Combining U.S.-based prioritization tools to improve screening level accountability for environmental impact: The case of the chemical manufacturing industry

There are two quantitative indicators that are most widely used to assess the extent of compliance of industrial facilities with environmental regulations: the quantity of hazardous waste generated and the amount of toxics released. These indicators, albeit useful in terms of some environmental monitoring, fail to account for direct or indirect effects on human and environmental health, especially when aggregating total quantity of releases for a facility or industry sector. Thus, there is a need for a more comprehensive approach that can prioritize a particular chemical (or industry sector) on the basis of its relevant environmental performance and impact on human health. Accordingly, the objective of the present study is to formulate an aggregation of tools that can simultaneously capture multiple effects and several environmental impact categories. This approach allows us to compare and combine results generated with the aid of select U.S.-based quantitative impact assessment tools, thereby supplementing compliance-based metrics such as data from the U.S. Toxic Release Inventory. A case study, which presents findings for the U.S. chemical manufacturing industry, is presented to illustrate the aggregation of these tools. Environmental impacts due to both upstream and manufacturing activities are also evaluated for each industry sector. The proposed combinatorial analysis allows for a more robust evaluation for rating and prioritizing the environmental impacts of industrial waste.     

A discussion of the U.S. EPA methodology for determining Water Quality Standards (WQS).

Based on material published by the U.S. Environmental Protection Agency (U.S. EPA) in the Federal Register for 19 November 1991, many state environmental agencies have proposed and/or adopted revisions to their State Water Quality Standards (WQS) for organic and inorganic chemicals in fresh and marine waters (see, for example, State of Connecticut, Department of Environmental Protection, Bureau of Water Management, (1992), memorandum to Interested Parties concerning the Water Quality Standards Hearing Report). Generally, many states simply republish the U.S. EPA's proposed Water Quality Criteria (WQC) as the State's proposed WQS. Many of the state WQS and federal WQC values--especially those for organic compounds regulated as human or animal carcinogens--are much more stringent than the values now in effect because the U.S. EPA's new methodology (i) for estimating exposure point concentrations, exposure doses, carcinogenic potency, and incremental lifetime cancer risk and (ii) for setting the target acceptable risk combine a series of conservative assumptions into an equally conservative set of results. In the Federal Register proposal, the U.S. EPA failed to honor its standard risk assessment methodology in that (i) it failed to perform a quantitative or even qualitative uncertainty analysis and (ii) it failed to analyze the overall degree of conservatism in the results. The U.S. EPA suggested that the analysis is suitably conservative for the average exposed adult, but it failed to consider various phenomena that make the proposed WQC far more conservative than acknowledged or intended. To focus on a central problem of manageable size, this article dissects the method by which the U.S. EPA calculates proposed WQC for organic chemicals regulated as human or animal carcinogens. Because the results for most such chemicals are driven by the pathway for the human ingestion of fish which have bioconcentrated the chemicals from the water column (as opposed to the pathway for direct ingestion of water by humans), this article focuses exclusively on the fish-to-human pathway. These considerations form the basis of general quality assurance criteria and standards.     

Sustainable manufacturing: a case study of the forklift painting process

Life cycle assessment (LCA) and design for environment (DFE) methods were applied to assess opportunities for reducing the environmental impacts of forklift manufacturing unit processes and to redesign those unit processes to increase overall sustainability. The unit processes of forklift manufacture generating the most environmental emissions were identified by applying LCA methodology. The results show that eco-toxicity and human toxicity were the most significant impacts of the forklift manufacturing process overall. Also, within the manufacturing unit processes, cutting, welding and painting had the highest impact values. In order to minimise environmental impacts, a new paint was created with increased solid content over the existing solvent paint used in the painting process. In addition, by applying DFE methodology and the high solid paint, overcoat and drying steps were eliminated from the forklift painting process. As a result, the environmental index of a follow-up LCA showed that environmental impacts could be reduced by 20%, while volatile organic compound (VOC) and paint usage could be decreased by 30% and 20%, respectively.     

The impact of environmental issues on the UK printed circuit boardindustry

The need for environmentally responsible manufacturing is forcing industry to change the way it produces its products and offers its services. This is evident in the electronics industry and especially so in the printed circuit board (PCB) manufacturing sector. PCB manufacture requires numerous chemical processes and materials, many of which contain chemicals that can be difficult to dispose of and harmful to the environment. With growing awareness of environmental issues and stricter legislation, the treatment and disposal of these materials can have a significant cost impact on the profitability of UK producers. This article discusses some of the environmental challenges facing the industry and highlights the fact that improvements in environmental performance can actually be used to commercial advantage     

Evaluating Pollution Prevention Progress (P2P)

P2P (Pollution Prevention Progress) is a computer-based tool that supports the comparison of process and product alternatives in terms of environmental impacts. This tool provides screening-level information for use in process design and in product life cycle assessment (LCA). Twenty one impact categories and data for approximately 3,000 chemicals are represented in the default database of the new release, P2P Mark III. These data help identify which emissions may require further, more sophisticated, characterisation in the different impact categories. In this paper, we primarily focus on the persistence-bioaccumulation toxicity (PBT) methodology adopted for the classification of chemicals in the context of (eco-)toxicological impacts. This classification methodology is cross-compared with a characterisation approach that provides a more complete model-based representation of the source-to-effect (or environmental) mechanism, but for fewer chemicals. To ensure that the quantity of the emission, and not just chemical hazard, is taken into account the comparison is based on a case study for the production of BDO (1,4-butanediol). Insights are presented independently for both the chemical processing stage, as well as from a broader life cycle perspective. Software available from:     

VOC emission reduction and energy efficiency in the flexible packaging printing processes: analysis and implementation

Volatile organic compound (VOC) emissions into the atmosphere are among the primary environmental problems caused by flexible packaging printing plants. Since 1999, VOC emissions from the use of solvents in various technological processes have been limited by the volatile organic compounds solvents emissions directive, and by directive 2010/75/EU on industrial emissions since 2010. Thus, flexible packaging plants require processing technologies or other solutions to ensure compliance with these requirements. In this paper, combined VOC pollution prevention and treatment alternatives were suggested and were evaluated for their technical, environmental, and economic feasibility. A flexible plastic packaging company that produces over 1920 t/year of plastic packaging for the food industry was selected for detailed analysis. The material and energy flow analysis shows that VOC emissions from the main technological processes reached 112.2 kg/t of production, and a considerable amount of energy (up to 771.6 kWh/t of production) was used. Three integrated pollution prevention and control (IPPC) alternatives of the five analysed in this study were selected and implemented within the company to reduce its VOC emissions and energy consumption. The results indicate that after the implementation of the three suggested economically reasonable IPPC alternatives (replacement of solvent-based with water-based inks; modernisation of the ventilation and lighting system), the VOC emissions decreased to 8.4 kg/t (92.5%) and the total energy consumption for the production of 1 t of flexible packaging decreased to 605.6 kWh/t (21.5%). This study shows that IPPC methods not only significantly reduces VOC emissions from flexible packaging printing processes, but also saves energy and raw materials, and reduces costs.     

How can electronics industries become green manufacturers in Taiwan and Japan

The world’s leading countries have reached a consensus concerning the need for environmental protection, and many international environmental protection rules and regulations have been implemented. Of these, the EU-legislated Restriction of the use of certain Hazardous Substances in electrical and electronic equipment (RoHS), Waste Electrical and Electronic Equipment (WEEE), and Eco-design of Energy-using Products (EuP) compel the electronics industry to incorporate waste disposal considerations in product design and manufacturing in order to benefit the environment. This study accordingly employed the ISO 14000 environmental management family’s ISO 14031 environmental performance evaluation (EPE) standards as an assessment framework, and investigated the types of factors influencing environmental performance, and their level of importance, when the electronics industry implements lead-free manufacturing. The study conducted a questionnaire survey of industry experts, scholars, and government officers in Taiwan and Japan—which constitute two of the world’s leading electronics product manufacturing centers—employing the Delphi method to extract assessment indicators, and using the Analytic Hierarchy Process (AHP) method to analyze indicators’ relative levels of importance. The results showed that the choice of lead-free substitute materials, soil heavy metal pollution, and compliance with environmental laws and regulations are the three important indicators of the environmental performance of lead-free manufacturing. As a consequence, when relevant industries adopt lead-free manufacturing in the future, they should first establish basic process technology, and also take their industries’ process characteristics and the suitability of substitute materials into consideration. In order to maintain compliance with laws and regulations, and to reduce pollution emissions, such industries should cooperate with government in connection with waste and wastewater treatment. In addition, apart from implementing environmental policies and testing standards, government can facilitate the realization of environmental protection policies and help conserve corporate resources by providing assistance, specialized training, and incentive measures to industry.     

Opportunities and Challenges of Artificial Intelligence for Green Manufacturing in the Process Industry

Smart manufacturing is critical in improving the quality of the process industry. In smart manufacturing, there is a trend to incorporate different kinds of new-generation information technologies into process-safety analysis. At present, green manufacturing is facing major obstacles related to safety management, due to the usage of large amounts of hazardous chemicals, resulting in spatial inhomogeneity of chemical industrial processes and increasingly stringent safety and environmental regulations. Emerging information technologies such as artificial intelligence (AI) are quite promising as a means of overcoming these difficulties. Based on state-of-the-art AI methods and the complex safety relations in the process industry, we identify and discuss several technical challenges associated with process safety: ① knowledge acquisition with scarce labels for process safety; ② knowledge-based reasoning for process safety; ③ accurate fusion of heterogeneous data from various sources; and ④ effective learning for dynamic risk assessment and aided decision-making. Current and future works are also discussed in this context.     

Recent advances in ion exchange materials and processes for pollution prevention

 Even though ion exchange technology is mature and widely employed in industry, new applications, approaches, and materials are emerging at a rapid pace. This article summarizes recent advances in ion exchange technology abstracted from presentations made at the Trends in Metal Adsorption Workshop held on May 5–6, 1998 in Cincinnati, OH co-sponsored by the United States Environmental Protection Agency (U.S. EPA), the American Institute of Chemical Engineers (AIChE), the Council for Chemical Research, and the United States Department of Energy (U.S. DOE). Additional information was obtained from reviews of U.S. EPA sponsored pollution prevention projects, panel discussions and workshops, user surveys, and the authors' discussions with practitioners in industry. The objectives of this article in the context of ion exchange applications were: (1) to review advances and applications of ion exchange; (2) to present an overview of commercially available ion exchange technology; and (3) to highlight areas for further research. Many of the advances discussed achieve improvement in ion exchange performance through the use of alternate support matrices or through the combination of technologies such as membranes or electric fields with ion exchange. Received: 8 October 1998 / Accepted: 15 Januar 1999     

Environmental and human health impact assessment of major interior wall decorative materials

Despite the growing interest in green products in the interior wall decorative material market, knowledge gaps exist because determining which product is more environmental and user friendly than the others is difficult. This work assesses the environmental and human health profiles of interior latex and wallpaper. Two interior latex products of different raw material ratios and one non-woven wallpaper product are considered. The environmental impact assessment follows life cycle assessment (LCA) methodology and applies Building Environmental Performance Analysis System (BEPAS). The human health impact is based on impact-pathway chain and is performed using Building Health Impact Analysis System (BHIAS). The assessment scope, associated emissions, and territorial scope of various emissions are defined to facilitate comparison study of interior wall decorative products. The impacts are classified into 15 categories belonging to three safeguard areas: ecological environment, natural resources, and human health. The impacts of categories are calculated and monetized using willingness to pay (WTP) and disability-adjusted life year (DALY) and summarized as an integrated external cost of environmental and human health impacts. Assessment results reveal that the integrated impact of interior latex is lower than that of non-woven wallpaper, and the interior latex of low quality causes low life cycle integrated impact. The most impacted categories are global warming, respiratory effects, and water consumption. Hotspots of product manufacturing are recognized to promote green product design.     

A process systems framework for rapid generation of life cycle inventories for pollution control and sustainability evaluation

Life cycle assessment (LCA) is a tool that aids in sustainable decision-making among product and process alternatives. When implementing LCA, the efficient and accurate modeling of chemical processes for life cycle inventory (LCI) generation is still challenging. Challenges include a lack of systematic design and simulation tools and approaches to develop chemical process models for obtaining and analyzing more realistic LCI results. In this contribution, a novel process systems framework is proposed for estimating LCI results when implementing pollution control technologies. This framework involves the development and incorporation of pollution control unit (PCU) modules into process simulation and generation of LCI data associated with the PCUs for use in a sustainability evaluation. Different pollution control modules are designed for rapid LCI estimation and applied to obtain emissions, utility consumption, material, and land footprint results related to waste streams of a process simulation. Then, the LCI results are analyzed with the objectives of minimizing the environmental impact and utility consumption. The proposed framework is illustrated via a biomass/coal gasification process for syngas production with the end goal of acetic acid manufacturing. Results associated with this case study show that the developed framework can provide guidelines for sustainable decision-making based on generated LCI results.     

有毒有害化学品环境污染及安全防治建议

文章简要介绍了国际上有毒有害化学品环境污染研究与安全防治的现状和趋势,同时对国内有关环境介质的污染状况作了分析。指出了这是一个国家的环境安全问题,阐述了它的重要性和紧迫性,建议组织力量进行调查研究,摸清国情,以便有针对性地制订法规标准,加强监管与防治。     

Environmental impact assessment in an uncertain environment

'Green' manufacturing has become an important issue in industry, driven by regulations governing manufacturing emissions, growing worldwide environmental certification requirements (ISO 14000) and an emerging consumer preference for ecolabel products. Establishing a quantitative and effective assessment model to assess the environmental impact of manufacturing processes for a product has become important. This paper focuses on analysing the uncertainty of weighting factors in an environmental impact assessment and applying fuzzy set theory to determine the vague or fuzzy weighting factors of the various environmental impact categories. A case study demonstrates that the fuzzy set-based model can effectively account for the vagueness and uncertainty of information being used for environmental impact assessments. The proposed fuzzy model is useful, not only for evaluating the environmental impact of a manufacturing process, but also for selecting processes when environmental impact is one of the factors to be considered.     

The role of deposition in limiting the hazard extent of dense-gas plumes

Accidents that involve large (multi-ton) releases of toxic industrial chemicals and form dense-gas clouds often yield far fewer fatalities, casualties and environmental effects than standard assessment and emergency response models predict. This modeling study, which considers both dense-gas turbulence suppression and deposition to environmental objects (e.g. buildings), demonstrates that dry deposition to environmental objects may play a significant role in reducing the distance at which adverse impacts occur--particularly under low-wind, stable atmospheric conditions which are often considered to be the worst-case scenario for these types of releases. The degree to which the released chemical sticks to (or reacts with) environmental surfaces is likely a key parameter controlling hazard extents. In all modeled cases, the deposition to vertical surfaces of environmental objects (e.g. building walls) was more efficient in reducing atmospheric chemical concentrations than deposition to the earth's surface. This study suggests that (1) hazard extents may vary widely by release environment (e.g. grasslands vs. suburbia) and release conditions (e.g. sunlight or humidity may change the rate at which chemicals react with a surface) and (2) greenbelts (or similar structures) may dramatically reduce the impacts of large-scale releases. While these results are demonstrated to be qualitatively consistent with the downwind extent of vegetation damage in two chlorine releases, critical knowledge gaps exist and this study provides recommendations for additional experimental studies.     

Selection and implementation of pollution prevention techniques in small and medium enterprises in countries in transition

This paper aims to open the discussion about the possibility and economic feasibility of applying pollution prevention techniques in industrial enterprises with smaller production capacities than those specified in Directive 2010/75/EU. The work refers to countries with transition economies where low cost of environmental resources and pollution fees are present. The research is conducted on pilot sample of seven small- and medium-size enterprises belonging to the food and beverage sector. The enterprises have different characteristics in terms of company size, capacity levels, production processes employed, and status of the transition in terms of their ownership status. The selection of appropriate prevention techniques is done using newly developed Method for Identification of Prevention Techniques (“MIP”). The MIP method combines: (i) Minimization Opportunities Environmental Diagnosis methodology developed by Regional Activity Center for Sustainable Consumption and Production Barcelona and its approach to data collection, (ii) United Nation Industrial Development Organisation’s step-by-step approach to environmental diagnosis of industrial enterprises, (iii) Driving Forces, Pressure, State, Impact, Response Framework used by European Environmental Agency to facilitate problem–solution identification, (iv) Multicriteria ranking method for selection of best available techniques, and (v) Philosophy of Shewhart–Deming’s circle to introduce the system of planning, control, and correction and integrate prevention concept into business policy. This provided necessary flexibility corresponding to companies’ abilities to finance implementation. The results confirmed that the pollution prevention concept can be applied to small- and medium-sized companies of different production capacities and organization levels with both environmental and economic benefits.     

Research integrity: a government perspective.

What is research integrity? At the United States Environmental Protection Agency (U.S. EPA) research integrity can be defined as conducting and fostering research to define, anticipate, and understand environmental problems; and generating sound, appropriate, credible, and effective solutions to those problems. Whether in government, academia, or industry, integrity is required at all stages of research--from data generation to data analysis. What constitutes research integrity? Simply put, Did we do the right thing? Did we do it the right way? Did we honestly document what we did? This is especially important if the research is used as a basis for public policy. The extensive and intensive use of the results of science in EPA's standard setting, regulatory, and enforcement responsibilities means that scientific misconduct can lead to costly and inappropriate actions through unnecessary expenditure or inadequate protection. The soundness, effectiveness, and credibility of EPA's regulations ultimately rest on the scientific and technical bases for these actions. Careful attention to research record keeping can help ensure data quality and integrity. The U.S. Environmental Protection Agency, its research requirements, and the work of the National Health and Environmental Effects Research Laboratory are discussed below.     

Preparation of artificial aggregate using waste concrete powder and CO2 fixed by microorganisms

Clean Technologies and Environmental Policy - High carbon emissions, shortages of natural aggregates and environmental pollution of waste concrete powder (WCP) have become open issues for the...     

Evaluation of cleaner production audit in pharmaceutical production industry: case study of the pharmaceutical plant in Dalian,P. R. China

The pharmaceutical industry in China makes an important contribution to the national economy. However, the associated pollution problems cause gradual deterioration of the environment and impact adversely on the local community. Cleaner production (CP) technology, an effective way to reduce waste emission and save resources, has been widely employed in the pharmaceutical industry in the developed countries. Such technologies have been applied in a number of factories in China, although there is no integrated assessment and implementation procedure for implementing CP technologies in pharmaceutical plants. To solve such problems, a series of CP options are proposed and assessed here. CP is a powerful tool for decreasing waste production, limiting environmental pollution and natural resource depletion. Moreover, the return on investment in CP is quick, so it would seem that CP activities should be very much in demand by enterprises. Reality is less optimistic: frequently only limited interest is expressed, even after an explanation; business people hesitate to become actively involved. The processes in the pharmaceutical production industry produce a vast amount of waste, including wastewater with high concentrations of organic substances (the principal component), solid waste, and organic off-gas. To solve such problems, a series of CP options are proposed and assessed in this study. Having consideration to environmental impacts and economic efficiency, four groups of medium/high cost CP options were screened in an integrated assessment. To verify the proposed options, a case study was conducted in Degussa Luyuan, Northeast China. The characteristics of resource consumption and waste emission during the production process were identified. The proposed options were evaluated according to different aspects. An integrated CP system based on the proposed options was designed and then implemented in the factory. In three years of practical use, the productivity and quality of alcohol product were improved, with a reduction in waste and pollution and a marked increase in water/energy savings. This study provides theoretical and practical support for the extensive application of CP technologies and sustainable development in China’s pharmaceutical industry. These methods include ways to clean up production that are incorporated in the process design, reforming present production technologies, updating the equipment, exploiting new producing flowcharts, using cleaner energy, building recycling into the manufacturing process, recycling waste, enhancing management, developing environmental protection technology, and ensuring satisfactory end-of-pipe disposal.     

Energy sub-modules applied in life-cycle inventory of processes

 The heating and cooling of unit processes (utilities) are often the most significant energy fraction of a gate-to-gate life-cycle inventory (LCI) for individual chemicals. Electricity usage is typically a smaller factor. An LCI of a manufacturing process for a specific chemical has been used to identify the heating and cooling requirements. This paper demonstrates the sub-modules used to convert these utilities into actual energy-related emissions for use in the LCI of a specific chemical. Assumptions and results of the unit operation inventory data and of the potential life-cycle burdens are clearly stated, to foster the objective of transparency. A user may substitute another energy grid, fuel sources, or efficiencies based on some site-specific data. The sub-modules utilize a design basis for calculating the utility emissions. Results may be used in LCI studies in the chemical, biochemical, and pharmaceutical industries. Received: 30 August 1999 / Accepted: 20 November 1999     

Runaway chemical reaction exposes community to highly toxic chemicals

The U.S. Chemical Safety and Hazard Investigation Board (CSB) conducted a comprehensive investigation of a runaway chemical reaction at MFG Chemical (MFG) in Dalton, Georgia on April 12, 2004 that resulted in the uncontrolled release of a large quantity of highly toxic and flammable allyl alcohol and allyl chloride into the community. Five people were hospitalized and 154 people required decontamination and treatment for exposure to the chemicals. This included police officers attempting to evacuate the community and ambulance personnel who responded to 911 calls from residents exposed to the chemicals. This paper presents the findings of the CSB report (U.S. Chemical Safety and Hazard Investigation Board (CSB), Investigation Report: Toxic Chemical Vapor Cloud Release, Report No. 2004-09-I-GA, Washington DC, April 2006) including a discussion on tolling practices; scale-up of batch reaction processes; Process Safety Management (PSM) and Risk Management Plan (RMP) implementation; emergency planning by the company, county and the city; and emergency response and mitigation actions taken during the incident. The reactive chemical testing and atmospheric dispersion modeling conducted by CSB after the incident and recommendations adopted by the Board are also discussed.