粉煤灰掺量对相同浆体体积比砂浆性能的影响

为了研究粉煤灰掺量对砂浆性能的影响,采用相同浆体体积比,分别以0％、10％、20％和30％的粉煤灰掺量配制砂浆,进行强度和碳化深度对比试验.结果表明,当水胶比一定时,随粉煤灰掺量的增加,砂浆的流动性不会明显降低;早期掺粉煤灰的水泥砂浆的强度会随着粉煤灰掺量的增加而降低,但其后期强度随着龄期的增长会逐渐提高并超过未掺粉煤...     

减水剂对高掺量粉煤灰砂浆性能的影响

研究了萘系高效减水剂（FDN）和木质素磺酸钙（LS）对高掺量粉煤灰砂浆性能的影响,测定了减水剂在胶凝颗粒表面的吸附、对水泥颗粒表面zeta电位等方面的影响。结果表明,和FDN相比,LS对砂浆的减水率较低,而对砂浆流动度保持能力较优;当掺量为0.4 wt%时,两者对砂浆稳定性的影响几乎一样。当掺量低于0.4 %时,LS的减水率和FDN接近是因为其具有较强的引气作用和FDN在胶凝颗粒表面吸附不完全;LS保持砂浆流动性能力较好是由于它的缓凝作用以及吸附LS的水泥颗粒表面zeta电位较稳定导致的。为了更好地将LS应用在高掺量粉煤灰砂浆中,可以从提高其减水率方面对其进行改性。     

大掺量粉煤灰混凝土抗碳化性能研究

根据影响混凝土碳化的主要因素和粉煤灰混凝土的特点,研究了对粉煤灰进行磨细和增加适量熟石灰的措施,在不降低粉煤灰混凝土强度前提下,探讨改善大掺量粉煤灰混凝土抗碳化性能的可行性。     

大体积混凝土施工配合比中粉煤灰最优掺量

利用粉煤灰掺量对混凝土的抗压强度和抗拉强度的影响,确定粉煤灰的最优掺量,为大体积混凝土施工配合比中的粉煤灰掺量提供了理论依据．     

掺粉煤灰对混凝土性能的影响

阐述了掺粉灰对混凝土性能影响的需水性原理和结构密实化原理，并为解决实际应用问题提供了思路。     

粉煤灰掺量及纤维体积率对ECC基本力学性能及断裂性能的影响

为研究粉煤灰掺量及纤维体积分数对ECC基本力学性能及断裂性能的影响,对不同粉煤灰掺入量和纤维体积分数的ECC进行了抗压强度和拉伸性能试验,并基于DIC进行了抗折和断裂性能试验。结果表明：大量粉煤灰的掺入提高了ECC的断裂韧性,但其各项强度及断裂能均有所下降;当掺入的纤维体积分数在1%～2%时,可以有效提高ECC的强度和断裂性能,增加拉伸应变的同时保证试件的完整性。当水泥与粉煤灰比例为1.2,纤维体积分数为2%时,在使ECC保持较高强度的同时还可以较大幅度改善一般混凝土所具有的“脆性”,使其具备较好的抗变形能力。     

高掺量粉煤灰对烧结坯体性能及工艺影响的试验研究

提高粉煤灰在烧结坯体中的掺量,虽然对节土、节能、利废、环保等方面的意义重大,但由于粉煤灰颗粒松散,瘠性强,烧结温度高等方面的特点,必然带来生产工艺方面的问题。本研究不仅探索出除少量黏土外,不掺任何外加剂的烧结坯体,在保证烧结普通砖主要性能指标的基础上,粉煤灰的掺量可达80%,同时探索了相应坯体的成型压力,烧结温度等工艺问题。     

大掺量粉煤灰混凝土抵抗碳化和钢筋锈蚀研究

通过在不同胶凝材料用量、不同粉煤灰掺量和不同水胶比下大掺量粉煤灰混凝土碳化和钢筋锈蚀试验,明确了其抵抗碳化和钢筋锈蚀的基本条件.结果显示水胶比是关键条件,只要保证足够低的水胶比,大掺量粉煤灰混凝土具有优异的耐久性.     

フライアッシュを用いたコンクリ一トの中性化に及ぼす暴露条件の影響

This report gathered measurement results about the carbonation of concrete using fly-ash. In Series Ⅰ, comparison among outdoor exposure area, the type of fly-ash and replacement ratio was made. In Series Ⅱ, comparison among the direction of the test piece, exposure place, exposure condition and mixture proportions was made. As a result of this experiment in Series Ⅰ, there were no large differences in carbonation between the outdoor exposure areas, the ratio of indoor by outdoor were smaller than the fact-finding results of the past, in addition in the case of same water-binder ratio, there were no differences in the coefficient of carbonation rate between the fly-ash type. In Series Ⅱ, in the case of outdoor exposure, the coefficient of carbonation rate was larger at with roof than without roof, and was smaller at the north side of the building than south side.     

大掺量粉煤灰高性能混凝土的工程应用

研究了采用超量取代法配制大掺量粉煤灰混凝土的工程应用技术．从混凝土配合比设计、施工质量控制等几个方面着手进行了分析研究,并对大掺量粉煤灰混凝土的和易性、强度、抗渗性方面等进行了检验,实践证明：通过控制较低的水灰比、掺加高效减水剂以及严格施工质量管理,大掺量粉煤灰混凝土在工程应用技术上是切实可行的．     

Comparisons of Fly Ash and Deposition Between Air and Oxy-FuelCombustion in Bench-Scale Fluidized Bed with Limestone Addition

In Oxy-fuel circulating fluidized bed, the residual CaO particles may react with high concentration of CO₂ in flue gas to form bonded deposit on heat transfer surfaces in backpass when limestone is used as a sorbent to capture SO₂.In this paper, experiments were designed on ash deposition in a bench-scale fluidized bed under oxy-fuel and air atmosphere. A novel ash deposit sampling probe was used to simulate the tubes of tail surfaces. The chemical composition of fly ash and ash deposit from both air-firing and oxy-fuel firing cases were analyzed by Inductively Coupled Plasma-Atomic Emission Spectrometry(ICP-AES) and Scanning Electron Microscopy(SEM), respectively. The degrees of carbonation reaction of ash deposits were measured by Thermo Gravimetric Analysis. The results showed that there are distinct differences in fly ash deposition rate between oxy-fuel and air firing cases, and oxy-fuel combustion with limestone addition can affect chemical composition of fly ash and ash deposit, especially for elements of Ca, Na, K, and S. However, the carbonation reaction degree of ash deposits is found weak, which is due to the relatively low CaO content in ash deposit or not long enough of the sampling time.[JP]     

Impact properties of engineered cementitious composites with high volume fly ash using SHPB test

The split Hopkinson pressure bar (SHPB) testing with diameter 40 mm was used to investigate the dynamic mechanical properties of engineered cementitious composites (ECCs) with different fly ash content. The basic properties including deformation, energy absorption capacity, strain-stress relationship and failure patterns were discussed. The ECCs showed strain-rate dependency and kept better plastic flow during impact process compared with reactive powder concrete (RPC) and concrete, but the critical compressive strength was lower than that of RPC and concrete. The bridging effect of PVA fiber and addition of fly ash can significantly improve the deformation and energy absorption capacities of ECCs. With the increase of fly ash content in ECCs, the static and dynamic compressive strength lowered and the dynamic increase factor enhanced. Therefore, to meet different engineering needs, the content of fly ash can be an important index to control the static and dynamic mechanical properties of ECCs.     

增钙灰对增钙灰-水泥混凝土体积安定性的影响

增钙灰是发电厂采用立式旋风炉并添加石灰作为助熔剂时产生的副产品，它与普通粉煤灰在诸多方面存在差异，尤其是f-CaO的含量较高，造成了混凝土的体积安定性不良，从而限制了增钙灰在混凝土中的应用。对增钙灰的体积安定性问题进行了实验研究，提出在保证体积安定性合格的前提下增钙灰的混凝土中的极限掺量。     

Properties of High Volume Fly Ash Concrete Compensated by Metakaolin or Silica Fume

The compressive strength and dynamic modulus of high volume fly ash concrete with incorporation of either metakaolin or silica fume were investigated. The water to cementitious materials ratio was kept at 0.4 for all mixtures. The use of high volume fly ash in concrete greatly reduces the strength and dynamic modulus during the first 28 days. The decreased properties during the short term of high volume fly ash concrete is effectively compensated by the incorporation of metakaolin or silica fume. The DTA results confirmed that metakaolin or silica fume increase the amount of the hydration products. An empirical relationship between dynamic modulus and compressive strength of concrete has been obtained. This relation provides a nondestructive evaluation for estimating the strength of concrete by use of the dynamic modulus.     

搅拌时间对粉煤灰水泥净浆流动性及早期抗压强度的影响

影响粉煤灰水泥净浆的流动性与早期抗压强度等问题一个重要原因就是拌合是否充分,搅拌时间是否合适。现有的相关规范中对于拌合时间的规定大都针对普通混凝土,随着高性能混凝土的发展,尤其是粉煤灰混凝土近几年来的广泛使用,导致现有的拌合时间规定无法满足粉煤灰混凝土均匀性的控制要求。为此,通过初步研究不同拌合时间对不同掺量的粉煤灰水泥净浆流动性及早期抗压强度的影响,最终确定合理的粉煤灰水泥净浆拌合时间,供进一步研究与工程应用参考。     

粉煤灰与矿粉改进减水剂与水泥相容性的研究

采用萘系、聚羧酸系减水剂与粉煤灰、矿粉双掺法,进行水泥流动性的试验,测定净浆流动度损失,研究粉煤灰、矿粉对减水剂与水泥相容性影响,研究发现,粉煤灰、矿粉能有效改进萘系、聚羧酸系减水剂与水泥的相容性;而聚羧酸系减水剂与水泥的相容性比萘系减水剂好．     

粉煤灰混凝土耐久性探讨

比较分析各国对粉煤灰混凝土的渗透性、氯离子扩散系数及抗硫酸盐腐蚀的性能、碳化与抗冻性研究,指出粉煤灰混凝土的渗透性比普通混凝土大,但其在水中养护时间较长时,渗透性会降低,但粉煤灰混凝土的氯离子扩散系数比普通混凝土低,因此,用于海洋工程是大有希望的．利用深圳和东莞地区的粉煤灰作为掺合料制备混凝土以达到抗海水侵蚀的效果急待深入研究．