐grained sediments was deposited. Ice‐distal and non‐glaciogenic deposits (i.e. lacustrine, marine and terrestrial) fill the remaining part of the incision. The infill architecture suggests formation and subsequent infill of the tunnel valleys at the outer margin of the Elsterian ice sheet during its punctuated northwards recession. The proposed model shows how the history of ice‐sheet recession determines the position of coarse‐grained depocentres, while the post‐glacial history controls the deposition of fines through a progressive infill of remnant depressions.     

Grain‐size variability within a mega‐scale point‐bar system,False River,Louisiana

Point bars formed by meandering river systems are an important class of sedimentary deposit and are of significant economic interest as hydrocarbon reservoirs. Standard point‐bar models of how the internal sedimentology varies are based on the structure of small‐scale systems with little information about the largest complexes and how these might differ. Here a very large point bar (>25·0 m thick and 7·5 × 13·0 km across) on the Mississippi River (USA) was examined. The lithology and grain‐size characteristics at different parts of the point bar were determined by using a combination of coring and electrical conductivity logging. The data confirm that there is a general fining up‐section along most parts of the point bar, with a well‐defined transition from massive medium‐grained sands below about 9 to 11 m depth up into interbedded silts and fine–medium sand sediment (inclined heterolithic strata). There is also a poorly defined increase in sorting quality at the transition level. Massive medium sands are especially common in the region of the channel bend apex and regions upstream of that point. Downstream of the meander apex, there is much less evidence for fining up‐section. Finer sediment accumulated more readily after the establishment of a compound bar in the later stages of construction, at the terminal apex and in the bar tail. This work implies that the best reservoir sands are likely to be located in the centre of the point bar, deposited in a simple bar system. Reservoir quality decreases towards the bar edge. The early‐stage channel plug is largely composed of coarsening‐upward cycles of silt to clay and is dominated by clay and clayey silt material with poor reservoir characteristics.     

Transient solution for a plane‐strain fracture driven by a shear‐thinning,power‐law fluid

This paper analyses the problem of a fluid‐driven fracture propagating in an impermeable, linear elastic rock with finite toughness. The fracture is driven by injection of an incompressible viscous fluid with power‐law rheology. The relation between the fracture opening and the internal fluid pressure and the fracture propagation in mobile equilibrium are described by equations of linear elastic fracture mechanics (LEFM), and the flow of fluid inside the fracture is governed by the lubrication theory. It is shown that for shear‐thinning fracturing fluids, the fracture propagation regime evolves in time from the toughness‐ to the viscosity‐dominated regime. In the former, dissipation in the viscous fluid flow is negligible compared to the dissipation in extending the fracture in the rock, and in the later, the opposite holds. Corresponding self‐similar asymptotic solutions are given by the zero‐viscosity and zero‐toughness (J. Numer. Anal. Meth. Geomech. 2002; 26 :579–604) solutions, respectively. A transient solution in terms of the crack length, the fracture opening, and the net fluid pressure, which describes the fracture evolution from the early‐time (toughness‐dominated) to the large‐time (viscosity‐dominated) asymptote is presented and some of the implications for the practical range of parameters are discussed. Copyright © 2006 John Wiley & Sons, Ltd.     

Macro‐ and micro‐sedimentology of a modern melt‐out till – Matanuska Glacier,Alaska, USA

The macro‐ and micro‐sedimentology of a supraglacial melt‐out till forming at the Matanuska Glacier was examined in relationship to the properties of the stratified basal zone ice and debris from which it is originating. In situ melting of the basal ice has produced a laminated to bedded diamicton consisting mainly of silt. Macroscopic properties include: discontinuous laminae and beds; lenses of sand, silt aggregates and open‐work gravel; deformed and elongate clasts of clay; widely dispersed pebbles and cobbles, those that are prolate usually with their long axes subparallel to parallel to the bedding. Evidence for deformation is absent except for localized bending of beds over or under rock clasts. Microscopic properties are a unique element of this work and include: discontinuous lineations; silt to granule size laminae; prolate coarse sand and rock fragments commonly with their long axis subparallel to bedding; subangular to subrounded irregular shaped clay clasts often appearing as bands; sorted and unsorted silt to granule size horizons, sometimes disrupted by pore‐water pathways. Limited deformation occurs around rock clasts and thicker parts of lamina. This study shows that in situ melting of debris‐rich basal ice can produce a laminated and bedded diamicton that inherits and thereby preserves stratified basal ice properties. Production and preservation of supraglacial melt‐out till require in situ melting of a stagnant, debris‐rich basal ice source with a low relief surface that becomes buried by a thick, stable, insulating cover of ice‐marginal sediment. Also required are a slow melt rate and adequate drainage to minimize pore‐water pressures in the till and overlying sediment cover to maintain stability and uninterrupted deposition. Many modern and ancient hummocky moraines down glacier of subglacial overdeepenings probably meet these process criteria and their common occurrence suggests that both modern and pre‐modern supraglacial melt‐out tills may be more common than previously thought.     

Stratigraphic architecture of a tide‐influenced shelf‐edge delta,Upper Cretaceous Dorotea Formation,Magallanes‐Austral Basin,Patagonia

The Magallanes‐Austral Basin of Patagonian Chile and Argentina is a retroforeland basin associated with Late Cretaceous–Neogene uplift of the southern Andes. The Upper Cretaceous Dorotea Formation records the final phase of deposition in the Late Cretaceous foredeep, marked by southward progradation of a shelf‐edge delta and slope. In the Ultima Esperanza district of Chile, laterally extensive, depositional dip‐oriented exposures of the Dorotea Formation contain upper slope, delta‐front and delta plain facies. Marginal and shallow marine deposits include abundant indicators of tidal activity including inclined heterolithic stratification, heterolithic to sandy tidal bundles, bidirectional palaeocurrent indicators, flaser/wavy/lenticular bedding, heterolithic tidal flat deposits and a relatively low‐diversity Skolithos ichnofacies assemblage in delta plain facies. This work documents the stratigraphic architecture and evolution of the shelf‐edge delta that was significantly influenced by strong tidal activity. Sediment was delivered to a large slump scar on the shelf‐edge by a basin‐axial fluvial system, where it was significantly reworked and redistributed by tides. A network of tidally modified mouth bars and tidal channels comprised the outermost reaches of the delta complex, which constituted the staging area and initiation point for gravity flows that dominated the slope and deeper basin. The extent of tidal influence on the Dorotea delta also has important implications for Magallanes‐Austral Basin palaeogeography. Prior studies establish axial foreland palaeodrainage, long‐term southward palaeotransport directions and large‐scale topographic confinement within the foredeep throughout Late Cretaceous time. Abundant tidal features in Dorotea Formation strata further suggest that the Magallanes‐Austral Basin was significantly embayed. This ‘Magallanes embayment’ was formed by an impinging fold–thrust belt to the west and a broad forebulge region to the east.     

Kīlauea,Hawai’i,puts on a ‘once‐in‐a‐century’ show

Kīlauea is the youngest of five basaltic shield volcanoes on the island of Hawai’i. It is located to the south‐east of the much larger Mauna Loa volcano, and rose above sea level about 100 ka ago. Kīlauea is one of the most monitored, and arguably the best understood volcanoes on Earth, providing scientists with a good understanding of its current eruption, in which magma rises from depth and is stored beneath its 4 × 3.2 km summit caldera in an underground reservoir. The reservoir is connected to a lava lake within a crater called Halema’uma’u, which is situated on the floor of the caldera. When magma drains from the summit area it travels in underground conduits and emerges on the flanks of the volcano at a rift zone, where it erupts through fissures. The magma is sometimes stored in other reservoirs along the way. This link between summit magma storage and fissure eruptions on the flanks has occurred thousands of times at many Hawai’ian volcanoes. The current eruptive episode is, however, a ‘once‐in‐a‐century’ show, because it is the first time since 1924 that fissure‐fed lava flow eruptions have been accompanied by significant explosive eruptions within Halema’uma’u Crater. This gives scientists a unique opportunity to use modern methods to understand exactly how such hazardous explosions happen at Kīlauea, a volcano that receives about 2 million visitors a year.     

Petrogenesis of kyanite‐ and corundum‐bearing mafic granulite in a meta‐ophiolite,SE Turkey

Although ophiolitic rocks are abundant in Anatolia (Turkey), only in rare cases have they experienced high‐grade metamorphism. Even more uncommon, in Anatolia and elsewhere are high‐grade meta‐ophiolites that retain an oceanic lithosphere stratigraphy from upper crustal mafic volcanic rocks through lower crustal gabbro to mantle peridotite. The Berit meta‐ophiolite of SE Turkey exhibits both features: from structurally higher to lower levels, it consists of garnet amphibolite (metabasalt), granulite facies metagabbro (as lenses in amphibolite inferred to be retrogressed granulite) and metaperidotite (locally with metapyroxenite layers). Whole‐rock major and trace‐element data indicate a tholeiitic protolith that formed in a suprasubduction setting. This paper presents new results for the metamorphic P–T conditions and path of oceanic lower crustal rocks in the Berit meta‐ophiolite, and an evaluation of the tectonic processes that may drive granulite facies metamorphism of ophiolite gabbro. In the Do?an?ehir (Malatya, Turkey) region, granulite facies gabbroic rocks contain garnet (Grt)+clinopyroxene (Cpx)+plagioclase (Pl)+corundum (Crn)±orthopyroxene (Opx)±kyanite (Ky)±sapphirine (Spr)±rutile. Some exhibit symplectites consisting of Crn+Cpx, Ky+Cpx and/or coronas of garnet (outer shell) around a polygonal aggregate of clinopyroxene that in some cases surrounds a polygonal aggregate of orthopyroxene. Coronitic and non‐coronitic textures occur in proximity in mm‐ to cm‐scale layers; corona structures typically occur in plagioclase‐rich layers. Their formation is therefore related primarily to protolith type (troctolite v. gabbro) rather than P–T path. Phase diagrams calculated for a kyanite‐rich granulite, a plagioclase‐rich non‐coronitic granulite, and a plagioclase‐rich coronitic granulite (taking into account changes in effective bulk composition during texture development) predict peak conditions of ~800°C, 1.1–1.5 GPa; these conditions do not require invoking an unusually high geothermal gradient. In the coronitic metagabbro, reaction textures formed along the prograde path: Crn–Cpx symplectites grew at the expense of garnet, sapphirine and plagioclase. Peak conditions were followed by isobaric cooling of ~150°C. Hornblende–plagioclase thermometry results for host amphibolite (Hbl+Pl±Crn±Grt±relict Cpx) indicate retrograde conditions of 620–675°C and 0.5–0.8 GPa accompanied by infiltration of H₂O‐rich fluid. This anticlockwise P–T path differs from an isothermal decompression path previously proposed for these rocks based on the presence of symplectite. Metamorphism of the ophiolitic rocks was driven by closing of the southern Neotethys Ocean, as oceanic lithosphere was obducted (most SE Anatolian ophiolites) or underthrust (Berit meta‐ophiolite). This was followed by subduction of a continental margin, driving cooling of the Berit granulite after the thermal peak at depths of ~40 km.     

New Thorium Isotope Ratio Measurements in Silicate Reference Materials: A‐THO,AGV‐2, BCR‐2, BE‐N,BHVO‐2 and BIR‐1

A two‐step Th isolation protocol, involving micro‐columns of TRU‐Spec extraction chromatography material and AG1 resin, was evaluated. The MC‐ICP‐MS procedure included ²³²Th tailing characterisation and correction, and calibrator bracketing using an in‐house standard solution (ThS1) to correct for instrumental mass bias and Faraday cup to secondary electron multiplier relative gain. Repeated analyses of reference solutions (UCSC Th ‘A’, WUN, OU Th ‘U’, IRMM‐36) were consistent with published data. Six reference materials (A‐THO, BCR‐2, AGV‐2, BHVO‐2, BE‐N and BIR‐1) were processed. The average ²³⁰Th/²³²Th values obtained for these samples are in excellent agreement with published data. In addition, we report the first ²³⁰Th/²³²Th values for BE‐N and BIR‐1. The intermediate precisions for rock samples ranged from ± 0.24 to ± 0.49% (2 RSD) and were similar to those achieved for synthetic solutions, thereby supporting the overall validity of the chemical separation, data acquisition and reduction procedures. Counting statistics on the ²³⁰Th isotope was the most significant source of uncertainty. The intermediate precision of the mean ²³⁰Th/²³²Th for the Th‐depleted BIR‐1 (5.64 × 10^?6 ± 0.27%, 2 RSD) is in the range of the analyses of other reference materials analysed in this study.     

Downslope‐migrating sandwaves and platform‐margin clinoforms in a current‐dominated,distally steepened temperate‐carbonate ramp (Guadix Basin,Southern Spain)

During the Late Tortonian, platform‐margin‐prograding clinoforms developed at the south‐western margin of the Guadix Basin. Large‐scale wedge‐shaped deposits here comprise 26 rhythms of mixed carbonate–siliciclastic bedset packages and marl beds. These sediments were deposited on a shallow‐water, temperate‐carbonate distally steepened ramp. A downslope‐migrating sandwave field developed in this ramp, with sandwaves moving progressively down the ramp to the ramp‐slope, where they destabilized, folded and occasionally collapsed. Downslope sandwave migration was induced by currents flowing basinwards. During the Late Tortonian, the Guadix Basin was open north to the Atlantic Ocean via the Dehesas de Guadix Strait and connected east to the Mediterranean Sea through the Almanzora Corridor. According to the proposed current circulation model for the Guadix Basin for this time, surface marine currents from the Atlantic entered the basin from the northern seaway. These currents moved counter‐clockwise and shifted the sediment on the ramp, forming sandwaves that migrated downslope. The development of platform‐margin prograding clinoforms by the basinward sediment‐transport mechanisms inferred here is known relatively poorly in the ancient sedimentary record. Moreover, these wedge‐shaped geometries are similar to those found in some shelves in the Western Mediterranean Sea and could represent an outcrop analogue to (sub)‐recent, platform‐margin clinoforms revealed by high‐resolution seismic studies.     

Low‐pressure–high‐temperature metamorphism during extension in a Jurassic magmatic arc,Central Pontides,Turkey

Magmatic arcs are zones of high heat flow; however, examples of metamorphic belts formed under magmatic arcs are rare. In the Pontides in northern Turkey, along the southern active margin of Eurasia, high temperature–low pressure metamorphic rocks and associated magmatic rocks are interpreted to have formed under a Jurassic continental magmatic arc, which extends for 2800 km through the Crimea and Caucasus to Iran. The metamorphism and magmatism occurred in an extensional tectonic environment as shown by the absence of a regional Jurassic contractional deformation, and the presence of Jurassic extensional volcaniclastic marine basin in the Pontides, over 2 km in thickness, where deposition was coeval with the high‐T metamorphism at depth. The heat flow was focused during the metamorphism, and unmetamorphosed Triassic sequences crop out within a few kilometres of the Jurassic metamorphic rocks. The heat for the high‐T metamorphism was brought up to crustal levels by mantle melts, relicts of which are found as ultramafic, gabbroic and dioritic enclaves in the Jurassic granitoids. The metamorphic rocks are predominantly gneiss and migmatite with the characteristic mineral assemblage quartz + K‐feldspar + plagioclase + biotite + cordierite ± sillimanite ± garnet. Mineral equilibria give peak metamorphic conditions of 4 ± 1 kbar and 720 ± 40 °C. Zircon U–Pb and biotite Ar–Ar ages show that the peak metamorphism took place during the Middle Jurassic at c. 172 Ma, and the rocks cooled to 300 °C at c. 162 Ma, when they were intruded by shallow‐level dacitic and andesitic porphyries and granitoids. The geochemistry of the Jurassic porphyries and volcanic rocks has a distinct arc signature with a crustal melt component. A crustal melt component is also suggested by cordierite and garnet in the magmatic assemblage and the abundance of inherited zircons in the porphyries.     

Facies model of a mixed clastic–carbonate,wave‐dominated open‐coast tidal flat (Tithonian–Berriasian,north‐east Spain)

Detailed logging and analysis of the facies architecture of the upper Tithonian to middle Berriasian Aguilar del Alfambra Formation (Galve sub‐basin, north‐east Spain) have made it possible to characterize a wide variety of clastic, mixed clastic–carbonate and carbonate facies, which were deposited in coastal mudflats to shallow subtidal areas of an open‐coast tidal flat. The sedimentary model proposed improves what is known about mixed coastal systems, both concerning facies and sedimentary processes. This sedimentary system was located in an embayed, non‐protected area of a wide C‐shaped coast that was seasonally dominated by wave storms. Clastic and mixed clastic–carbonate muds accumulated in poorly drained to well‐drained, marine‐influenced coastal mudflat areas, with local fluvial sandstones (tide‐influenced fluvial channels and sheet‐flood deposits) and conglomerate tsunami deposits. Carbonate‐dominated tidal flat areas were the loci of deposition of fenestral‐laminated carbonate muds and grainy (peloidal) sediments with hummocky cross‐stratification. Laterally, the tidal flat was clastic‐dominated and characterized by heterolithic sediments with hummocky cross‐stratification and local tidal sandy bars. Peloidal and heterolithic sediments with hummocky cross‐stratification are the key facies for interpreting the wave (storm) dominance in the tidal flat. Subsidence and high rates of sedimentation controlled the rapid burial of the storm features and thus preserved them from reworking by fair‐weather waves and tides.     

Validation of a chrysophyte stomatocyst‐based cold‐season climate reconstruction from high‐Alpine Lake Silvaplana,Switzerland

For the reliable assessment of past climate variability, quantitative reconstructions of seasonal temperatures are required. Currently, reconstructions of cold‐season temperatures are scarce, because most biological proxies are biased towards the growing season. Here we test the potential of chrysophyte stomatocysts (or simply ‘cysts’; siliceous resting stages of the golden‐brown algae) as a proxy for cold‐season temperature. Climate reconstructions based on biological proxies are commonly constructed using transfer functions derived from calibration in space. However, the performance of these reconstructions is rarely tested by direct comparison with meteorological data due to limitations of sample resolution or chronological control. We compare a cyst‐based near‐annual reconstruction of ‘date of spring mixing’ from the varved sediments of Lake Silvaplana (Swiss Alps) spanning AD 1870–2004 with climate variables from the same period measured at the lake shore. The high correlation between cyst‐based ‘date of spring mixing’ and cold‐season temperature demonstrates the ability of chrysophyte cysts to archive cold‐season temperature variability. Lake eutrophication, which was extensive during the last 50 years, had no obvious effect on the cyst‐based reconstruction. This study underlines the high potential of chrysophyte cysts as a quantitative proxy for cold‐season climate reconstructions. Copyright © 2011 John Wiley & Sons, Ltd.     

Middle Pleistocene ice‐marginal sedimentation at a constrained ice‐sheet margin,East Anglia,UK

This paper presents a reconstruction of the marginal zone of the Anglian (Elsterian, 480–420 ka BP) age ice sheet in the Danbury‐Tiptree area, East Anglia, UK. The research area is a unique locality where the ice front abutted against a 30‐km‐long and 100‐m‐tall ridge in an otherwise lowland area. Observations from three main field localities (Danbury quarry, Royal Oak pit and Tiptree quarry) are complemented with ground penetrating radar survey data, borehole data analysis, laboratory analyses and geological map interpretation. A four‐stage model of the evolution of the landscape in the Danbury‐Tiptree area is presented. The results are of broader importance, in that the sedimentary record sheds light on the processes operating at a constrained ice‐sheet margin. The paper identifies the most important characteristics of the depositional environments at an ice front terminating within this type of setting: (i) high temporal and spatial variability of energetic depositional conditions, resulting in the presence of a vast array of distinct depositional sub‐environments; (ii) mechanisms promoting differential erosion leading to enhanced topography, and (iii) unusually high overburden pressure in the topographically constrained ice margin within the otherwise lowland area influencing the ice‐sheet–bedrock interaction in this particular research area, inducing postglacial seismicity.     

High‐Precision Sr‐Nd‐Hf‐Pb Isotopic Composition of Chinese Geological Standard Glass Reference Materials CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5 by MC‐ICP‐MS and TIMS

To assess the homogeneity of and provide the first Sr‐Nd‐Hf‐Pb isotopic reference values for the Chinese Geological Standard Glasses CGSG‐1, CGSG‐2, CGSG‐4 and CGSG‐5, we measured these isotopes in several measurement sessions over the course of nearly 3 years. The results were obtained by high‐precision MC‐ICP‐MS and TIMS. Our investigation indicates that these CGSG glass reference materials are homogenous with regard to Sr‐Nd‐Hf‐Pb isotopic distribution and are therefore suitable geochemical materials for Sr‐Nd‐Hf‐Pb isotope measurements. Clear differences in Sr‐Nd‐Hf‐Pb isotopic composition were observed between the glasses and the original powdered rock reference materials (CGSG‐2 and GSR‐7, and especially CGSG‐5 and GSR‐2) because of flux addition during preparation of the glasses. The new Sr‐Nd‐Hf‐Pb isotope data provided here might be useful to the geochemical community for in situ and bulk analysis.     

Warm‐temperate,marine, carbonate sedimentation in an Early Miocene,tide‐influenced,incised valley; Provence,south‐east France

The Saumane‐Venasque compound palaeovalley succession accumulated in a strongly tide‐influenced embayment or estuary. Warm‐temperate normal marine to brackish conditions led to deposition of extensive cross‐bedded biofragmental calcarenites. Echinoids, bryozoans, coralline algae, barnacles and benthic foraminifera were produced in seagrass meadows, on rocky substrates colonized by macroalgae and within subaqueous dune fields. There are two sequences, S1 and S2, the first of which contains three high‐frequency sequences (S1a, S1b and S1c). Sequence 1 is largely confined to the palaeovalley with its upper part covering interfluves. Each of these has a similar upward succession of deposits that includes: (i) a basal erosional surface that is bored and glauconitized; (ii) a discontinuous lagoonal lime mudstone or wackestone; (iii) a thin conglomerate generated by tidal ravinement; (iv) a transgressive systems tract series of cross‐bedded calcarenites; (v) a maximum flooding interval of argillaceous, muddy quartzose, open‐marine limestones; and (vi) a thin highstand systems tract of fine‐grained calcarenite. Tidal currents during stages S1a, S1b and S1c were accentuated by the constricted valley topography, whereas basin‐scale factors enhanced tidal currents during the deposition of S2. The upper part of the succession in all but S1c has been removed by later erosion. There is an overall upward temporal change with quartz, barnacles, encrusting corallines and epifaunal echinoids decreasing but bryozoans, articulated corallines and infaunal echinoids increasing. This trend is interpreted to be the result of changing oceanographic conditions as the valley was filled, bathymetric relief was reduced, rocky substrates were replaced as carbonate factories by seagrass meadows and subaqueous dunes, and the setting became progressively less confined and more open marine. These limestones are characteristic of a suite of similar cool‐water calcareous sand bodies in environments with little siliciclastic or fresh water input during times of high‐amplitude sea‐level change wherein complex inboard antecedent topography was flooded by a rising ocean.     

Metamorphic evolution of sapphirine‐ and orthoamphibole‐cordierite‐bearing gneiss,Okanogan dome,Washington, USA

Gneiss domes are commonly cored by quartzofeldspathic rocks that provide little information about the pressure–temperature–fluid history of the domes. Three northern Cordilleran migmatite domes (Thor‐Odin and Valhalla/Passmore, British Columbia, Canada; Okanogan, Washington, USA), however, contain Mg–Al‐rich orthoamphibole‐cordierite gneiss as layers and lenses that record metamorphic conditions and pressure–temperature (P–T) path information not preserved in the host migmatite. These Mg–Al‐rich rocks are therefore a valuable archive of metamorphic conditions during dome evolution, although refractory rocks such as these commonly contain reaction textures that may complicate the calculation of metamorphic conditions. In the Okanogan dome, Mg–Al‐rich layers are part of the Tunk Creek unit, which occurs at the periphery of an underlying migmatite domain. Bulk compositional layers (mm‐ to m‐scale) consist of gedrite‐dominated, hornblende‐dominated and biotite‐bearing layers that contain variable amounts of gedrite, hornblende, anorthite, cordierite, spinel, sapphirine, corundum, kyanite, biotite and/or staurolite. The presence of different compositional layers (some with reaction textures, some without) allows systematic analysis of metamorphic history by a combined petrographic and phase equilibrium analysis. Gedrite‐dominated layers containing relict kyanite preserve evidence of the highest‐P conditions; symplectitic and coronal reaction textures around kyanite indicate decompression at high temperature. Gedrite‐dominated layers lacking these reaction textures contain layers of sapphirine and spinel in apparent textural equilibrium and record a later high‐T–low‐P part of the path. Phase equilibria (pseudosection) analysis for layers that lack reaction textures indicates metamorphic conditions of 720–750 °C at a range of pressures (>8 to <4 kbar) following decompression. Elevated crustal temperatures and concordant structural fabrics in the Tunk Creek unit and underlying migmatite domain suggest that the calculated P–T conditions recorded in Tunk Creek rocks were coeval with anatexis, extension, and dome formation in Palaeocene–Eocene time. In contrast to orthoamphibole‐cordierite gneiss in the other Cordilleran domes, the Tunk Creek unit occurs as a discontinuous km‐scale layer rather than as smaller (m‐scale) pods, is more calcic, and lacks garnet. In addition, kyanite did not transform to sillimanite, and spinel commonly occurs as a blocky matrix phase in addition to vermicules in symplectite. These differences, along with the compositional layering, allow an analysis of bulk composition v. tectonic (P–T path) controls on mineral assemblages and textures. Pseudosection modelling of different layers in the Tunk Creek unit provides a basis for understanding the metamorphic history of these texturally complex, refractory rocks and their host gneiss domes, and other such rocks in similar tectonic settings.     

Metamorphic and tectonic evolution of a structurally continuous blueschist‐to‐Barrovian terrane,Sivrihisar Massif,Turkey

Metamorphic terranes comprised of blueschist facies and regional metamorphic (Barrovian) rocks in apparent structural continuity may represent subduction complexes that were partially overprinted during syn‐ to post‐subduction heating or may be comprised of unrelated tectonic slices. An excellent example of a composite blueschist‐to‐Barrovian terrane is the southern Sivrihisar Massif, Turkey. Late Cretaceous blueschist facies rocks are dominated by marble characterized by rod‐shaped calcite pseudomorphs after aragonite and interlayered with blueschist that contains eclogite and quartzite pods. Barrovian rocks, which have ⁴⁰Ar/³⁹Ar white mica ages that are >20 Myr younger than those of the blueschists, are also dominated by marble, but rod‐shaped calcite has been progressively recrystallized into massive marble within a ～200‐m transition zone. Barrovian marble is interlayered with quartzite and schist in which isograds are closely spaced and metamorphic conditions range from chlorite to sillimanite zone over ～1 km present‐day structural thickness. Andalusite, kyanite and prismatic sillimanite are present in muscovite‐rich quartzite; in one location, all three are in the same rock. Andalusite pre‐dates Barrovian metamorphism, kyanite is both pre‐ and syn‐Barrovian and sillimanite is entirely Barrovian. Muscovite with phengitic cores and relict kyanite in quartzite below the staurolite‐in isograd are evidence for pre‐Barrovian subduction metamorphism preserved at the low‐T end of the Barrovian domain; above the staurolite isograd, all evidence for subduction metamorphism has been erased. Some regional metamorphism may have occurred during exhumation, as indicated by syn‐kinematic high‐T minerals defining the fabric of L‐tectonite. Quartz microstructures in lineated quartzite reveal a strong constrictional fabric that may have formed in a transtensional bend in the plate boundary. Transtension accounts for the closely spaced isograds and development of a strong constrictional fabric during exhumation.     

Forty‐Nine Major and Trace Element Concentrations Measured in Soil Reference Materials NIST SRM 2586, 2587, 2709a, 2710a and 2711a Using ICP‐MS and Wavelength Dispersive‐XRF

Excellent agreement was noted in the concentration of major and trace elements in five NIST (National Institute for Science and Technology) soil reference materials (NIST SRM 2586, 2587, 2709a, 2710a and 2711a) between measurement results from wavelength dispersive‐XRF and ICP‐MS from two independent laboratories, and NIST certificate of analysis and literature data. We describe the variability in concentrations of up to forty‐nine elements (plus loss on ignition) and provide values for up to twenty‐one elements previously uncharacterised by NIST in these soil RMs. The additional characterisation provided in this investigation can be utilised to reduce the measurement bias of custom calibration routines and improve the quality of control checks developed using these NIST RMs.