The optical properties of the finest fraction of lunar soil: Implications for space weathering

Abstract— The fine fraction of lunar soils (<45 μm) dominates the optical properties of the bulk soil. Definite trends can be seen in optical properties of size separates with decreasing particle size: diminished spectral contrast and a steeper continuum slope. These trends are related to space weathering processes and their affects on different size fractions. The finest fraction (defined here as the <10 μm fraction) appears to be enriched in weathering products relative to the larger size fractions, as would be expected for surface correlated processes. This <10 μm fraction tends to exhibit very little spectral contrast, often with no distinguishable ferrous iron absorption bands. Additionally, the finest fractions of highland soils are observed to have very different spectral properties than the equivalent fraction of mare soils when compared with larger size fractions. The spectra of the finest fraction of feldspathic soils flatten at longer wavelengths, whereas those of the finest fraction of basaltic soils continue to increase in a steep, almost linear fashion. This compositional distinction is due to differences in the total amount of nanophase iron that accumulates in space weathering products. Such ground‐truth information derived from the <10 μm fraction of lunar soils provides valuable insight into optical properties to be expected in other space weathering environments such as the asteroids and Mercury.     

Atom probe tomography of space‐weathered lunar ilmenite grain surfaces

The surfaces of airless bodies, such as the Moon and asteroids, are subject to space weathering, which alters the mineralogy of the upper tens of nanometers of grain surfaces. Atom probe tomography (APT) has the appropriate 3‐D spatial resolution and analytical sensitivity to investigate such features at the nanometer scale. Here, we demonstrate that APT can be successfully used to characterize the composition and texture of space weathering products in ilmenite from Apollo 17 sample 71501 at near‐atomic resolution. Two of the studied nanotips sampled the top surface of the space‐weathered grain, while another nanotip sampled the ilmenite at about 50 nm below the surface. These nanotips contain small nanophase Fe particles (~3 to 10 nm diameter), with these particles becoming less frequent with depth. One of the nanotips contains a sequence of space weathering products, compositional zoning, and a void space (~15 nm in diameter) which we interpret as a vesicle generated by solar wind irradiation. No noble gases were detected in this vesicle, although there is evidence for ⁴He elsewhere in the nanotip. This lunar soil grain exhibits the same space weathering features that have been well documented in transmission electron microscope studies of lunar and Itokawa asteroidal regolith grains.     

On the origin of the lunar smooth-plains

Before the Apollo 16 mission, the material of the Cayley Formation (a lunar smooth plains) was theorized to be of volcanic origin. Because Apollo 16 did not verify such interpretations, various theories have been published that consider the material to be ejecta of distant multiringed basins. Results presented in this paper indicate that the material cannot be solely basin ejecta. If smoothplains are a result of formation of these basins or other distant large craters, then the plains materials are mainly ejecta of secondary craters of these basins or craters with only minor contributions of primary-crater or basin ejecta. This hypothesis is based on synthesis of knowledge of the mechanics of ejection of material from impact craters, photogeologic evidence, remote measurements of surface chemistry, and petrology of lunar samples. Observations, simulations, and calculations presented in this paper show that ejecta thrown beyond the continuous deposits of large lunar craters produce secondary-impact craters that excavate and deposit masses of local material equal to multiples of that of the primary crater ejecta deposited at the same place. Therefore, the main influence of a large cratering event on terrain at great distances from such a crater is one of deposition of more material by secondary craters, rather than deposition of ejecta from the large crater. Examples of numerous secondary craters observed in and around the Cayley Formation and other smooth plains are presented. Evidence is given for significant lateral transport of highland debris by ejection from secondary craters and by landslides triggered by secondary impact. Primary-crater ejecta can be a significant fraction of a deposit emplaced by an impact crater only if the primary crater is nearby. Other proposed mechanisms for emplacement of smooth-plains formations are discussed, and implications regarding the origin of material in the continuous aprons surrounding large lunar craters is considered. It is emphasized that the importance of secondary-impact cratering in the highlands has in general been underestimated and that this process must have been important in the evolution of the lunar surface.     

On the chronology of lunar origin and evolution

An origin of the Moon by a Giant Impact is presently the most widely accepted theory of lunar origin. It is consistent with the major lunar observations: its exceptionally large size relative to the host planet, the high angular momentum of the Earth–Moon system, the extreme depletion of volatile elements, and the delayed accretion, quickly followed by the formation of a global crust and mantle.According to this theory, an impact on Earth of a Mars-sized body set the initial conditions for the formation and evolution of the Moon. The impact produced a protolunar cloud. Fast accretion of the Moon from the dense cloud ensured an effective transformation of gravitational energy into heat and widespread melting. A “Magma Ocean” of global dimensions formed, and upon cooling, an anorthositic crust and a mafic mantle were created by gravitational separation.Several 100 million years after lunar accretion, long-lived isotopes of K, U and Th had produced enough additional heat for inducing partial melting in the mantle; lava extruded into large basins and solidified as titanium-rich mare basalt. This delayed era of extrusive rock formation began about 3.9 Ga ago and may have lasted nearly 3 Ga.A relative crater count timescale was established and calibrated by radiometric dating (i.e., dating by use of radioactive decay) of rocks returned from six Apollo landing regions and three Luna landing spots. Fairly well calibrated are the periods ≈4 Ga to ≈3 Ga BP (before present) and ≈0.8 Ga BP to the present. Crater counting and orbital chemistry (derived from remote sensing in spectral domains ranging from γ- and x-rays to the infrared) have identified mare basalt surfaces in the Oceanus Procellarum that appear to be nearly as young as 1 Ga. Samples returned from this area are needed for narrowing the gap of 2 Ga in the calibrated timescale. The lunar timescale is not only used for reconstructing lunar evolution, but it serves also as a standard for chronologies of the terrestrial planets, including Mars and possibly early Earth.The Moon holds a historic record of Galactic cosmic-ray intensity, solar wind composition and fluxes and composition of solids of any size in the region of the terrestrial planets. Some of this record has been deciphered. Secular mixing of the Sun was constrained by determining ³He/⁴He of solar wind helium stored in lunar fines and ancient breccias. For checking the presumed constancy of the impact rate over the past ≈3.1 Ga, samples of the youngest mare basalts would be needed for determining their radiometric ages.Radiometric dating and stratigraphy has revealed that many of the large basins on the near side of the Moon were created by impacts about 4.1 to 3.8 Ga ago. The apparent clustering of ages called “Late Heavy Bombardment (LHB)” is thought to result from migration of planets several 100 million years after their accretion.The bombardment, unexpectedly late in solar system history, must have had a devastating effect on the atmosphere, hydrosphere and habitability on Earth during and following this epoch, but direct traces of this bombardment have been eradicated on our planet by plate tectonics. Indirect evidence about the course of bombardment during this epoch on Earth must therefore come from the lunar record, especially from additional data on the terminal phase of the LHB. For this purpose, documented samples are required for measuring precise radiometric ages of the Orientale Basin and the Nectaris and/or Fecunditatis Basins in order to compare these ages with the time of the earliest traces of life on Earth.A crater count chronology is presently being built up for planet Mars and its surface features. The chronology is based on the established lunar chronology whereby differences between the impact rates for Moon and Mars are derived from local fluxes and impact energies of projectiles. Direct calibration of the Martian chronology will have to come from radiometric ages and cosmic-ray exposure ages measured in samples returned from the planet.     

Roughness of the lunar soil

In situ measurements at the lunar surface at millimeter resolution by the Apollo astronauts have been analyzed. Several statistical parameters have been determined for the landing site. The surface roughness has been found to be very nearly gaussian. The root-mean-square slopes have been obtained over scales between 0.5 mm and 5 cm. They steadily decrease with increasing scale length from 58° to 2° and are in reasonable agreement with radar-measured values. The autocorrelation coefficient of the height distribution has also been obtained. It has a scale-length of 0.7 mm.Adjunct Professor at the University of Massachusetts.Visiting Scholar at the University of Massachusetts.     

Heterogeneous agglutinitic glass and the fusion of the finest fraction (F3) model

Abstract— Evidence in favor of the model fusion of the finest fraction (F³) for the origin of lunar agglutinitic glass has been accruing. They include (1) theoretical expectations that shock pulses should engulf and melt smaller grains more efficiently than larger grains, (2) experimental results of impact shock, albeit at lower than presumed hypervelocity impacts of micrometeorites on the lunar regolith, and (3) new analyses confirming previous results that average compositions of agglutinitic glass are biased towards that of the finest fraction of lunar soils from which they had formed. We add another reason in support of the F³ model. Finer grains of lunar soils are also much more abundant. Hence, electrostatic forces associated with the rotating terminator region bring the finest grains that are obviously much lighter than courser grains to the surface of the Moon. This further contributes to the preferential melting of the finest fraction upon micrometeoritic impacts. New backscattered electron imaging shows that agglutinitic glass is inhomogeneous at submicron scale. Composition ranges of agglutinitic glass are extreme and deviate from that of the finest fraction, even by more than an order of magnitude for some components. Additionally, we show how an ilmenite grain upon impact would produce TiO₂‐rich agglutinitic glass in complete disregard to the requirements of fusion of the finest fraction. We propose an addition to the F³ model to accommodate these observations (i.e., that micrometeorite impacts indiscriminately melt the immediate target regardless of grain size or grain composition). We, therefore, suggest that (1) agglutinitic glass is the sum of (a) the melt produced by the fusion of the finest fraction of lunar soils and (b) the microvolume of the indiscriminate target, which melts at high‐shock pressures from micrometeoritic impacts, and that (2) because of the small volume of the melt and incorporating cold soil grains, the melt quenched so rapidly that it did not mix and homogenize to represent any preferential composition, for example, that of the finest fraction.     

Shear strength of lunar soil from oceanus procellarum

Soil from the scoop of Surveyor 3, returned to Earth by Apollo 12 astronauts, has been tested in a miniature shear box at five bulk densities, from 0.99 to 1.87 g cm^–3. Cohesion increased with bulk density from 3 × 10^–2 to 3 × 10^–1 N cm^–2; internal friction angle increased from 13° to 56°. Shear stress vs normal stress data fit a logarithmic relationship better than a linear one, at normal stresses of 3 × 10^–3 to 3 x 10⁰ N cm^–2. Results of these tests, in air, show no systematic differences from those for tests made elsewhere in vacuum and nitrogen. Results agree with those obtained in remotely controlled lunar surface operations with Surveyor 3 and other spacecraft provided that the bulk density was slightly underestimated for the on-surface measurements.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.This work represents one phase of research conducted at the Jet Propulsion Laboratory, California Institute of Technology, for the National Aeronautics and Space Administration, under Contract NAS 7-100.     

The origin of the shapes of lunar globules

This paper considers three hypotheses for the origin of the shapes of the regular elongated prolate and dumbbell-shaped lunar glass globules. These are the break-up of a jet, the vibration-freezing hypothesis and the rotational hypothesis. It is concluded that there are many results favouring the latter hypothesis so that its validity now appears conclusive. Applications of the hypothesis as a tool in lunar science are briefly discussed.     

On the origin of ancient lunar magnetic fields

The maximum value of possible lunar dynamo-field in our epoch is estimated in the scheme of precession dynamo model. In the light of our notions on the evolution of the Earth-Moon system this scheme may account for the size and character of ancient lunar fields that resulted in magnetization of surface lunar rocks, as well as for the absence of lunar dipole field of paleomagnetic origin in our epoch.     

Anatomy of individual agglutinates from a lunar highland soil

Abstract— We report results of our investigation of the relationship between values of I_s/FeO (relative concentration of nanophase Fe⁰ divided by total FeO content), glass abundance, total Fe content, and degree of digestion of <20 μm clasts for 22 individual agglutinates (250–1000 μm) from the mature Apollo 16 soil 61181 (I_s/FeO = 82 units in the <250 μm fraction). Agglutinates are important products of space weathering on the Moon, and they influence spectral observations at visible and near-IR wavelengths. Values of I_s/FeO for individual agglutinates (250–1000 μm) within this single soil span a range from 3 to 262 units which is larger than the range observed for all Apollo 16 bulk soils (～0 to 110 units). No correlation was observed between I_s/FeO and glass abundance and FeO concentrations for either agglutinitic glass or whole agglutinate particles under investigation. Our results suggest that the variation in I_s/FeO for agglutinates from a single soil may be in part a consequence of natural mixing processes on the Moon that produce highly-variable environments (with respect to surface exposure) for agglutinate formation and in part to variable kinetics of reactions in an agglutinate melt, which are influenced by a variety of factors including melt composition, temperature, impactor velocity, and quench rate. We cannot exclude but do not see evidence for other processes including addition of exotic agglutinates, micrometeoritic bombardment into compositionally-diverse microtargets, recycling of agglutinates, preferential melting of very fine soil particles, and production of nanophase Fe⁰ in amorphous rims of very fine irradiated lunar grains contributing to the observed variation of I_s/FeO.     

Boulder tracks and nature of lunar soil

Boulder tracks from 19 different locations on the Moon, observable in Lunar Orbiter photographs, have been examined. Measurements of the track width indicate that some of the boulders sank considerably deeper than others. It is suggested that lunar surface materials vary from place to place; the state of compaction (density of lunar soil) is probably one of the significant variables. Using bearing capacity theory, modified to be applicable to the rolling boulder problem by theoretical studies and extensive testing, the friction angle of the lunar soil was estimated. Most of the results were between 24 and 47 degrees with an arithmetic average of 37 degrees. These values suggest corresponding density variations of 1.25 to 2.00 g/cm³.     

Structural uplift and ejecta thickness of lunar mare craters: New insights into the formation of complex crater rims

We investigate the elevated crater rims of lunar craters. The two main contributors to this elevation are a structural uplift of the preimpact bedrock and the emplacement of ejecta on top of the crater rim. Here, we focus on five lunar complex mare craters with diameters ranging between 16 and 45 km: Bessel, Euler, Kepler, Harpalus, and Bürg. We performed 5281 measurements to calculate precise values for the structural rim uplift and the ejecta thickness at the elevated crater rim. The average structural rim uplift for these five craters amounts to S_RU = 70.6 ± 1.8%, whereas the ejecta thickness amounts to E_T = 29.4 ± 1.8% of the total crater rim elevation. Erosion is capable of modifying the ratio of ejecta thickness to structural rim uplift. However, to minimize the impact of erosion, the five investigated craters are young, pristine craters with mostly preserved ejecta blankets. To quantify how strongly craters were enlarged by crater modification processes, we reconstructed the dimensions of the transient crater. The difference between the transient crater diameter and the final crater diameter can extend up to 11 km. We propose reverse faulting and thrusting at the final crater rim to be one of the main contributing factors of forming the elevated crater rim.     

Petrology,chemistry, and isotopic compositions of the lunar highland regolith breccia Dar al Gani 262

Abstract— Lunar meteorite Dar al Gani 262 (DG 262)—found in the Libyan part of the Sahara—is a mature, anorthositic regolith breccia with highland affinities. The origin from the Moon is undoubtedly indicated by its bulk chemical composition; radionuclide concentrations; noble gas, N, and O isotopic compositions; and petrographic features. Dar al Gani 262 is a typical anorthositic highland breccia similar in mineralogy and chemical composition to Queen Alexandra Range (QUE) 93069. About 52 vol% of the studied thin sections of Dar al Gani 262 consist of fine-grained(100 μm) constituents, and 48 vol% is mineral and lithic clasts and impact-melt veins. The most abundant clast types are feldspathic fine-grained to microporphyritic crystalline melt breccias (50.2 vol%; includes recrystallized melt breccias), whereas mafic crystalline melt breccias are extremely rare (1.4 vol%). Granulitic lithologies are 12.8 vol%, intragranularly recrystallized anorthosites and cataclastic anorthosites are 8.8 and 8.2 vol%, respectively, and (devitrified) glasses are 2.7 vol%. Impact-melt veins (5.5 vol% of the whole thin sections) cutting across the entire thin section were probably formed subsequent to the lithification process of the bulk rock at pressures below 20 GPa, because the bulk rock never experienced a higher peak shock pressure. Mafic crystalline melt breccias are very rare in Dar al Gani 262 and are similar in abundance to those in QUE 93069. The extremely low abundance of mafic components and the bulk composition may constrain possible areas of the Moon from which the breccia was derived. The source area of Dar al Gani 262 must be a highland terrain lacking significant mafic impact melts or mare components. On the basis of radionuclide activities, an irradiation position of DG 262 on the Moon at a depth of 55–85 g/cm³and a maximum transit time to Earth <0.15 Ma is suggested. Dar al Gani 262 contains high concentrations of solar-wind-implanted noble gases. The isotopic abundance ratio ⁴⁰Ar/³⁶Ar < 3 is characteristic of lunar soils. The terrestrial weathering of DG 262 is reflected by the occurrence of fractures filled with calcite and by high concentrations of Ca, Ba, Cs, Br, and As. There is also a large amount of terrestrial C and some N in the sample, which was released at low temperatures during stepped heating. High concentrations of Ni, Co, and Ir indicate a significant meteoritic component in the lunar surface regolith from which DG 262 was derived.     

Integrated investigation of the mixed origin of lunar sample 72161,11

Sample 72161,11 (dark mantle at LRV-3) has a graphic mean grain size (M _z) of 3.88 ø, inclusive graphic standard deviation (σ _I) of 1.29, and a total carbon content of 204µg C g^?1 sample, and is, therefore, quite mature. However, the agglutinate content is only 30% in the 90–177µm particles, indicating an apparent departure from steady state. Analyses of C, CH₄, and H₂ concentrations in size fractions larger than 149µm show that the volume correlated component of these species increases with increasing grain size. In a homogeneous agglutinate population the volume correlated component is expected to be independent of grain size. The observed increase can be interpreted in terms of the mixing of a dominant local population of coarser agglutinates, with high carbon and hydrogen, with an imported population of finer agglutinates relatively poor in carbon and hydrogen. When analyses of size-fractions from the bulk sample are considered, these effects are apparently obliterated by the admixture of coarse-grained material low in agglutinates. It seems likely that this low agglutinate content is a consequence of the breakdown of the fragile, large agglutinates in the imported material during their movement to the sample site.     

The origin of young mare basalts inferred from lunar meteorites Northwest Africa 4734, 032, and LaPaz Icefield 02205

Northwest Africa (NWA) 4734 is an unbrecciated basaltic lunar meteorite that is nearly identical in chemical composition to basaltic lunar meteorites NWA 032 and LaPaz Icefield (LAP) 02205. We have conducted a geochemical, petrologic, mineralogic, and Sm‐Nd, Rb‐Sr, and Ar‐Ar isotopic study of these meteorites to constrain their petrologic relationships and the origin of young mare basalts. NWA 4734 is a low‐Ti mare basalt with a low Mg* (36.5) and elevated abundances of incompatible trace elements (e.g., 2.00 ppm Th). The Sm‐Nd isotope system dates NWA 4734 with an isochron age of 3024 ± 27 Ma, an initial ε_Nd of +0.88 ± 0.20, and a source region ¹⁴⁷Sm/¹⁴⁴Nd of 0.201 ± 0.001. The crystallization age of NWA 4734 is concordant with those of LAP 02205 and NWA 032. NWA 4734 and LAP 02205 have very similar bulk compositions, mineral compositions, textures, and ages. Their source region ¹⁴⁷Sm/¹⁴⁴Nd values indicate that they are derived from similar, but distinct, source materials. They probably do not sample the same lava flow, but rather are similarly sourced, but isotopically distinct, lavas that probably originate from the same volcanic complex. They may have experienced slightly different assimilation histories in route to eruption, but can be source‐crater paired. NWA 032 remains enigmatic, as its source region ¹⁴⁷Sm/¹⁴⁴Nd definitively precludes a simple relationship with NWA 4734 and LAP 02205, despite a similar bulk composition. Their high Ti/Sm, low (La/Yb)_N, and Cl‐poor apatite compositions rule out the direct involvement of KREEP. Rather, they are consistent with low‐degree partial melting of late‐formed LMO cumulates, and indicate that the geochemical characteristics attributed to urKREEP are not unique to that reservoir. These and other basaltic meteorites indicate that the youngest mare basalts originate from multiple sources, and suggest that KREEP is not a prerequisite for the most recent known melting in the Moon.     

Solar wind noble gases and nitrogen in metal from lunar soil 68501

Abstract Noble gases and N were analyzed in handpicked metal separates from lunar soil 68501 by a combination of step-wise combustions and pyrolyses. Helium and Ne were found to be unfractionated with respect to one another when normalized to solar abundances, for both the bulk sample and for all but the highest temperature steps. However, they are depleted relative to Ar, Kr and Xe by at least a factor of 5. The heavier gases exhibit mass-dependent fractionation relative to solar system abundance ratios but appear unfractionated, both in the bulk metal and in early temperature steps, when compared to relative abundances derived from lunar ilmenite 71501 by chemical etching, recently put forward as representing the abundance ratios in solar wind. Estimates of the contribution of solar energetic particles (SEP) to the originally implanted solar gases, derived from a basic interpretation of He and Ne isotopes, yield values of about 10%. Analysis of the Ar isotopes requires a minimum of 20% SEP, and Kr isotopes, using our preferred composition for solar wind Kr, yield a result that overlaps both of these values. It is possible to reconcile the data from these gases if significant loss of solar wind Ar, Kr and presumably Xe has occurred relative to the SEP component, most likely by erosive processes that are mass independent, although mass-dependent losses (Ar > Kr > Xe) cannot be excluded. If such losses did occur, the SEP contribution to the solar implanted gases must have been no more than a few percent. Nitrogen is a mixture of indigenous meteoritic N, whose isotopic composition is inferred to be relatively light, and implanted solar N, which has probably undergone diffusive redistribution and fractionation. If the heavy noble gases have not undergone diffusive loss, then N/Ar in the solar wind can be inferred to be at least several times the accepted solar ratio. The solar wind N appears, even after correction for fractionation effects, to have a minimum δ¹⁵N value ≥+150‰ and a more probable value ≥+200‰.     

Some aspects of the minor element chemistry of lunar mare basalts

The principal minor element (including Ti) characteristics of mare basalts which must be explained by an acceptable theory of petrogenesis are reviewed. Thes include: (i) Theabsolute abundances of incompatible elements vary over a twentyfold range yet therelative abundances within this group rarely deviate by more than a factor of two from the chondritic relative abundances. (ii) The sizes of the europium and strontium anomalies show a general trend to decrease as the absolute abundances of incompatible elements decrease. This trend is also one of increasing degree of partial melting and implies that the source region did not possess intrinsic Eu or Sr anomalies. (iii) Titanium seems to behave largely as an incompatible element. (iv) Many mare basalts have Rb/Sr model ages of about 4.5 b.y. whereas their crystallization ages are 3.2–3.8 b.y.Recent hypotheses have proposed that mare basalts formed by equilibrium partial melting of pyroxene-rich cumulates which underlay and were complementary to the anorthositic crust. According to a variant of this category, the residual liquid resulting from fractional crystallization of the highlands and their complementary cumulates segregated to form an intermediate layer between the highlands and the underlying primary cumulates. This highly fractionated residual liquid crystallized to form a pyroxene-olivine-ilmenite assemblage. High-Ti mare basalts subsequently formed by partial melting of this layer, whereas low-Ti basalts formed by partial melting of the underlying cumulates. These hypotheses are examined in detail and are rejected on several grounds.A new hypothesis based upon partial melting under conditions of surface or local equilibrium is proposed. It is assumed that the moon accreted from material which had ultimately formed by fractional condensation from a gas phase of appropriate composition. The essential members of the condensation sequence with falling temperature were perovskite, melilite, spinel, fassaite, forsterite, enstatite, alkali felspar. As the gas cooled over an extended period (>100 yr) large megacrysts (> 1 m) were formed. Trace elements were partitioned into these phases according to equilibrium condensation and crystal chemical relationships. Trivalent rare earths and other incompatible elements mainly entered perovskite, most of the Eu and Sr entered melilite whilst Rb entered alkali felspar. Radiogenic⁸⁷Sr thus produced remained within the alkali felspar. The moon accreted from a mixture of these condensates to form a disequilibrium mineral assemblagewith a bulk composition similar to that of the pyroxenite source region of mare basalts as derived from experimental petrological considerations. After heating deep in the lunar interior, solid state reaction occurred around megacryst boundaries to form an equilibrium pyroxenite containing large unreacted cores of refractory melilite and perovskite. The latter mineral readily forms low melting point liquids when in contact with pyroxenes whereas melilite remains relatively inert. As partial melting commenced, all the perovskite and other low-melting accessory minerals (eg. alk. felspar) entered the first batch of liquid which thereby received most of the incompatible elements and⁸⁷Sr (but not Eu and common Sr) present in the source region. Further melting of the pyroxenite matrix occurred under conditions of surface equilibrium. As the degree of partial melting increased, the first batch of incompatible-element-rich liquid was diluted by major elements from the pyroxenite matrix whilst refractory melilite cores were gradually consumed, thereby supplying relatively constant amounts of Eu and Sr to liquids so produced. It is considered that this model is capable of explaining the principal minor element characteristics of mare basalts and is consistent with interpretations of the major element chemistry of their source region based upon experimental petrology.     

On244Pu in lunar rocks from Fra Mauro and implications regarding their origin

The evidence forin situ produced fission xenon from²⁴⁴Pu in rock 14321 is presented. The inferred abundance ratio²⁴⁴Pu/²³⁸U is found to be consistent with values observed in a meteorite. Data from a stepwise release of the xenon permits a characterization of the trapped component, which can be shown to be distinct from solar xenon. We discuss the evidence for the presence of fission gases and of uncorrelated radiogenic argon in this and in other Apollo 14 rocks and some implications regarding their origin.Paper dedicated to Prof. Harold C. Urey on the occasion of his 80th birthday on 29 April 1973.