Some things we can infer about the Moon from the composition of the Apollo 16 regolith

Abstract— Characteristics of the regolith of Cayley plains as sampled at the Apollo 16 lunar landing site are reviewed and new compositional data are presented for samples of <1 mm fines (“soils”) and 1–2 mm regolith particles. As a means of determining which of the many primary (igneous) and secondary (crystalline breccias) lithologic components that have been identified in the soil are volumetrically important and providing an estimate of their relative abundances, more than 3 × 10⁶ combinations of components representing nearly every lithology that has been observed in the Apollo 16 regolith were systematically tested to determine which combinations best account for the composition of the soils. Conclusions drawn from the modeling include the following. At the site, mature soil from the Cayley plains consists of 64.5% ± 2.7% components representing “prebasin” materials: anorthosites, feldspathic breccias, and a small amount (2.6% ± 1.5% of total soil) of nonmare, mafic plutonic rocks, mostly gabbronorites. On average, these components are highly feldspathic, with average concentrations of 31–32% Al₂O₃ and 2–3% FeO and a molar Mg/(Mg + Fe) ratio of 0.68. The remaining 36% of the regolith is syn- and postbasin material: 28.8% ± 2.4% mafic impact-melt breccias (MIMBs, i.e., “LKFM” and “VHA basalts”) created at the time of basin formation, 6.0% ± 1.4% mare-derived material (impact and volcanic glass, crystalline basalt) with an average TiO₂ concentration of 2.4%, and 1% postbasin meteoritic material. The MIMBs are the principal (80–90%) carrier of incompatible trace elements (rare earths, Th, etc.) and the carrier of about one-half of the siderophile elements and elements associated with mafic mineral phases (Fe, Mg, Mn, Cr, Sc). Most (71%) of the Fe in the present regolith derives from syn- and postbasin sources (MIMBs, mare-derived material, and meteorites). Thus, although the bulk composition of the Apollo 16 regolith is nominally that of noritic anorthosite, the noritic part (the MIMBs) and the anorthositic part (the prebasin components) are largely unrelated. There is compositional evidence that 3–4% of the soil is Th-rich material such as that occurring at the Apollo 14 site, and one fragment of this type was found among the small regolith particles studied here. If regolith such as that represented by the Apollo 16 ancient regolith breccias was a protolith of the present regolith, such regolith cannot exceed ～71% of the present regolith; the rest must be material added or redistributed since closure of the ancient regolith breccias. The postclosure material includes the mare-derived material and the Apollo-14-like component. Compositions of all mature surface soils from Apollo 16, even those collected 4 km apart on the Cayley plains, are very similar, which is in stark contrast to the wide compositional range of the lithologies of which the soil is composed. This uniformity indicates that the ratio of MIMBs to feldspathic prebasin components is not highly variable in the megaregolith over distances of a few kilometers, that there are no large, subsurface concentrations of “pure” mafic impact-melt breccia, and that the intimate mixing is inherent to the Cayley plains at a gross scale. Thus, the mixing of mafic impact-melt breccias and feldspathic prebasin components must have occurred during formation and deposition of the Cayley plains; such uniformity could not have been achieved by small postdeposition impacts into a stratified megaregolith. Using this conclusion as one constraint, and the known distribution of Th on the lunar surface as another, and the assumption that the Imbrium impact is primarily responsible for formation of the Cayley plains, arguments are presented that the Apollo 16 MIMBs derive from the Imbrium region, and, consequently, that one-fourth of the Apollo 16 regolith is primary Imbrium ejecta in the form of mafic impact-melt breccias.     

Origin and history of chondrite regolith,fragmental and impact-melt breccias from Spain

Abstract— Six ordinary chondrite breccias from the Museo Nacional de Ciencias Naturales, Madrid (Spain), are described and classified as follows: the solar gas-rich regolith breccia Oviedo (H5); the pre-metamorphic fragmental breccias Cabezo de Mayo (type 6, L-LL), and Sevilla (LL4); the fragmental breccias Cañellas (H4) and Gerona (H5); and the impact melt breccia, Madrid (L6). We confirm that chondrites with typical light-dark structures and petrographic properties typical of regolith breccias may (Oviedo) or may not (Cañellas) be solar gas-rich. Cabezo de Mayo and Sevilla show convincing evidence that they were assembled prior to peak metamorphism and were equilibrated during subsequent reheating. These meteorites contain small melt rock clasts that were incorporated into the host chondrite while still molten and/or plastic and cooled rapidly and, yet, are totally equilibrated with their hosts. Compositions of olivine and low-Ca pyroxene in host chondrite and breccia clasts in Cabezo de Mayo are transitional between groups L and LL. It is suggested, based on mineralogic and oxygen isotopic compositions of host and clasts, that the rock formed on the L parent body by mixing, prior to peak metamorphism. This was followed by partial equilibration of two different materials: the indigenous L chondrite host and exotic LL melt rock clasts.     

Chronology of dimict breccias and the age of South Ray crater at the Apollo 16 site

Abstract— We report the noble gas isotopic abundances of five dimict breccias and one cataclastic anorthosite that were collected at the Apollo 16 landing site. Orbital and surface photographs indicate that rays from South Ray crater, an almost 1 km wide young crater in the Cayley plains, extend several kilometers from their source into the area that was sampled by the Apollo 16 mission. Previous studies have shown that South Ray crater formed 2 Ma ago and that a large number of rocks might originate from this cratering event. On the basis of cosmic-ray produced nuclei, we find that the six rocks investigated in this work yield the same lunar surface exposure age. Using literature data, we recalculate the exposure ages of additional 16 rocks with suspected South Ray crater origin and obtain an average exposure age of 2.01 ± 0.10 Ma. In particular, all nine dimict breccias (a type of rock essentially restricted to the Apollo 16 area consisting of anorthosite and breccia phases) dated until now yield an average ejection age of 2.06 ± 0.17 Ma. We conclude that they must originate from the Cayley formation or from bedrock underlying the Cayley plain. We determined the gas retention ages for the dimict breccias based on the ⁴⁰K-⁴⁰Ar and U,Th-¹³⁶Xe dating methods: rock 64425 yields a ⁴⁰K-⁴⁰Ar age of 3.96 Ga and rock 61016 a U,Th-¹³⁶Xe age of 3.97 Ga. These results, together with ³⁹Ar-⁴⁰Ar ages obtained by other workers for rocks 64535 (3.98 Ga) and 64536 (3.97 Ga), show that the dimict breccias formed 3.97 Ga ago.     

Lunar meteorite regolith breccias: An in situ study of impact melt composition using LA‐ICP‐MS with implications for the composition of the lunar crust

Dar al Gani (DaG) 400, Meteorite Hills (MET) 01210, Pecora Escarpment (PCA) 02007, and MacAlpine Hills (MAC) 88104/88105 are lunar regolith breccia meteorites that provide sampling of the lunar surface from regions of the Moon that were not visited by the US Apollo or Soviet Luna sample return missions. They contain a heterogeneous clast population from a range of typical lunar lithologies. DaG 400, PCA 02007, and MAC 88104/88105 are primarily feldspathic in nature, and MET 01210 is composed of mare basalt material mixed with a lesser amount of feldspathic material. Here we present a compositional study of the impact melt and impact melt breccia clast population (i.e., clasts that were generated in impact cratering melting processes) within these meteorites using in situ electron microprobe and LA‐ICP‐MS techniques. Results show that all of the meteorites are dominated by impact lithologies that are relatively ferroan (Mg#_<70), have high Sc/Sm ratios (typically >10), and have low incompatible trace element (ITE) concentrations (i.e., typically <3.2 ppm Sm, <1.5 ppm Th). Feldspathic impact melt in DaG 400, PCA 02007, and MAC 88104/05 are similar in composition to that estimated composition for upper feldspathic lunar crust ( Korotev et al. 2003 ). However, these melt types are more mafic (i.e., less Eu, less Sr, more Sc) than feldspathic impact melts returned by the Apollo 16 mission (e.g., the group 3 and 4 varieties). Mafic impact melt clasts are common in MET 01210 and less common in PCA 02007 and MAC 88104/05. We show that unlike the Apollo mafic impact melt groups ( Jolliff 1998 ), these meteorite impact melts were not formed from melting large amounts of KREEP‐rich (typically >10 ppm Sm), High Magnesium Suite (typically >70 Mg#) or High Alkali Suite (high ITEs, Sc/Sm ratios <2) target rocks. Instead the meteorite mafic melts are more ferroan, KREEP‐poor and Sc‐rich, and represent mixing between feldspathic lithologies and low‐Ti or very low‐Ti (VLT) basalts. As PCA 02007 and MAC 88104/05 were likely sourced from the Outer‐Feldspathic Highlands Terrane our findings suggest that these predominantly feldspathic regions commonly contain a VLT to low‐Ti basalt contribution.     

The petrology,geochemistry, and age of lunar regolith breccias Miller Range 090036 and 090070: Insights into the crustal history of the Moon

Meteorites ejected from the surface of the Moon as a result of impact events are an important source of lunar material in addition to Apollo and Luna samples. Here, we report bulk element composition, mineral chemistry, age, and petrography of Miller Range (MIL) 090036 and 090070 lunar meteorites. MIL 090036 and 090070 are both anorthositic regolith breccias consisting of mineral fragments and lithic clasts in a glassy matrix. They are not paired and represent sampling of two distinct regions of the lunar crust that have protoliths similar to ferroan anorthosites. ⁴⁰Ar‐³⁹Ar chronology performed on two subsplits of MIL 090070,33 (a pale clast impact melt and a dark glassy melt component) shows that the sample underwent two main degassing events, one at ~3.88 Ga and another at ~3.65 Ga. The cosmic ray exposure data obtained from MIL 090070 are consistent with a short (~8–9 Ma) exposure close to the lunar surface. Bulk‐rock FeO, TiO₂, and Th concentrations in both samples were compared with 2‐degree Lunar Prospector Gamma Ray Spectrometer (LP‐GRS) data sets to determine areas of the lunar surface where the regolith matches the abundances observed on the sample. We find that MIL 090036 bulk rock is compositionally most similar to regolith surrounding the Procellarum KREEP Terrane, whereas MIL 090070 best matches regolith in the feldspathic highlands terrane on the lunar farside. Our results suggest that some areas of the lunar farside crust are composed of ferroan anorthosite, and that the samples shed light on the evolution and impact bombardment history of the ancient lunar highlands.     

On the origin of shocked and unshocked CM clasts in H‐chondrite regolith breccias

Abstract— CM chondrite clasts that have experienced different degrees of aqueous alteration occur in H‐chondrite and HED meteorite breccias. Many clasts are fragments of essentially unshocked CM projectiles that accreted at low relative velocities to the regoliths of these parent bodies. A few clasts were heated and dehydrated upon impact; these objects most likely accreted at higher relative velocities. We examined three clasts and explored alternative scenarios for their formation. In the first scenario, we assumed that the H and HED parent bodies had diameters of a few hundred kilometers, so that their high escape velocities would effectively prevent soft landings of small CM projectiles. This would imply that weakly shocked CM clasts formed on asteroidal fragments (family members) associated with the H and HED parent bodies. In the second scenario, we assumed that weakly shocked CM clasts were spall products ejected at low velocities from larger CM projectiles when they slammed into the H and HED parent bodies. In both cases, if most CM clasts turn out to have ancient ages (e.g., ?3.4‐4.1 Ga), a plausible source for their progenitors would be outer main belt objects, some which may have been dynamically implanted 3.9 Ga ago by the events described in the so‐called “Nice model.” On the other hand, if most CM clasts have recent ages (<200 Ma), a plausible source location for their parent body would be the inner main belt between 2.1–2.2 AU. In that case, the possible source of the CM‐clasts' progenitors' parent fragments would be the breakup ?160 Ma ago of the parent body 170 km in diameter of the Baptistina asteroid family (BAF).     

Ultra‐reduced phases in Apollo 16 regolith: Combined field emission electron probe microanalysis and atom probe tomography of submicron Fe‐Si grains in Apollo 16 sample 61500

The lunar regolith contains a variety of chemically reduced phases of interest to planetary scientists and the most common, metallic iron, is generally ascribed to space weathering processes (Lucey et al. 2006 ). Reports of silicon metal and iron silicides, phases indicative of extremely reducing conditions, in lunar samples are rare (Anand et al. 2004 ; Spicuzza et al. 2011 ). Additional examples of Fe‐silicides have been identified in a survey of particles from Apollo 16 sample 61501,22. Herein is demonstrated the utility of low keV electron probe microanalysis (EPMA), using the Fe Ll X‐ray line, to analyze these submicron phases, and the necessity of accounting for carbon contamination. We document four Fe‐Si and Si⁰ minerals in lunar regolith return material. The new Fe‐Si samples have a composition close to (Fe,Ni)₃Si, whereas those associated with Si⁰ are close to FeSi₂ and Fe₃Si₇. Atom probe tomography of (Fe,Ni)₃Si shows trace levels of C (60 ppma and nanodomains enriched in C, Ni, P, Cr, and Sr). These reduced minerals require orders of magnitude lower oxygen fugacity and more reducing conditions than required to form Fe⁰. Documenting the similarities and differences in these samples is important to constrain their formation processes. These phases potentially formed at high temperatures resulting from a meteorite impact. Whether carbon played a role in achieving the lower oxygen fugacities—and there is evidence of nearby carbonaceous chondritic material—it remains to be proven that carbon was the necessary component for the unique existence of these Si⁰ and iron silicide minerals.     

“New” lunar meteorites: Impact melt and regolith breccias and large‐scale heterogeneities of the upper lunar crust

Abstract— We have analyzed nine highland lunar meteorites (lunaites) using mainly INAA. Several of these rocks are difficult to classify. Dhofar 081 is basically a fragmental breccia, but much of its groundmass features a glassy‐fluidized texture that is indicative of localized shock melting. Also, much of the matrix glass is swirly‐brown, suggesting a possible regolith derivation. We interpret Dar al Gani (DaG) 400 as an extremely immature regolith breccia consisting mainly of impact‐melt breccia clasts; we interpret Dhofar 026 as an unusually complex anorthositic impact‐melt breccia with scattered ovoid globules that formed as clasts of mafic, subophitic impact melt. The presence of mafic crystalline globules in a lunar material, even one so clearly impact‐heated, suggests that it may have originated as a regolith. Our new data and a synthesis of literature data suggest a contrast in Al₂O₃‐incompatible element systematics between impact melts from the central nearside highlands, where Apollo sampling occurred, and those from the general highland surface of the Moon. Impact melts from the general highland surface tend to have systematically lower incompatible element concentration at any given Al₂O₃ concentration than those from Apollo 16. In the case of Dhofar 026, both the bulk rock and a comparatively Al‐poor composition (14 wt% Al₂O₃, 7 μg/g Sm) extrapolated for the globules, manifest incompatible element contents well below the Apollo 16 trend. Impact melts from Luna 20 (57°E) distribute more along the general highland trend than along the Apollo 16 trend. Siderophile elements also show a distinctive composition for Apollo 16 impact melts: Ni/Ir averaging ?1.8x chondritic. In contrast, lunaite impact‐melt breccias have consistently chondritic Ni/Ir. Impact melts from Luna 20 and other Apollo sites show average Ni/Ir almost as high as those from Apollo 16. The prevalence of this distinctive Ni/Ir ratio at such widely separated nearside sites suggests that debris from one extraordinarily large impact may dominate the megaregolith siderophile component of a nearside region 2300 km or more across. Highland polymict breccia lunaites and other KREEP‐poor highland regolith samples manifest a strong anticorrelation between Al₂O₃ and mg. The magnesian component probably represents the chemical signature of the Mg‐suite of pristine nonmare rocks in its most “pure” form, unaltered by the major KREEP‐assimilation that is so common among Apollo Mg‐suite samples. The average composition of the ferroan anorthositic component is now well constrained at Al₂O₃ ?29–30 wt% (implying about 17–19 wt% modal mafic silicates), in good agreement with the composition predicted for flotation crust over a “ferroan” magma ocean (Warren 1990).     

Apollo 17 regolith, 71501,262: A record of impact events and mare volcanism in lunar glasses

Abstract— Thirteen glasses from Apollo 17 regolith 71501,262 have been chemically analyzed by electron microprobe and isotopically dated with the ⁴⁰Ar/³⁹Ar dating method. We report here the first isotopic age obtained for the Apollo 17 very low titanium (VLT) volcanic glasses, 3630 ± 40 Ma. Twelve impact glasses that span a wide compositional range have been found to record ages ranging from 102 ± 20 Ma to 3740 ± 50 Ma. The compositions of these impact glasses show that some have been produced by impact events within the Apollo 17 region, whereas others appear to be exotic to the landing site. As the data sets that include compositions and ages of lunar impact glasses increase, the impact history in the Earth‐Moon system will become better constrained.     

Searching for nonlocal lithologies in the Apollo 12 regolith: A geochemical and petrological study of basaltic coarse fines from the Apollo lunar soil sample 12023,155

New data from a petrological and geochemical examination of 12 coarse basaltic fines from the Apollo 12 soil sample 12023,155 provide evidence of additional geochemical diversity at the landing site. In addition to the bulk chemical composition, major, minor, and trace element analyses of mineral phases are employed to ascertain how these samples relate to the Apollo 12 lithological basalt groups, thereby overcoming the problems of representativeness of small samples. All of the samples studied are low‐Ti basalts (0.9–5.7 wt% TiO₂), and many fall into the established olivine, pigeonite, and ilmenite classification of Apollo 12 basaltic suites. There are five exceptions: sample 12023,155_1A is mineralogically and compositionally distinct from other Apollo 12 basalt types, with low pigeonite REE concentrations and low Ni (41–55 ppm) and Mn (2400–2556 ppm) concentrations in olivine. Sample 12023,155_11A is also unique, with Fe‐rich mineral compositions and low bulk Mg# (=100 × atomic Mg/[Mg+Fe]) of 21.6. Sample 12023,155_7A has different plagioclase chemistry and crystallization trends as well as a wider range of olivine Mg# (34–55) compared with other Apollo 12 basalts, and shows greater similarities to Apollo 14 high‐Al basalts. Two other samples (12023,155_4A, and _5A) are similar to the Apollo 12 feldspathic basalt 12038, providing additional evidence that feldspathic basalts represent a lava flow proximal to the Apollo 12 site rather than material introduced by impacts. We suggest that at least one parent magma, and possibly as many as four separate parent magmas, are required in addition to the previously identified olivine, pigeonite, and ilmenite basaltic suites to account for the observed chemical diversity of basalts found in this study.     

“New” lunar meteorites: Implications for composition of the global lunar surface,lunar crust,and the bulk Moon

Abstract— New data for lunar meteorites and a synthesis of literature data have significant implications for the interpretation of global Th data and for the Moon's bulk composition. As presently calibrated (Prettyman et al. 2002), the Lunar Prospector gamma‐ray data imply that the average global surface Th = 1.58 μg/g. However, that calibration yields implausibly high concentrations for the three most Th‐poor documented sampling sites, it extrapolates to a nonzero Lunar Prospector Th, ?0.7 μg/g, at zero sample Th, and it results in a misfit toward too‐high Th when compared with the global regolith Th spectrum as constrained using mainly lunaite regolith breccias. Another problem is manifested by Th versus K systematics. Ground truth data plot consistently to the high‐Th/K side of the Prospector data trend, offset by a factor of 1.2. A new calibration is proposed that represents a compromise between the Th levels indicated by ground truth constraints and the Prettyman et al. (2002) calibration. Conservatively assuming that the Th versus K issue is mostly a K problem, the average global surface Th is estimated to be ?1.35 μg/g. The Moon's remarkable global asymmetry in KREEP abundance is even more pronounced than previously supposed. The surface Th concentration ratio between the hemisphere antipodal to the Procellarum basin and the hemisphere centered on Procellarum is reduced to 0.24 in the new calibration. This extreme disparity is most simply interpreted as a consequence of Procellarum's origin at a time when the Moon still contained at least a thin residual layer of a global magma ocean. Allowing for diminution of Th with depth, the extrapolated bulk crustal Th is ?0.73 μg/g. Further extrapolation to bulk Moon Th yields ?0.07 μg/g, which is nearly identical to the consensus estimate for Earth's primitive mantle. Assuming chondritic proportionality among refractory lithophile elements implies Al₂O₃ of approximately 3.8 wt%. The Moon's bulk mantle mg ratio is only weakly constrained by seismic and mare‐basaltic data. KREEP‐and mare‐free lunaite regolith samples, other thoroughly polymict lunar meteorites, and a few KREEP‐free Apollo highland samples manifest a remarkable anticorrelation on a plot of Al₂O₃ versus mg. This trend implies that an important component of the Moon is highly magnesian. The bulk Moon is inferred to have an Earth‐like oxide mg ratio of ?87–88 mol%. The close resemblance between the bulk Moon and Earth's primitive mantle extends to moderately volatile elements, most clearly Mn. Unless major proportions of Cr and V are sequestered into deep mantle spinel, remarkably Earth‐like depletions (versus chondrites) are also inferred for bulk Moon Cr and V.     

Comparison of the crater morphology-size relationship for Mars,Moon, and Mercury

New central peak-crater size data for Mars shows that a higher percentage of relatively unmodified Martian craters have central peaks than do fresh lunar craters below a diameter of 30 km. For example, in the diameter range 10 to 20 km, 60% of studied Martian craters have central peaks compared to 26% for the Moon. Gault et al. (1975, J. Geophys. Res.80, 2444–2460) have demonstrated that central peaks occur in smaller craters on Mercury than on the Moon, and that this effect is due to the different gravity fields in which the craters formed. Similar differences when comparing Mars and the Moon show that gravity has affected the diameter at which central peaks form on Mars. Erosion on Mars, therefore, does not completely mask differences in crater interior structure that are caused by differences in gravity. Effects of Mars' higher surface gravity when compared to the Moon are not detected when comparing terrace and crater shape data. The morphology-crater size statistics also show that a full range of crater shapes occur on Mars, and craters tend to become more morphologically complex with increasing diameter. Comparisons of Martian and Mercurian crater data show differences which may be related to the greater efficacy of erosion on Mars.     

The relationship between geology and geochemistry in the Undarum/Spumans/Balmer region of the Moon

A detailed study of geochemical variation in the Undarum/Spumans/Balmer region identifies major rock components which form the region's regolith. The northern portion of the region contains numerous small mare deposits, which cluster in the Undarum and Spumans areas particularly. In the southern portion of the region lies the Balmer basin chemical anomaly, which correlates with extensive plains deposits. Regional maps of the orbital geochemical variables (Mg, Al, Fe, Ti, and Th) are examined individually, then correlated to one another and to the most recent geological map of the region. Results of the study indicate the presence of basalt components, which show considerable variation in character and which are correlated with both mare and plains features in a region otherwise dominated by ANT suite material. The northeastern area is the most characteristically anorthositic part of the region and mare plains deposits from this area have relatively anorthositic composition. A basalt intermediate in composition between mare basalt and Fra Mauro basalt is proposed as a probable component of the Balmer plains deposits. Southeastern Crisium basalts, and the parts of other mare deposits that are distributed along a structurally-related ring have a similar character. The major basalt deposits around the eastern part of Fecunditatis appear to have a different character. All deposits, particularly those in the northeastern area, appear to be mare basalt contiminated with ANT suite material from the surrounding highlands. In general, the surface geochemistry of the Undarum/Spumans/Balmer region is quite heterogeneous, showing a distinct north/south dichotomy.     

Possible relationship between the Farmington meteorite and a seismically detected swarm of meteoroids impacting the Moon

Abstract— The Farmington ordinary L5 chondrite with its uniquely short cosmic-ray exposure age of less than 25 000 years may have been a member of a large meteoroid swarm which was detected by the Apollo seismic network when it encountered the Moon in June 1975. The association implies that the parent body of the Farmington meteorite was in an Earth-crossing orbit at the time the swarm was formed. This supports the idea that at least some meteorites are derived from the observable population of Earth-crossing asteroids.     

Geologic context of in situ rocky exposures in Mare Serpentis, Mars: Implications for crust and regolith evolution in the cratered highlands

Global acquisition of infrared spectra and high-resolution visible and infrared imagery has enabled the placement of compositional information within stratigraphic and geologic context. Mare Serpentis, a low albedo region located northwest of Hellas Basin, is rich in spectral and thermophysical diversity and host to numerous isolated exposures of in situ rocky material. Most martian surfaces are dominated by fine-grained particulate materials that bear an uncertain compositional and spatial relationship to their source. Thus location and characterization of in situ rock exposures is important for understanding the origin of highland materials and the processes which have modified those materials. Using spectral, thermophysical and morphologic information, we assess the local and regional stratigraphy of the Mare Serpentis surface in an effort to reconstruct the geologic history of the region. The martian highlands in Mare Serpentis are dominated by two interspersed surface units, which have distinct compositional and thermophysical properties: (1) rock-dominated surfaces relatively enriched in olivine and pyroxene, and depleted in high-silica phases, and (2) sediment or indurated material depleted in olivine and pyroxene, with relatively higher abundance of high-silica phases. This is a major, previously unrecognized trend which appears to be pervasive in the Mare Serpentis region and possibly in other highland areas. The detailed observations have led us to form two hypotheses for the relationship between these two units: either (1) they are related through a widespread mechanical and/or chemical alteration process, where less-mafic plains materials are derived from the mafic bedrock, but have been compositionally altered in the process of regolith formation, or (2) they are stratigraphically distinct units representing separate episodes of upper crust formation. Existing observations suggest that the second scenario is more likely. In this scenario, plains materials represent older, degraded, and possibly altered, “basement” rock, whereas the rocky exposures represent later additions to the crust and are probably volcanic in origin. These hypotheses should be further testable with decimeter-resolution imagery and meter-resolution short wavelength infrared spectra.     

Primary and secondary magnetizations in lunar rocks - Implications for the ancient magnetic field of the Moon

The nature of the ancient magnetic field of the Moon, in which lunar rocks acquired their remanent magnetism, has emerged as an important potential source of evidence, if somewhat controversial, for a lunar core which at a period in the Moon's history was the source of the magnetic field. Many of the lunar rocks possess a stable, primary remanence (NRM) with characteristics consistent with and indicative of thermo-remanent magnetization, acquired when the rocks cooled in an ambient magnetic field. Also present are secondary components of magnetization, one type of which appears to have been acquired between collection on the Moon and reception in the laboratory and others which were apparently acquired on the Moon.An important question to be answered is whether meteorite impacts play any part in lunar magnetism, either in modifying pre-existing magnetizations or by imparting a shock remanent magnetism (SRM) in a transient magnetic field associated with the impact. With current knowledge, SRM, in either a global lunar magnetic field of a transient field, and TRM cannot be distinguished, and in the paper the secondary magnetization characteristic of lunar rocks are examined to investigate whether their nature favours the presence of a permanent lunar magnetic field or whether they are consistent with an origin as a transient field-generated SRM.Besides terrestrial processes of secondary magnetization, such as viscous, chemical and partial thermoremanent magnetization, possible processes peculiar to the Moon are discussed and their likely importance assessed in relation to lunar sample history. The nature of the secondary magnetizations appear to be best explained on the assumption that they are due to one or more of the processes that require an ambient lunar field, namely viscous, partial thermoremanent and shock magnetization. When associated with other types of evidence obtained from lunar magnetism studies, investigations of lunar sample remanent magnetism now favours the existence of an ancient lunar magnetic field.     

Earliest high-Ti volcanism on the Moon: 40Ar-39Ar,Sm-Nd,and Rb-Sr isotopic studies of Group D basalts from the Apollo 11 landing site

Abstract High-Ti basalts from the Apollo collections span a range in age from 3.87 Ga to 3.55 Ga. The oldest of these are the common Apollo 11 Group B2 basalts which yield evidence of some of the earliest melting of the lunar mantle beneath Mare Tranquillitatis. Rare Group D high-Ti basalts from Mare Tranquillitatis have been studied in an attempt to confirm a postulated link with Group B2 basalts (Jerde et al., 1994). The initial Sr isotopic ratio of a known Group D basalt (0.69916 ± 3 at 3.85 Ga) lies at the lower end of the tight range for Group B2 basalts (⁸⁷Sr/⁸⁶Sr = 0.69920 to 0.69921). One known Group D basalt and a second postulated Group D basalt yield indistinguishable initial ?_Nd (1.2 ± 0.6 and 1.2 ± 0.3) and again lie at the lower end of the range for the Group B2 basalts from Apollo 11 (+2.0 ± 0.4 to +3.9 ± 0.6, at 3.85 Ga). A third sample has isotopic (⁸⁷Sr/⁸⁶Sr = 0.69932 ± 2; ?_Nd = 2.5 ± 0.4; at 3.59 Ga; as per Snyder et al., 1994b) and elemental characteristics similar to the Group A high-Ti basalts returned from the Apollo 11 landing site. Ages of ⁴⁰Ar-³⁹Ar have been determined for one known Group D basalt and a second postulated Group D basalt using step-heating with a continuous-wave laser. Suspected Group D basalt, 10002, 1006, yielded disturbed age spectra on two separate runs, which was probably due to ³⁹Ar recoil effects. Using the “reduced plateau age” method of Turner et al. (1978), the ages derived from this sample were 3898 ± 19 and 3894 ± 19 Ma. Three separate runs of known Group D basalt 10002, 116 yielded ⁴⁰Ar/³⁹Ar plateau ages of 3798 ± 9 Ma, 3781 ± 8 Ma, and 3805 ± 7 Ma (all errors 2σ). Furthermore, this sample has apparently suffered significant ⁴⁰Ar loss either due to solar heating or due to meteorite impact. The loss of a significant proportion of ⁴⁰Ar at such a time means that the plateau ages underestimate the “true” crystallization age of the sample. Modelling of this Ar loss yields older, “true” ages of 3837 ± 18, 3826 ± 16, and 3836 ± 14 Ma. These ages overlap the ages of Group B2 high-Ti basalts (weighted average age = 3850 ± 20 Ma; range in ages = 3.80 to 3.90 Ga). The combined evidence indicates that the Group D and B2 high-Ti basalts could be coeval and may be genetically related, possibly through increasing degrees of melting of a similar source region in the upper mantle of the Moon that formed >4.2 Ga ago. The Group D basalts were melted from the source first and contained 3–5×more trapped KREEP-like liquid than the later (by possibly only a few million years) Group B2 basalts. Furthermore, the relatively LREE- and Rb-enriched nature of these early magmas may lend credence to the idea that the decay of heat-producing elements enriched in the KREEP-like trapped liquid of upper mantle cumulates, such as K, U, and Th, could have initiated widespread lunar volcanism.     

Proton flux and radiation dose from galactic cosmic rays in the lunar regolith and implications for organic synthesis at the poles of the Moon and Mercury

Galactic cosmic rays are a potential energy source to stimulate organic synthesis from simple ices. The recent detection of organic molecules at the polar regions of the Moon by LCROSS (Colaprete, A. et al. [2010]. Science 330, 463–468, http://dx.doi.org/10.1126/science.1186986), and possibly at the poles of Mercury (Paige, D.A. et al. [2013]. Science 339, 300–303, http://dx.doi.org/10.1126/science.1231106), introduces the question of whether the organics were delivered by impact or formed in situ. Laboratory experiments show that high energy particles can cause organic production from simple ices. We use a Monte Carlo particle scattering code (MCNPX) to model and report the flux of GCR protons at the surface of the Moon and report radiation dose rates and absorbed doses at the Moon’s surface and with depth as a result of GCR protons and secondary particles, and apply scaling factors to account for contributions to dose from heavier ions. We compare our results with dose rate measurements by the Cosmic Ray Telescope for the Effects of Radiation (CRaTER) experiment on Lunar Reconnaissance Orbiter (Schwadron, N.A. et al. [2012]. J. Geophys. Res. 117, E00H13, http://dx.doi.org/10.1029/2011JE003978) and find them in good agreement, indicating that MCNPX can be confidently applied to studies of radiation dose at and within the surface of the Moon. We use our dose rate calculations to conclude that organic synthesis is plausible well within the age of the lunar polar cold traps, and that organics detected at the poles of the Moon may have been produced in situ. Our dose rate calculations also indicate that galactic cosmic rays can induce organic synthesis within the estimated age of the dark deposits at the pole of Mercury that may contain organics.