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辐射增强共混物相容性的研究 总被引:3,自引:0,他引:3
研究了在多官能团单体存在下,辐射对PP/LDPE,PS/EPDM等不相容共混体系的敏化效应,并用SEM,DSC以及动态力学性能等对其进行了表征。结果表明,辐射敏化界在反应的方法是增强不相容聚合物共混物相界面粘接和改善其相容性的一种有效途径。 相似文献
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聚合物共混相容性研究进展 总被引:5,自引:0,他引:5
介绍了聚合物共混相容性的热力学理论,讨论了相容性的实验表征方法,包括共混物形态和物性表征等,提出了改善聚合物相容性的重要途径及其进展。 相似文献
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本文讨论了高分子共混物的相容性及其与组分高分子的溶解度参数δ、极性(分子结构)、表面张力γ、结晶能力及粘度(分子量)等因素的关系。 相似文献
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改善聚合物共混材料界面相容性的研究进展 总被引:3,自引:0,他引:3
本文综述了聚合物共混材料界面相容性的概念、理论基础以及改善相容性的方法和增容技术的应用,简要介绍了原住复合材料的发展趋势和正弦脉动流场从物理的角度对共混物起到了增容的作用。 相似文献
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聚合物共混物的红外光谱研究 总被引:2,自引:0,他引:2
采用傅立叶变换红外光谱(FTIR)技术,同时将谱图进行归一化处理,通过合谱共混谱研究了氯丁橡胶(CR)/聚氯乙烯(PVC)和CR/聚苯乙烯(PS)两个二元聚合物共混体系的相容性,结果表明,CR与PVC所组成的共混物中组分矣合物红外光谱特征吸收谱带发生较大位移,表现出较强的相互作用,CR与PS所组成的共混物的红外吸收特征峰发生了较小偏移,同时特征峰形略有变化,说明有较弱的相互作用。 相似文献
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N. A. Ibrahim A. Hebeish H. M. Fahmy M. H. Abo-Shosha 《Polymer-Plastics Technology and Engineering》2013,52(3):341-350
Free radical polymerization of acrylamide (Aam) in the presence of aqueous solution of three commercial grades of polyvinyl alcohol (PVOH), namely, Vinarol FV (containing very few acetyl groups), Mowiol 4-80 (low viscosity-partially hydrolyzed), and Vinarol STH (medium viscosity-partially hydrolyzed), using ammonium persulfate (AP) initiator resulted in three corresponding PVOH/Aam polyblends. Optimum polymerization conditions were PVOH and AP concentrations, 10% and 0.05 mol/L, respectively; Aam concentration, 50% based on the weight of PVOH; polymerization temperature and time, 70°C and 20 min, respectively; rate of stirring, 200 rpm, at which the three polyblends were prepared at very high polymerization extent ranging from 98.2 to 99.9%. Rheological properties of 10% aqueous solutions of the polyblends at 80°C were studied. The extent of film resolubility of PVOH's and their polyblends follows the descending order: Mowiol®4-80/Aam > Mowiol®4-80 > Vinarol®STH/Aam > Vinarol®STH > Vinarol®FV/Aam > Vinarol®FV. Sizing of gauzy cotton fabric with the polyblends and PVOH's showed that (1) their tensile strength follows the order: Vinarol®STH/Aam > Vinarol®STH > Mowiol®4-80/Aam > Mowiol®4-80 > Vinarol®FV/Aam > Vinarol®FV > Unsized and (2) their desizability follows the order: Mowiol®4-80/Aam > Mowiol®4-80 > Vinarol®STH/Aam > Vinarol®STH > Vinarol®FV/Aam > Vinarol®FV. 相似文献
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Poly(2-methoxy-5-(2′-ethyl-hexyloxy)-p-phenylenevinylene) (MEH-PPV) and poly(2,3-diphenyl-5-octyl-p-phenylenevinylene) (DPO-PPV) are basically immiscible as verified by fluorescence spectroscopy and differential scanning
calorimetry. This immiscibility results in insufficient energy transfer from DPO-PPV to MEH-PPV in photoluminescence. A vertically
segregated structure with DPO-PPV green domains dispersing on the MEH-PPV-rich matrix was observed in a spin-cast film by
two-photon excitation microscopy. The turn-on voltages for electroluminescence (EL) of polyblends were lower than those of
their individual pristine polymers, while their EL quantum efficiencies were higher. Because both the highest occupied molecular
orbital and the lowest unoccupied molecular orbital levels of MEH-PPV are higher than those of the DPO-PPV, the energy gap
of the vertical heterojunction (1.98 eV) in polyblends is lower than that of the pristine MEH-PPV (2.14 eV), which is believed
to result in the improved EL properties. 相似文献
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针对在聚砜生产实践中提取的质量控制问题,然决了在线的粘度连续测定的问题。该粘度连续测定法是根据粘度测定的基本原则而设计的。从理论及实验中,证明了它的可靠性。 相似文献
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Polymer blends of Polycarbonate (PC) and Styrene-Butadiene-Styrene triblock (SBS) have been investigated. SBS copolymers have four different styrenic contents, three of which are linear SBS. PC and PS blends are partially miscible as revealed by dynamic mechanical analysis with two clear Tgs near 100–150°C. On the contrary, PC/SBS blends have only one Tg with a left shoulder. Based on the PS domain model of pure SBS, we suggest a micelle model based on the structure when the micelle and absorb PC in the PC/SBS blends. The micelle plays an important role in improving the miscibility. The proposed micelle model has been empolyed to interpret the testing results, such as toughness, impact strength, dynamic mechanical property and SEM morphologies. This proposed micelle model seems a worth-while method to explain the properties of partialtly miscible blends of PC and SBS. 相似文献
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使用推广的 Flory-Huggins理论结合 Monte Carlo法模拟聚苯乙烯与几种不同溶剂的相容性。用 Monte Carlo法从大量分子对中取样 ,计算配位数和相互作用能 ,将数据输入 Flory-Huggins格子模型中 ,估算出体系的混合自由能和相图 ,研究聚合度对聚苯乙烯与溶剂体系相容性的影响。模拟结果表明聚苯乙烯与甲苯等溶剂的相容性较好 ,与水等溶剂的相容性较差 ;随着聚苯乙烯聚合度增大 ,体系相容性变差 ;而且在聚合度较低时 ,相容性变差的程度更显著 ;以上结果与实际情况相符。 相似文献
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A series of blend films from cellulose acetate (CA) and castor oil-based polyurethane (PU) were prepared. Morphology, miscibility, free volume behavior and properties of such blend films were investigated by wide-angle X-ray diffraction (WXRD), infrared, scanning electron microscopy (SEM), differential scanning calorimetry (DSC), positron annihilation lifetime spectroscopy (PALS), thermogravimetric analysis and tensile test. The results indicated that lager free volume cavities did not form at the interface of two polymers although a certain degree of phase separation was found by the studies of SEM and DSC. Strong intermolecular hydrogen bonding interactions at the interface, which was proved by Fourier transform infrared spectroscopy, favors even better molecular packing, that is, PU dispersed in CA continuous phase to form fine microphase separation domain in the CA-rich blends. Due to such special interactions in the fine microphase separation domain structure, optimized properties of tensile strength, breaking elongation and cold-resistivity were obtained in the blend film with 75 wt% CA. The toughness of all the blend films was significantly higher than that of the film CA, owing to the plasticizing of PU elastomer in the blends. 相似文献