THE 82S1/2→62D EXCITATION TRANSFER OF RUBIDIUM ATOMS INDUCED BY COLLISIONS WITH GROUND-STATE RUBIDIUM AND HYDROGEN MOLECULES

The processes of excitation transfer from the 8²S_1/2 state to the 6²D state of rubidium in Rb(8²S_1/2)-Rb(5²S_1/2) and Rb(8²S_1/2)-H₂ collisions have been studied experimentally. During irradiating the Rb vapor, mixed with H₂, by two light beams for selective stepwise excitation, the Rb 8²S_1/2→5²P_3/2 direct fluorescence and the Rb 6²D_3/2→5²P_1/2 sensitized fluorescence have been measured as a function of H₂ gas pressure. The measurements yielded the cross-sections σ(8²S_1/2→6²D) and σ^*(8²S_1/2→6²D) of Rb 8²S_1/2→6²D excitation tranfer induced by collisions with 5²S_1/2 atom and H₂ molecules respectively. The results are discussed in detail.     

THE 82S1/2→62D EXCITATION TRANSFER OF RUBIDIUM ATOMS INDUCED BY COLLISIONS WITH GROUND-STATE RUBIDIUM AND HYDROGEN MOLECULES

The processes of excitation transfer from the 8²S_1/2 state to the 6²D state of rubidium in Rb(8²S_1/2)-Rb(5²S_1/2) and Rb(8²S_1/2)-H₂ collisions have been studied experimentally. During irradiating the Rb vapor, mixed with H₂, by two light beams for selective stepwise excitation, the Rb 8²S_1/2→5²P_3/2 direct fluorescence and the Rb 6²D_3/2→5²P_1/2 sensitized fluorescence have been measured as a function of H₂ gas pressure. The measurements yielded the cross-sections σ(8²S_1/2→6²D) and σ^*(8²S_1/2→6²D) of Rb 8²S_1/2→6²D excitation tranfer induced by collisions with 5²S_1/2 atom and H₂ molecules respectively. The results are discussed in detail.     

EXPERIMENTAL STUDY OF EXCITATION AND IONIZATION CROSS SECTIONS OF ATOMS AND MOLECULES BY ELECTRON COLLISIONS

About ten groups over universities and institutes are engaged in thevariety of experimental studies on electron-atom and electron-moleculecollisions in Japan.From works by these groups,two different topics,     

APPLICATION OF CORRELATION—POLARIZA TION POTENTIAL TO THE LOW—ENERGY ELECTRON SCATTERING WITH ATOMS AND MOLECULES

Applicability of the correlation potential,which is currently used in the local density functional theory,to the low-energy electron-atom and molecule scattering is investigated with some examples of scattering processes.     

反应N(2D)+H2→NH+H和N(2D)+D2→ND+D的立体动力学理论研究.

基于Ho等人的精确势能面(J. Chem. Phys. 119, 3063(2003))研究,运用准经典轨线方法计算了21.3 kJ/mol碰撞能下反应N(²D)+H₂→NH+H和N(²D)+D₂→ND+D的产物与反应物之间的矢量相关．发现两个反应的产物角分布都是前向和后向呈现峰值分布,产物的转动角动量矢量j′不仅是取向的,而且是在y轴负方向上定向的．两个反应显示出的同位素效应主要归因于同位素质量的差别．     

OPTICAL-OPTICAL DOUBLE-RESONANCE EXCITATION SPECTRA OF THE (6d)1Πg, (7d)1Πg HIGH-LYING RYDBERG STATES IN Na2

Two ¹Π_g states of Na₂ for v≤13 have been observed by using optical-optical double resonance (OODR) fluorescence excitation spectroscopy. The intermediate levels in B¹Π_u state are identified by the numerical calculations with the molec-ular constants for B¹Π_u←X¹Σ_g⁺ transitions and confirmed by the complemen-tary A¹Σ_g⁺←X¹Σ_g⁺ polarization spectra. Absolute vibrational numberings of the (6d)¹Π_g and (7d)¹Π_g states are determined by comparing the experimental OODR excitation intensities with the simulated Franck-Condon factors. The Dnnham coef-ficients and the Rydberg-Klein-Rees (RKR) potential energy curves of the (6d)¹Π_g, (7d)¹Π_g states are reported.     

镱原子超精细诱导5d6s 3D1,3→6s2 1S0 E2跃迁及超精细常数的精确计算

在镱原子中,利用5d6s³D₁→6s²¹S₀跃迁探索宇称破缺效应已经得到了深入的研究.但是5d6s³D₁态与基态6s²¹S₀之间的M1跃迁和超精细诱导E2跃迁很大程度上影响了宇称破缺信号的探测.因此,很有必要精确计算5d6s³D₁态与基态6s²¹S₀之间的M1跃迁和超精细诱导E2跃迁的跃迁概率.本文利用多组态Dirac-Hartree-Fock理论精确计算了5d6s³D₁→6s²¹S₀ M1跃迁和超精细诱导5d6s³D_1,3→6s²¹S₀ E2跃...     

H+CH→H2+C（1D）反应的立体动力学研究

利用从头计算的对称性为1A′的势能面,用准经典轨线（QCT）方法在不同的碰撞能下研究了反应H+CH→H₂+C（¹D）的产物和反应物的矢量相关性质.在质心系下计算了四个极化微分反应截面.计算并讨论了描述k和j′夹角分布关系的P（θ_r）和描述k-k′-j′三者的二面角分布关系的P（（?）_r）.计算结果表明势能面上的深势阱和不同的碰撞能对产物分子H₂有重要影响.     

THE STUDY OF α-EMISSION INDUCED BY 16O ON 27Al

The α-particles induced by 84.5MeV and 62 MeV ¹⁶O on ²⁷Al are measured using ΔE-E semiconductor telescope. The energy spectra, the angular distributions, the contour plot of d²σ/dE﹒dΩ in the E-θ plane of the emitted α particles and the variation of the nuclear temperature with the emission angles are obtained. The mechanism of the direct α particles is discussed.     

Relativistic calculations of 3s2 1S0-3s3p 1P1 and 3s2 1S0-3s3p 3P1,2 transition probabilities in the Mg isoelectronic sequence

Using the multi-configuration Dirac-Fock self-consistent field method and the relativistic configuration-interaction method,calculations of transition energies,oscillator strengths and rates are performed for the 3s 2 1 S 0-3s3p 1 P 1 spinallowed transition,3s 2 1 S 0-3s3p 3 P 1,2 intercombination and magnetic quadrupole transition in the Mg isoelectronic sequence(Mg I,Al II,Si III,P IV and S V).Electron correlations are treated adequately,including intravalence electron correlations.The influence of the Breit interaction on oscillator strengths and transition energies are investigated.Quantum electrodynamics corrections are added as corrections.The calculation results are found to be in good agreement with the experimental data and other theoretical calculations.     

ONE-BODY DENSITIES AND FEATURES OF THE STRUCTURE OF THE 2S+1Pe DOUBLY EXCITED HELIUM STATES

The qualitative features of electron-electron correlation of the 2S+1Pe doubly excited helium states have been investigated. The anisotropism of the electronic cloud has been shown. A comparison has been made between the S=1 and S=0 states. The structures among the states, which belong to the same rotorlike supermultiplet, have also been compared with each other.     

ELECTRON-ELECTRON CORRELATION IN THE HELIUM 3De DOUBLY EXCITED STATES

The qualitative features of the electron-electron correlation in the helium ³D^e doubly excited states have been investigated via an example of the N = 3, n=4 series. The angular, radial-angular and radial-radial correlations have been shown in detail and the anisotropism of the electronic cloud has been found. The features of the ³D^e states have been compared with those of the L≤1 states.     

氦原子1Se双激发态的强径-径关联区

本文详细地研究了氦原子¹S^e态N=3序列内的电子-电子关联。探索并确认了K分类的几何内涵。发现了“强径-径关联区”的存在,其中两个电子的径向运动呈强烈的反位相耦合。 关键词：     

ELECTRON-ELECTRON CORRELATION IN THE HELIUM 3De DOUBLY EXCITED STATES

The qualitative features of the electron-electron correlation in the helium ³D^e doubly excited states have been investigated via an example of the N = 3, n=4 series. The angular, radial-angular and radial-radial correlations have been shown in detail and the anisotropism of the electronic cloud has been found. The features of the ³D^e states have been compared with those of the L≤1 states.     

氦原子1Se态的分波分析和强径——角关联区

氦原子的哈密顿量在四个空间的并空间内被对角化从而得到诸¹S^e态的解。对波函数进行了仔细的分析,找出了内部结构的一些特征。 关键词：     

He+离子和Ne原子碰撞过程中激发态的研究

在He⁺离子和Ne原子碰撞过程中,我们发现两种碰撞激发过程,一种是电子俘获激发过程,另一种是直接激发过程。本实验用光学多道分析系统(OMA)对这些过程进行了光学测量,给出了发射截面数据。入射离子实验室能量范围为70—150keV。 关键词：     

He+离子和Ar原子碰撞过程中激发态的研究

在He⁺离子和Ar原子碰撞过程中,同样存在着电子俘获激发和直接激发两种过程。本文把实验结果同He⁺离子和Ne原子碰撞体系进行了比较,发现:在入射离子速度较小时,实验所得到的Hel三重态发射截面要大得多;当入射离子He⁺的速度大于一个原子单位(2.2×10⁸cm/s)时,情况则相反。因此,在俘获电子过程中,势能亏损同He⁺离子的入射速度是两个非常重要的因素,而且它们之间存在一个竞争过程。入射离子He 关键词：     

HYLLERAASIAN WAVE FUNCT/ON OF 2s2 1S OF HELIUM

A variatioual calculation of the energy of the 2s^{2 1}S state of helium has been carried out with the use of a wave function of the Hylleraasian type. The wave function is ψ=e^-0.2278s{1-0.17079s-0.063155u-0.013869t² +0.010044u²+0.0064785s²} where s,t u are in units of 4 times the first Bohr radius of hydrogen. The energy is E(2s^{2 1}S)=-1.5412Rh. compared with the value -1.4400 Rh obtained by the method of self-consistent field.     

高双激发Intershell共振态的辐射和Auger跃迁率

采用Conventional infiguration(简写为CI)方法计算了类氦Ar¹⁶⁺离子高双激发Intershell(n>N)共振态的辐射和Auger跃迁率,并利用超球坐标方法和新量子数_n(K,T)_N^A2s+1L^π来作系统分析。计算结果表明,对A=+1态,Auger过程是主要的,辐射过程仅仅是对给定的多重簇(manifold)中更高的态才有意义。对A=0,-1态,Auger宽度更小。对这些 关键词：     

Ar2+与Li,Na原子碰撞中单电子俘获过程的实验研究

对Ar²⁺与Li,Na碰撞过程中由于单电子俘获而产生的ArII谱线进行了绝对测量,给出各谱线的发射截面数据。入射离子能量为40—300keV。从发射截面对势能亏损的依赖关系,发现对应中等△E(>0)值的过程具有较大的截面。并且还发现与观察到的光谱线相应的激发态属于一个电子组态中高J量子数的态。 关键词：