Polychlorinated dibenzo-p-dioxins （PCDDs） and dibenzofurans （PCDFs） in surface sediment and bivalve from the Changjiang Estuary, China

Surface sediments and bivalves were collected from the Changjiang Estuary in December 2003 and November 2004, respectively. Polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) in these samples were measured with high-resolution chromatography (HRGC)/High Resolution Mass Spectrometer (HRMS). The concentrations of total PCDD/Fs and toxic equivalent (TEQ) were 169.83±119.63 and 0.81±0.36 pg/g dry weight (dw) in sediments, and 580.33±240.17 and 7.24±3.65 pg/g dw in bivalves. The homolog compositions of PCDD/Fs were similar among samples, the most abundant congener was octa-chlorinated dibenzo-p-dioxin (OCDD) and then octa-chlorinated dibenzofuran (OCDF) and 1,2,3,4,6,7,8-hepta-chlorinated dibenzo-p-dioxin (HpCDD). The herbicide pentachlorophenol (PCP) and sodium pentachlorophenol (Na-PCP) were proved the main source of PCDD/Fs in this area.     

ANNUAL LAMINATIONS IN THE SEDIMENTS OF HONGFENG LAKE, CHINA

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Comparison between BCR sequential extraction and geo-accumulation method to evaluate metal mobility in sediments of Dongting Lake,Central China

The form in which a metal exists strongly influences its mobility and thus, the effects on the environment. Operational methods of speciation analysis, such as the use of sequential extraction procedures, are commonly applied. The Dongting Lake, the second largest fresh-water lake in China, contains three China wetlands of international importance, the East Dongting Lake, South Dongting Lake, and West Dongting Lake. In this work, an optimized BCR sequential extraction procedure was used to assess the environmental risk of Cd, Cr, Cu, Ni, Pb and Zn in contaminated sediment of the Dongting Lake. The procedure was evaluated by using a certified reference material, BCR701. The results of the partitioning study indicated that in the lake sediments, more easily mobilized forms （acid exchangeable） were predominant for Cd, particularly in the samples from the East Dongting Lake. In contrast, the largest amount of Pb was associated with the iron and manganese oxide fractions and Cu, Zn, Cr, and Ni analyzed were mainly distributed in residual phase at an average percentage greater than 60% of the total metals. The potential risk to the lake＇s water contamination was highest in the East Dongting Lake based on the calculated contamination factors. On the other hand, the total metal content was determined as well by inductively coupled plasma and mass spectrometry （ICP-MS） and assessed by using geo-accumulation index. The assessment results using geo-accumulation index were compared with the information on metal speciation. Both were correspondent with each other.     

Application of MODIS data in monitoring suspended sediment of Taihu Lake,China

Application of MODIS in ocean color is mainly based on bands 8-16 with the spatial resolution of 1 000 m.This spatial resolution,however,can not meet the application demand of inland waters where the areas are relatively small.With the assumption of the black water at shortwave infrared(SWIR) wavelengths(>1 000 nm),we first propose an atmospheric correction method for bands 1 and 2 with their spatial resolution of 250 m,and we then establish a quantitative retrieval model for suspended sediment concentratio...     

Chronology and nutrients change in recent sediment of Taihu Lake,lower Changjiang River Basin,east China

Two short sediment cores named ZS and THS dated by the 210Pb or 137Cs method were collected from the northwest and southwest of Taihu Lake respectivly,and total organic carbon(TOC) and nutrients including total nitrogen(TN) and total phosphorus(TP) were determined to analyze the chronology and nutrients change in recent sediment.The results show that 137Cs activities are low(less than 15 Bq/kg) in the two cores,attributed to the 137Cs migration.Based on 210Pb constant rate of supply(CRS) model,the sedimentation accumulation rates range from 0.13 g/(cm2·yr) to 0.76 g/(cm2·yr) in the ZS core,and from 0.10 g/(cm2·yr) to 0.56 g/(cm2·yr) in the THS core.A remarkable increase in organic matter and nutrients has occurred in the two dated cores since the mid-1980s.The historical changes of organic matter and nutrients in the two cores are consisitent with the monitoring data for surface sediment after the 1960s.The TP accumulation rates after the early 1980s are 0.97 and 0.92 times higher than those from the 1950s to the 1980s in ZS and THS cores,respectively.Higher TP concentrations in the past two-decade deposits of Taihu Lake are due to both diagenetic factors and human activities.     

Assessment of heavy metal pollution in estuarine surface sediments of Tangxi River in Chaohu Lake Basin

A total of 30 surface sediments samples from the estuary wetland of the Tangxi River, Chaohu Lake Basin were obtained and tested. Enrichment factor (EF) and geoaccumulation index (I_(geo)) as well as multivariate statistical analysis methods including Factor Analysis (FA) and Hierarchical Cluster Analysis (HCA) were applied for the assessment of heavy metal pollution in surface sediments. The results of EF values show that the pollution of copper (Cu) and cadmium (Cd) occurs in the estuarine sediments, and that zinc (Zn), lead (Pb) and chrome (Cr) may originate from crustal materials or natural weathering process. The mean EF values of the five heavy metals are in the decreasing order: Cu>Cd>Zn>Pb>Cr. Based on the I_(geo) of target heavy metals, the surface sediments collected from the study area can be approximately categorized as unpolluted with Zn, Pb and Cr, and moderately polluted with Cu and Cd. The degree of heavy metal pollution decreases in the order of Cu>Cd>Zn>Pb>Cr. Three groups of pollution factors are presented from FA: Zn-TOC, Cu-Cd and Cr-Pb, which respectively accounte for 27.22%, 25.20% and 21.05% of variance. By means of HCA, a total number of seven groups are distinguished from 30 sampling sites. Results indicate that Cu and Cd are the prior controlled pollutants in the estuarine sediments of the Tangxi River.     

Paleoclimatic Change Inferred from Carbon Isotope Composition of Organic Matter in Sediments of Dabusu Lake, Jilin Province, China

Study on the organic compounds and stable isotope composition of a sediment section in Dabusu Lake revealed that the organic materials in the sediments came mainly from terrestrial plants brought into the lake by rtmoff.The δ^13 C of the organic materials had high values during warm-dry climatic stages and decreased in cold-wet stages.Analysis of data on carbonate content and ^14C age showed that the lake basin had experienced several wet-cold and warm-dry climatic cycles since 15000 a BP. Since 6700 a BP, the climate reached a relatively stable warm-dry stage,so that the lake water was gradually condensed and finally a saline lake was formed.     

Distribution and accumulation characteristics of heavy metals in sediments in southern sea area of Huludao City, China

The southern sea area of the Huludao City, Liaoning Province might be polluted by heavy metals because it is close to the Jinzhou Bay, one of the heaviest sea area polluted by heavy metals in China. The undisturbed modern sediment core can be used to analyze the accumulation and source of the pollutants using 137 Cs and 210 Pb ex . Thirty-five samples of surface sediment and two core sediments were collected from the southern sea area of Huludao City. The concentrations of copper (Cu), lead (Pb), chrome (Cr), zinc (Zn), arsenic (As) and mercury (Hg) in the surface sediments as well as Cu, Pb, Zn, Cr, 137 Cs and 210 Pb ex in the core sediments were determined to research the spatial distribution and accumulation characteristics, and to analyze the sources and the potential risks of heavy metals. The results show that the pollution levels of Zn and Hg are serious, and 26 stations are at moderate or heavy ecological risks. The concentrations of the heavy metals increase from east to west, as well as from open sea to offshore marine area. The concentrations of heavy metals are not high in the sediments adjacent to the Jinzhou Bay, and the influence caused by the seawater exchange with the Jinzhou Bay is little. The concentrations of the heavy metals in the core sediments show low-high-low characteristic, and it coincides with the pollution history of Huludao City. The atmospheric deposition of heavy metals from the Huludao Zinc Plant is likely to be the main source of pollution without direct discharge of wastewater. The high concentrations of heavy metals appear on the upper sediment of 20 cm. The shallow sediment with high heavy metal contents might be exposed to surface when it was disturbed by the ocean engineering and big storm surge, then cause risk to the safety of aquaculture and human healthy.     

Flume simulation of wave-induced release of internal dissolved nitrogen in Taihu Lake, China

A wave flume simulator was used to study internal nitrogen release from the surface sediment collected from Taihu Lake,China.Particulate nitrogen concentrations were positively correlated with the concentrations of suspended solids,primarily from surface erosion related to the shear stress and duration of wave action.In response to 4 cm-and 10 cm-high wave production representing waves generated in Taihu Lake by gentle and gusty winds,respectively,the mean dynamic release rate of ammonium(NH+4) from the sediment to the overlying water was 1×10-3 mg/(m2.s) and the NH4+ concentration in the overlying water increased by 0.016 mg/L,indicating that waves resulting from strong wind can induce the rapid release of dissolved nitrogen from Taihu Lake sediments.The decrease in interstitial NH+4 concentrations at all sediment depths was associated with an increase in NH4+ concentrations in the overlying water by 0.01 mg/L,showing that sediment below the eroded layer was the main source of internal nitrogen release.Changes in the interstitial dissolved oxygen and NH+4 concentrations showed that wave-induced pore water movement can greatly increase the diffusion rate,and that these effects can influence the sediment to a depth of at least 15 cm.Diffusion induced by pore water movement may be very important for the formation of an active sediment layer in Taihu Lake.     

Application of geophysical-geochemical method in verification of stream sediment anomaly in Baoxinggou area of Heilongjiang

Baoxinggou area is located in northern Daxing'anling. In this area,comprehensive use of geophysical and geochemical exploration methods plays an important role in the prospecting,and has yielded some application results so far. Based on the 1 /100 000 stream sediment anomaly survey,the methods of 1 /20 000 soil geochemical measurement,trenching engineering on the earth's surface and 1 /10 000 IP intermediate gradient survey were all used to verify and decompose drainage anomalies,as well as to find and locate ore bodies. In this way,an effective,economical and quick prospecting method was concluded,which focuses on the middle and lower mountain forest swamp landscape in the northern part of Daxing'anling,and provides reference for the prospecting in the area.     

A 16 ka climate record deduced from δ^13C and C/N ratio in Qinghai Lake sediments, northeastern Tibetan Plateau

1 INTRODUCTION δ13C in organic matters from lacustrine sedi- ments varies with several factors including aquatic plants, vegetation type in the catchment, atmos- pheric CO2 concentration, climate (temperature and precipitation), and properties of water, …     

Phosphorus speciation in sediments of Lake Hongfeng, China

This study was conducted to evaluate the distribution characteristics of phosphorus and its species in 14 sediments samples collected from Lake Hongfeng based on sequential extraction. Lake Hongfeng, a major drinking-water source for Guiyang City in southwestern China, is one of the largest artificial reservoirs located in a typical karstic area of the Yunnan-Guizhou Plateau. The results of this study indicate that the average percentages of DP, Al-P, Fe-P, Ca-P and OP in the lake sediments were 0.52, 6.59,...     

A 3600 years paleoclimatic change inferred from organic δ13C and TOC/TN of the Gucheng Lake sediments, southeast China

A 6.2 m thick core of Gucheng Lake sediment provided a 3600 years record of climate change. The contents of the TOC in the core changed from 2.63% to 8.48%, and the δ¹³C values of organic matter were from −21.54% to −27.3%. The TOC/TN ratios indicated that the organic materials in sediments were from lake plankton and land-derived plants. The 2.9–22 m core interval with high TOC/TN ratios, low δ¹³C values and low contents of TOC indicated a cold climate stage. The 6.2–5.5 m and 0.4–0.1 m intervals were characterized by low TOC/TN ratios, high δ¹³C values and high contents of TOC, and reflected temperate climate stages. Project 49372129 supported by NSFC.     

Recent sedimentation and suspended matter in Erhai Lake, Yunnan Province, China

INTR0DUCnONErhailake,thesecondlargestlakeintheYUnnanPlateauinS0uthWstChina,islo-catedinDaliDefecthe25035'to25"58'N,looo05't0l(X)o07'E(Fig.l)-The40kInlong3-9kInwidelakeisnaInedafteritsearlikeshape.ItsbasicchimteristicsaregiveninTablel.EtheibeeisampicalriftlakeintheDalibasinwhichdeveloPedalongtheYuaniangHongheThewestsideofthebasinisformedbytheDiancangMountainwhichconsists0frock(PrecaInbrianschistandgneissandMiocenemetaInrphiclimestone).TheseisndcallystillactivemoUntainrangrisab0ut…     

Heavy metal distribution in sediments of Muthupettai mangroves, south east coast of India

Core sediments from the Muthupettai mangroves on the southeast coast of India were analyzed for soil texture,total nitrogen,organic carbon,phosphorus and heavy metals(Fe,Mn,Cr,Cu,Ni,Pb,Zn and Cd).The distinct seasonal variation in the distribution of metals in the sediments was observed.The minimum concentration was recorded in river mouth and the maximum was in lagoon.High metal concentration in sediment was observed during monsoon and low concentration in summer.The total nu-trient in lagoon and river mouth was recorded in the range of 4.528 to 8.526 mg g-1 for organic carbon,2.213 to 10.5 mg g-1 for nitro-gen and 0.824 to 7.22 mg g-1.     

Phytoplanktonic desmids community in Donghu Lake, Wuhan,China

1 INTRODUCTION Donghu Lake (30o33′N, 114o23′E) is a shallow medium sized freshwater lake in Wuhan City, Hubei Province, China and about 5 kilometers away from the Changjiang (Yangtze) River. Before the 1960s, the water surface area was about 27.8 km2. The lake water was clear and the pH ranged from 6 to 7. The shallow area of the lake abounded with macrophytes. The phytoplanktonic and peripheral desmids were very abundant also in this lake. In the late 1960s, Donghu Lake with tota…     

MODERN CLIMATIC SIGNALS DEDUCED FROM STABLE ISOTOPE IN SHELLS IN XINGCUO LAKE SEDIMENTS,EAST TIBETAN PLATEAU,CHINA

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Comparative study on rain splash erosion of representative soils in China

As the first event of soil erosion, rain splash erosion supplies materials for subsequent transportation and entrainment. The Loess Plateau, the southern hilly region and the Northeast China are subject to serious soil and water loss; however, the characteristics of rain splash erosion in those regions are still unclear. The objectives of the study are to analyze the characteristics of splash erosion on loess soil, red soil, purple soil and black soil, and to discuss the relationship between splash erosion and soil properties. Soil samples spatially distributed in the abovementioned regions were collected and underwent simulated rainfalls at a high intensity of 1.2mm/min, lasting for 5, 10, 15, and 20min, respectively. Rain splash and soil crust development were analyzed. It shows that black soil sample from Heilongjiang Province corresponds to the minimum splash erosion amount because it has high aggregate content, aggregate stability and organic matter content. Loess soil sample from Inner Mongolia corresponds to the maximum splash erosion amount because it has high content of sand particles. Loess soil sample from Shanxi Province has relatively lower splash erosion amount because it has high silt particle content and low aggregate stability easily to be disrupted under rainfalls with high intensity. Although aggregate contents of red soil and purple soil samples from Hubei and Guangdong provinces are high, the stability is weak and prone to be disrupted, so the splash erosion amount is medium. Splash rate which fluctuates over time is observed because soil crust development follows a cycling processes of formation and disruption. In addition, there are two locations of soil crust development, one appears at the surface, and the other occurs at the subsurface.     

Hyper-spectrum models for monitoring water quality in Dianshan Lake,China

The correlation between water quality parameters and hyper-spectral reflectance is studied with models established for each parameter and applied in Dianshan Lake, in the upstream of the Huangpu River running through Shanghai, China. Models are for dissolved oxygen (DO in mg/L): R720/R680 = 20.362×(R720/R680)2-31.438×(R720/R680)+19.156; for turbidity (NTU): R*714.5 = 206.07× (R*714.5)2-582.5×R*714.5 + 423.24; and for total phosphorus (TP in mg/L): R*509.5 = 16.661× (R*509.5)2-32.646×R*509.5+16.116. The R2 values are 0.770 8, 0.660 4 and 0.738 7, respectively, showing strong positive relationships. The models were then applied to assess water quality of different times. Results are quite satisfactory for some samples.