Interaction of sodium fullerene derivatives with trimethylchlorosilane

Soluble dimer compounds of the general formula [C₆₀(Me ₃Si)_n]₂ (where n = 3, 5, 7, or 9 and M _e = CH₃) and a soluble monomer compound, C₆₀(Me ₃Si)₁₂, are synthesized by the reaction of the compound C₆₀Na_n(THF)_x (where n = 4, 6, 8, 10, or 12 and THF = tetrahydrofuran) with trimethylchlorosilane Me ₃SiCl. The compounds synthesized are identified using IR and NMR spectroscopy and mass spectrometry. An irreversible endothermic effect exhibited by the [C₆₀(Me ₃Si)₇]₂ compound in the temperature range 448–570 K is revealed by dynamic adiabatic calorimetry. From analyzing the experimental results, it becomes possible for the first time to demonstrate the structural flexibility of the fullerene in the following sequence of reactions: $\begin{array}{*{20}c} {C_{60} \xrightarrow[{ - 12C_{10} H_8 }]{{ + 12NaC_{10} H_8 }}C_{60} Na_{12} \xrightarrow[{ - 12NaCl}]{{ + excess Me_3 SiCl}}C_{60} (Me_3 Si)_{12} \xrightarrow[{ - 12Me_3 SiCl}]{{ + HCl(gas)}}[C_{60} H_n ]\xrightarrow[{ - 1/2nH_2 }]{{hv}}C_{60} } \\ {C_{60} \xrightarrow[{ - 8C_{10} H_8 }]{{ + 8NaC_{10} H_8 }}C_{60} Na_8 \xrightarrow[{ - 8NaCl}]{{ + excess Me_3 SiCl}}[C_{60} (Me_3 Si)_7 ]_2 \xrightarrow{{573K}}\begin{array}{*{20}c} {products of the} \\ {transformation of + } \\ {Me_3 Si groups} \\ \end{array} C_{60^ - } } \\ \end{array} $      

Low-temperature heat capacities and standard molar enthalpy of formation of 4-（2-aminoethyl）-phenol （C8H11NO）

This paper reports that low-temperature heat capacities of 4-（2-aminoethyl）-phenol （C8H11NO） are measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 400 K. A polynomial equation of heat capacities as a function of the temperature was fitted by the least square method. Based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15K were calculated and tabulated at the interval of 5K. The energy equivalent, εcalor, of the oxygen-bomb combustion calorimeter has been determined from 0.68g of NIST 39i benzoic acid to be εcalor=（14674.69±17.49）J·K^-1. The constant-volume energy of combustion of the compound at T=298.15 K was measured by a precision oxygen-bomb combustion calorimeter to be ΔcU=-（32374.25±12.93）J·g^-1. The standard molar enthalpy of combustion for the compound was calculated to be ΔcHm = -（4445.47 ± 1.77） kJ·mol^-1 according to the definition of enthalpy of combustion and other thermodynamic principles. Finally, the standard molar enthalpy of formation of the compound was derived to be ΔfHm（C8H11NO, s）=-（274.68 ±2.06） kJ·mol^-1, in accordance with Hess law.     

Transport coefficients of quasicrystals

The transport coefficients for the nine point groups —which represent the symmetry groups of the quasicrystals in two and three dimensions—have been evaluated and tabulated in this work, employing group-theoretical methods.     

Nuclear quadrupole moments of radioactive83Rb,84Rb and86Rb

Excited atomic² P _3/2-states of radioactive Rb isotopes have been investigated by level crossing and optical double resonance spectroscopy. The measured hyperfine structure constants yielded the nuclear moments $$\begin{gathered} \mu _I (^{84} Rb) = - 1.296(11)\mu _K Q(^{83} Rb) = + 0.27(5) \cdot 10^{ - 24} cm^2 \hfill \\ Q(^{84} Rb) = + 0.005(13) \cdot 10^{ - 24} cm^2 \hfill \\ Q(^{86} Rb) = + 0.20(3) \cdot 10^{ - 24} cm^2 \hfill \\ \end{gathered} $$ and the hyperfine anomaly₈₄Δ₈₅=+1.7(1.0) · 10^?2. The quadrupole moments of⁸³Rb to⁸⁷Rb can be explained with the unified model of vibrations.     

Observation of a strong correlation betweeng(2+γvib) andg(2+rot) in strongly deformed nuclei

The E2/M1 multipole mixing parameters of cascade transitions inγ-vibrational bands of¹⁵⁴Gd,¹⁶⁶Er and¹⁶⁸Er have been determined byγ-γ directional correlation measurements as: $$\begin{array}{l} \delta \left( {^{154} Gd\left( {3_\gamma ^ + \to 2_\gamma ^ + } \right)} \right) = - 4.3_{ + 2.1}^{ - 9.4} \\ \delta \left( {^{166} Er\left( {5_\gamma ^ + \to 4_\gamma ^ + } \right)} \right) = + 1.94_{ - 0.21}^{ + 0.23} \\ \end{array}$$ and $$\delta \left( {^{168} Er\left( {3_\gamma ^ + \to 2_\gamma ^ + } \right)} \right) = + 1.42_{ - 0.04}^{ + 0.04} $$ (with conversion data [15] taken into account) These data were used to deriveg(2⁺ γvib)?g(2⁺rot). The results, together withg-factors derived from direct measurements by IPAC and Mössbuer spectroscopy [10] or by use of transient fields [9, 31] exhibit a strong correlation between bothg-factors, i.e. ifg(2⁺rot) is largeg(2⁺ γvib) is small and vice versa. The most direct and most simple interpretation is the assumption of a more or less different density distribution of protons and neutrons in the nuclei.     

Dy2 AlFe13 Mn3 化合物的本征磁致伸缩

通过X-射线衍射及磁测量手段研究了Dy2AlFe13Mn3化合物的结构及磁性质。研究结果表明Dy2AlFe13Mn3化合物具有六角相的Th2Ni17型结构。通过X-射线热膨胀测定法发现Dy2AlFe13Mn3化合物在245到344K的温度范围内存在负热膨胀现象，其平均热膨胀系数为α＝-1.1×10-4K-1K-1。在105到360K的温度范围内，通过比较磁性状态下的晶胞参数和由高温顺磁状态外延得到的低温顺磁状态下的晶胞参数间的差别计算了Dy2AlFe13Mn3化合物的本征磁致伸缩。结果表明Dy2AlFe13Mn3化合物的本征体磁致伸缩ωS在105到245K的温度范围内随着温度的升高而增大，由105K时的7.0×10-3 增加到245K时的9.1×10-3。随着温度的进一步升高，ωS反而减小。沿c轴方向的本征线磁致伸缩λc随着温度的升高而减小。基面内的本征线磁致伸缩λa在105到270K的温度范围内随着温度的升高而增大，从105K时的0.8×10-3增大到270K时的3.4×10-3，然后随着温度的进一步升高而减小。     

A measurement of the branching ratio∑ +→pγ/∑ +→pπ 0⋆

In an experiment performed in the CERN SPS hyperon beam we have obtained a value for the branching ratio $${{\Sigma ^ + \to p\gamma } \mathord{\left/ {\vphantom {{\Sigma ^ + \to p\gamma } {\Sigma ^ + \to p\pi }}} \right. \kern-\nulldelimiterspace} {\Sigma ^ + \to p\pi }}^0 of\left( {2.46_{ - 0.35}^{ + 0.30} } \right) \times 10^{ - 3} ,$$ corresponding to a branching ratio $${{\Sigma ^ + \to p\gamma } \mathord{\left/ {\vphantom {{\Sigma ^ + \to p\gamma } {\Sigma ^ + \to all}}} \right. \kern-\nulldelimiterspace} {\Sigma ^ + \to all}}of\left( {1.27_{ - 0.18}^{ + 0.16} } \right) \times 10^{ - 3} .$$ This result is discussed in the context of present understanding of hyperon radiative decays.     

Structures of distorted phases and critical and noncritical atomic displacements of elpasolite Rb<Subscript>2</Subscript>KInF<Subscript>6</Subscript> during phase transitions

The structures of all three phases of the Rb₂KInF₆ crystal have been determined from the experimental X-ray diffraction data for the powder sample. The refinement of the profile and structural parameters has been carried out by the technique implemented in the DDM program, which minimizes the differences between the derivatives of the calculated and measured X-ray intensities over the entire profile of the X-ray diffraction pattern. The results obtained have been discussed using the group-theoretical analysis of the complete order-parameter condensate, which takes into account the critical and noncritical atomic displacements and permits the interpretation of the experimental data obtained previously. It has been reliably established that the sequence of changes in the symmetry during phase transitions in Rb₂KInF₆ can be represented as $ Fm\bar 3m\xrightarrow[{0,0,\phi }]{{11 - 9\left( {\Gamma _4^ + } \right)}}{{I114} \mathord{\left/ {\vphantom {{I114} {m\xrightarrow[{\left( {\psi ,\phi ,\phi } \right)}]{{11 - 9\left( {\Gamma _4^ + } \right) \oplus 10 - 3\left( {X_3^ + } \right)}}{{P12_1 } \mathord{\left/ {\vphantom {{P12_1 } {n1}}} \right. \kern-\nulldelimiterspace} {n1}}}}} \right. \kern-\nulldelimiterspace} {m\xrightarrow[{\left( {\psi ,\phi ,\phi } \right)}]{{11 - 9\left( {\Gamma _4^ + } \right) \oplus 10 - 3\left( {X_3^ + } \right)}}{{P12_1 } \mathord{\left/ {\vphantom {{P12_1 } {n1}}} \right. \kern-\nulldelimiterspace} {n1}}}} $ Fm\bar 3m\xrightarrow[{0,0,\phi }]{{11 - 9\left( {\Gamma _4^ + } \right)}}{{I114} \mathord{\left/ {\vphantom {{I114} {m\xrightarrow[{\left( {\psi ,\phi ,\phi } \right)}]{{11 - 9\left( {\Gamma _4^ + } \right) \oplus 10 - 3\left( {X_3^ + } \right)}}{{P12_1 } \mathord{\left/ {\vphantom {{P12_1 } {n1}}} \right. \kern-\nulldelimiterspace} {n1}}}}} \right. \kern-\nulldelimiterspace} {m\xrightarrow[{\left( {\psi ,\phi ,\phi } \right)}]{{11 - 9\left( {\Gamma _4^ + } \right) \oplus 10 - 3\left( {X_3^ + } \right)}}{{P12_1 } \mathord{\left/ {\vphantom {{P12_1 } {n1}}} \right. \kern-\nulldelimiterspace} {n1}}}} .     

Photonic decays involving the2^{ + + } \left( {\bar bb} \right): Partial widths and jets from tensor meson dominance

Tensor meson dominance combined with vector meson dominance, QCD-potentials and the experimental leptonic widths of Γ and Γ′ predicts $$\Gamma _{\Upsilon '\left( {10.01} \right) \to \gamma 2^{ + + } \left( {\bar bb} \right)} = 2.8keV$$ and $$\Gamma _{2^{ + + } \left( {\bar bb} \right) \to \gamma \Upsilon \left( {9.46} \right)} = 134keV.$$ The angular distributions of the γ and the jetsj resulting from the decays $$e^ + e^ - \to \Upsilon '\left( {10.01} \right) \to \gamma 2^{ + + } \left( {\bar bb} \right) \to \gamma gg \to \gamma jj$$ and $$e^ + e^ - \to \Upsilon '\left( {10.01} \right) \to \gamma 2^{ + + } \left( {\bar bb} \right) \to \gamma \bar qq \to \gamma jj$$ with massless vector gluonsg, (coupled gauge invariantly) and quarksq are uniquely determined in TMD. The result for the first process agrees with that of perturbative QCD. No perturbative QCD-prediction for the latter is known.     

Polarization-optical and X-ray diffraction investigations on the symmetry of distorted phases of ammonium cryolite (NH4)3 ScF6

Single-crystal plates of different sections of the (NH₄)₃ScF₆ crystal have been investigated by polarization-optical microscopy and X-ray diffraction over a wide temperature range, including the temperatures of two known phase transitions and the third transition found recently. It is established that the symmetry of 5 phases changes in the following sequence: $\begin{gathered} O_h^5 - Fm3m(Z = 4) \leftrightarrow C_{2h}^5 - {{P12_1 } \mathord{\left/ {\vphantom {{P12_1 } {n1}}} \right. \kern-0em} {n1}}(Z = 2) \leftrightarrow C_{2h}^3 - {{I12} \mathord{\left/ {\vphantom {{I12} {m1}}} \right. \kern-0em} {m1}} \\ (Z = 16) \leftrightarrow C_i^1 - I\bar 1(Z = 16) \\ \end{gathered} $ .     

An expansion of Hartree-Fock and correlation energies,relativistic corrections and the dipole matrix element in the powers of of 1/Z

Feynman diagrammatic technique was used for the calculation of Hartree-Fock and correlation energies, relativistic corrections, dipole matrix element. The whole energy of atomic system was defined as a polen-electron Green function. Breit operator was used for the calculation of relativistic corrections. The Feynman diagrammatic technique was developed for 〈H_B>. Analytical expressions for the contributions from diagrams were received. The calculations were carried out for the terms of such configurations as 1s² 2sⁿ¹ 2pⁿ² (2 ≧n₁≧ 0, 6≧ n₂ ≧ 0). Numerical results are presented for the energies of the terms in the form $$E = E_0 Z^2 + \Delta {\rm E}_2 + \frac{1}{Z}\Delta {\rm E}_3 + \frac{{\alpha ^2 }}{4}(E_0^r + \Delta {\rm E}_1^r Z^3 )$$ and for fine structure of the terms in the form $$\begin{gathered} \left\langle {1s^2 2s^{n_1 } 2p^{n_2 } LSJ|H_B |1s^2 2s^{n_1 \prime } 2p^{n_2 \prime } L\prime S\prime J} \right\rangle = \hfill \\ = ( - 1)^{\alpha + S\prime + J} \left\{ {\begin{array}{*{20}c} {L S J} \\ {S\prime L\prime 1} \\ \end{array} } \right\}\frac{{\alpha ^2 }}{4}(Z - A)^3 [E^{(0)} (Z - B) + \varepsilon _{co} ] + \hfill \\ + ( - 1)^{L + S\prime + J} \left\{ {\begin{array}{*{20}c} {L S J} \\ {S\prime L\prime 2} \\ \end{array} } \right\}\frac{{\alpha ^2 }}{4}(Z - A)^3 \varepsilon _{cc} . \hfill \\ \end{gathered} $$ Dipole matrix elements are necessary for calculations of oscillator strengths and transition probabilities. For dipole matrix elements two members of expansion by 1/Z have been obtained. Numerical results were presented in the form P(a,a′) = a/Z(1+τ/Z).     

Band spectrum of manganese oxide (MnO)

New measurements of the wavelengths of the band heads of MnO spectrum have been made. In all 57 band heads, including 15 hitherto unrecorded ones, have been measured. The equation representing the wave-number of a band head has been modified as,

$$\begin{gathered} v = 17949 \cdot 19 + \{ 762 \cdot 75(v' + \tfrac{1}{2}) - 9 \cdot 60(v' + \tfrac{1}{2})^2 + 0 \cdot 06(v' + \tfrac{1}{2})^3 \} \hfill \\ - \{ 839 \cdot 55(v'' + \tfrac{1}{2}) - 4 \cdot 79(v'' + \tfrac{1}{2})^2 \} \hfill \\ \end{gathered} $$     

Measurement of the\sum {^ - \to ne^ - \bar v} rate and search for ΔQ=−ΔS transitions in Σ+→ne + ν decay

In a bubble chamber experiment about 2×10⁶ Σ ^±-decays have been measured to separateΣ ^±→ne^±¯ν events from the two-body modes. NoΣ ⁺ →ne ⁺ ν event was found whereas 607Σ ^?→ne^?¯ν decays could be identified. The data yield for the ΔQ=?ΔS decay an upper limit: $$\frac{{\Gamma \left( {\sum {^ + } \to ne^ + v} \right)}}{{\Gamma \left( {\sum {^ - } \to ne^ - v} \right)}}< 1.9 x 10^{ - 2} (90\% confidence level)$$ and the branching ratio: $$\frac{{\Gamma \left( {\sum {^ - } \to ne^ - v} \right)}}{{\Gamma \left( {\sum {^ - } \to n\pi ^ - } \right)}} = (1.09 \pm 0.06) x 10^{ - 3} .$$      

On (n,p) cross sections for 14 MeV neutrons

Using older compilations and recent data the (n, p) cross sections for neutron energies between 14 and 15 MeV have been collected and revised critically. The experimental data can be represented phenomenologically by the formula $$\log _{10} ({{\sigma _{np} } \mathord{\left/ {\vphantom {{\sigma _{np} } {mb}}} \right. \kern-\nulldelimiterspace} {mb}}) = 0.2 + 0.4A^{{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} - 4.6{{(N - Z)} \mathord{\left/ {\vphantom {{(N - Z)} {A^{{2 \mathord{\left/ {\vphantom {2 3}} \right. \kern-\nulldelimiterspace} 3}} }}} \right. \kern-\nulldelimiterspace} {A^{{2 \mathord{\left/ {\vphantom {2 3}} \right. \kern-\nulldelimiterspace} 3}} }}$$ . The compound part of the (n, p) reactions is described by a statistical model; the direct reactions are taken into account semiempirically.     

Search for rare radiative decays ofΦ-meson at VEPP-2M

Results of the search for rare radiative decay modes of the ?-meson performed with the Neutral Detector at the VEPP-2M collider are presented. For the first time upper limits for the branching ratios of the following decay modes have been placed at 90% confidence level: $$\begin{gathered} B(\phi \to \eta '\gamma )< 4 \cdot 10^{ - 4} , \hfill \\ B(\phi \to \pi ^0 \pi ^0 \gamma )< 10^{ - 3} , \hfill \\ B(\phi \to f_0 (975)\gamma )< 2 \cdot 10^{ - 3} , \hfill \\ B(\phi \to H\gamma )< 3 \cdot 10^{ - 4} , \hfill \\ \end{gathered} $$ whereH is a scalar (Higgs) boson with a mass 600 MeV<m _H <1000 MeV, the real measurement isB(φ→H γ)·B(H→2π⁰)<0.8·10^-4, the quoted result is model dependent, as explained in the text, $$\begin{gathered} B(\phi \to a\gamma ) \cdot B(a \to e^ + e^ - )< 5 \cdot 10^{ - 5} , \hfill \\ B(\phi \to a\gamma ) \cdot B(a \to \gamma \gamma )< 2 \cdot 10^{ - 3} , \hfill \\ \end{gathered} $$ wherea is a particle with a low mass and a short lifetime, $$B(\phi \to a\gamma )< 0.7 \cdot 10^{ - 5} ,$$ wherea is a particle with a low mass not observed in the detector.     

Self-diffusion in α-Fe2O3 natural single crystals

Measurements of¹⁸O self-diffusion in hematite (Fe₂O₃) natural single crystals have been carried out as a function of temperature at constant partial pressure a_{O 2}=6.5·10^?2 in the temperature range 890 to 1227 °C. The a_{O 2} dependence of the oxygen self-diffusion coefficient at fixed temperature T=1150 °C has also been deduced in the a_{O 2} range 4.5·10^?4 - 6.5·10^?1. The concentration profiles were established by secondary-ion mass spectrometry; several profiles exhibit curvatures or long tails; volume diffusion coefficients were computed from the first part of the profiles using a solution taking into account the evaporation and the exchange at the surface. The results are well described by $$D_O \left( {{{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } s}} \right. \kern-\nulldelimiterspace} s}} \right) = 2.7 \cdot 10^8 a_{O_2 }^{ - 0.26} \exp \left( { - \frac{{542\left( {{{kJ} \mathord{\left/ {\vphantom {{kJ} {mol}}} \right. \kern-\nulldelimiterspace} {mol}}} \right)}}{{RT}}} \right)$$ From fitting a grain boundary diffusion solution to the profile tails, the oxygen self-diffusion coefficient in sub-boundaries has been deduced. They are well described by $$D''_O \left( {{{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } s}} \right. \kern-\nulldelimiterspace} s}} \right) = 3.2 \cdot 10^{25} a_{O_2 }^{ - 0.4} \exp \left( { - \frac{{911\left( {{{kJ} \mathord{\left/ {\vphantom {{kJ} {mol}}} \right. \kern-\nulldelimiterspace} {mol}}} \right)}}{{RT}}} \right)$$ Experiments performed introducing simultaneously¹⁸O and⁵⁷Fe provided comparative values of the self-diffusion coefficients in volume: iron is slower than oxygen in this system showing that the concentrations of atomic point defects in the iron sublattice are lower than the concentrations of atomic point defects in the oxygen sublattice. The iron self-diffusion values obtained at T>940 °C can be described by $$D_{Fe} \left( {{{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } s}} \right. \kern-\nulldelimiterspace} s}} \right) = 9.2 \cdot 10^{10} a_{O_2 }^{ - 0.56} \exp \left( { - \frac{{578\left( {{{kJ} \mathord{\left/ {\vphantom {{kJ} {mol}}} \right. \kern-\nulldelimiterspace} {mol}}} \right)}}{{RT}}} \right)$$ The exponent - 1/4 observed for the oxygen activity dependence of the oxygen self-diffusion in the bulk has been interpreted considering that singly charged oxygen vacancies V _O ^? are involved in the oxygen diffusion mechanism. Oxygen activity dependence of iron self-diffusion is not known accurately but the best agreement with the point defect population model is obtained considering that iron self-diffusion occurs both via neutral interstitals Fe _x ⁱ and charged ones.     

Measurement of the inclusive charged-current cross section for neutrino and antineutrino scattering on isoscalar nucleons

This paper reports on measurements of the total cross section for the inclusive reaction v_μ+N , as a function of incident energy. Neutrinos and antineutrinos with energy in the range 30–300 GeV were produced in the 1982 Fermilab narrow-band neutrino beamline. A total of 35 000 neutrino and 7000 antineutrino interactions were recorded in the CCFR detector located in LabE. The incident neutrino flux was determined by methods similar to those used in previous experiments. The rate of increase with energy of the total cross section (σ/E _v) in the range 30 to 75 GeV was determined to be 0.659±0.005(stat)±0.039(syst)×10^?38 cm²/GeV and 0.307±0.008(stat)±0.020(syst)×10^?38 cm²/GeV for incident neutrinos and antineutrinos, respectively. The 5.9% systematic errors are due primarily to uncertainties in the flux intensity measurement. The energy dependence of the cross section in the regionE _ν=100–300 GeV was found to be linear, as determined by relative normalization techniques. A weighted average of our previous and present measurement for the total ν-N cross section yields: $$\begin{gathered} \sigma (vN) = 0.666 \pm 0.020(statistical \hfill \\ + systematic)E_v 10^{ - 38} cm^2 ; \hfill \\ \sigma (\bar vN) = 0.324 \pm 0.014(statistical \hfill \\ + systematic)E_v 10^{ - 38} cm^2 ; \hfill \\ \end{gathered} $$ .     

The temperature dependence of the hyperfine interaction of the transition metal osmium in a gadolinium host matrix

Integral perturbed angular correlations of the 931-155keVγγ-cascade of¹⁸⁸Os in Gd have been measured. With this technique the combined magnetic and electric hyperfine interaction of the 155 keV level of¹⁸⁸Os as an impurity in a Gd host has been studied as a function of temperature. The result for the electric field gradient of Os in Gd at 300 K is: $$\left| {V_{zz} \left( {Os:\underline {Gd} } \right)} \right| = \left( {12.8_{ - 1.9}^{ + 3.1} } \right) \cdot 10^{17} {V \mathord{\left/ {\vphantom {V {cm^2 }}} \right. \kern-\nulldelimiterspace} {cm^2 }}.$$ For the magnetic hyperfine field at 4.2 K the value $$H_{hf} \left( {Os:\underline {Gd} } \right) = - 134\left( {26} \right)kG$$ was obtained. Sign and magnitude of the magnetic hyperfine field suggest the existence of a localized moment of about ?0.4 µ _B at the site of Os in Gd. With increasing temperature the magnetic hyperfine field decreases much stronger than the magnetization of the host. Possible explanations for this anomalous temperature dependence are discussed.     

Coherent pion production in neutrino and antineutrino interactions on nuclei of heavy freon molecules

Studying the coherent diffractive production of pions in neutrino and antineutrino scattering off the nuclei of freon molecules we have observed for the first time in one experiment all three states of the isospin triplet of the axial part of the weak charged and neutral currents. For the corresponding cross sections we derive $$\begin{array}{*{20}c} {\sigma _{coh}^v (\pi ^ + ) = (106 \pm 16) \cdot 10^{ - 40} {{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } {\left\langle {nucl.} \right\rangle }}} \right. \kern-\nulldelimiterspace} {\left\langle {nucl.} \right\rangle }}} \\ {\sigma _{coh}^{\bar v} (\pi ^ - ) = (113 \pm 35) \cdot 10^{ - 40} {{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } {\left\langle {nucl.} \right\rangle }}} \right. \kern-\nulldelimiterspace} {\left\langle {nucl.} \right\rangle }}and} \\ {\sigma _{coh}^v (\pi ^0 ) = (52 \pm 19) \cdot 10^{ - 40} {{cm^2 } \mathord{\left/ {\vphantom {{cm^2 } {\left\langle {nucl.} \right\rangle }}} \right. \kern-\nulldelimiterspace} {\left\langle {nucl.} \right\rangle }}} \\ \end{array} $$ . Comparing our data with theoretical predictions based on the standard model of weak interactions we find reasonable agreement. Independently from any model of coherent pion production we determine the isovector axial vector coupling constant to be |β|=0.99±0.20.     

A stochastic model for metabolizing systems with computer simulation

A stochastic model for a first-order metabolizing system which was studied in the deterministic sense by Branson and others is formulated and a detailed study of the random integral equation arising in the probabilistic model is presented. The equation is used to describe the evolution in time of the amount of metabolite present in the system. Specifically we present a study of the random integral equation of the Volterra type given by $$M\left( {t; \omega } \right) = M\left( {0; \omega } \right)e^{ - et} + \int_0^t {R\left( {\tau ; \omega } \right) e^{ - e\left( {t - \tau } \right)} d\tau , } t \geqslant 0$$ whereM(t; ω) is an unknown random function giving the amount of metabolite in the system at time t ≥ 0. This equation can be expressed in the general form $$x\left( {t; \omega } \right) = h\left( {t; \omega } \right) + \int_0^t {k\left( {t, \tau ; \omega } \right) f\left( {\tau , x\left( {\tau ; \omega } \right)} \right) d\tau } t \geqslant 0$$ which is of a type whose theoretical aspects have recently been studied by the present authors using as a basis the techniques of probabilistic functional analysis. Conditions are derived under which there exists a unique random solution to the above equation. The usefulness of the model is illustrated using computer simulation by considering a one-organ model, an organ-heart model, and a multicompartment model.