TiAl/42CrMo感应钎焊接头力学性能及断裂特征

在Ar气保护条件下,采用Ag-Cu-Ni-Li钎料实现了TiAl基合金与42CrMo钢的感应钎焊。结果表明,在界面上有Ti₃Al,AlCuTi,AlCu₂Ti,Ag基固溶体、Ag-Cu共晶组织以及TiC等反应相生成。钎焊温度1000℃、保温30s,接头界面组织主要为Al-Cu-Ti的三元金属间化合物,拉伸测试中断裂发生在金属间化合物的内部;当钎焊温度890℃,保温时间30s时,接头室温抗拉强度、高温(400℃)抗拉强度分别达到309MPa,286MPa,拉伸测试中裂纹源于焊缝中金属间化合物粒子与Ag基体固溶体相界处,扩展到两侧母材界面的脆性相处发生断裂。     

AgCuZnMnNi钎料感应钎焊35CMo/YG15C焊缝强度研究

根据该银基钎料的可焊接温度制定钎焊温度,每次试验试样的位置相同,利用高频感应钎焊进行焊接.制定焊接温度为630℃、650℃、670℃、700℃,保温时间30s.试验结果表明,放置在感应圈相同位置,保温时间相同的情况情况下,随着焊接温度的升高,抗剪强度呈现先增大后减小的趋势.在670℃达到最大,为388 MPa.焊缝缺陷主要为夹渣和气孔,未出现未焊透、裂纹等缺陷.     

Ni对AgCuZn钎焊201不锈钢接头组织及性能的影响

采用BAg45CuZn(Y1)、BAg40CuZnNi(Y2)和BAg49ZnCuMnNi(Y3)钎料感应钎焊获得201不锈钢对接接头,利用MTS万能材料试验机测试接头抗拉强度,利用SEM和EDS分析钎焊接头组织结构和观察接头断口形貌。结果表明,3种钎料和母材均实现良好的冶金结合,界面区钎料侧和钎缝区组织由灰白色富Ag相和灰黑色富Cu相组成;随着钎料中Ni元素含量的增加,Y1、Y2和Y3接头组织中界面富Cu相从粗大树枝晶向"痘点"状胞状晶、连续层状胞状晶演变,钎缝富Cu相也从粗大树枝晶向块状晶转变;Y1、Y2和Y3断口起裂源从强度较弱的钎缝富Cu相/富Ag相界面向Ni固溶强化较弱的富Ag相和富Ag相转变,裂纹扩展均发生在富Ag相中,随着钎料中Ni的增加,钎缝富Ag相固溶强化效果增大,提高了接头的抗拉强度;Y1、Y2和Y3平均抗拉强度分别为430.99 MPa、444.92 MPa和456.40 MPa。     

TiAl/Ag-Cu-Ni-Li/35 CrMo感应钎焊接头的组织特征

利用扫描电镜、电子探针及能谱分析等方法,对TiAl／Ag-Cu-Ni-Li／35CrMo感应钎焊的接头组织进行了研究。结果表明,钎焊焊缝沿圆柱试件径向出现宽、窄两反应区：钎焊试件外侧为宽反应区,内侧为窄反应区．两区界线明显。900℃保温5min时的钎焊接头组织结构为：TiAl／TiAl与钎缝间的扩散层／富Ag、Cu相／Ti(Cu,Al)2相／富Ag相／AlM2Ti相(M代表Fe,Cu,Ni)／钎缝与35CrMo间的扩散层／35CrMo。靠近TiAl侧的反应层组织形态依次为等轴细晶和Ti(Cu,A1)2相柱状晶,Ti(Cu,Al)2相柱状晶与TiAl母材存在一定的位向关系。     

Microstructure and mechanical properties of C/C composite joint brazed with Ni-based filler

The novel Ni-based brazing filler was used to join C/C composites. When brazing temperature increased from 1080 to 1100 °C, the wetting angle decreased from 23° to 14°, and the brazing filler had good wettability on the surface of C/C composites. The brazing seam of the brazed joint consisted of Ni(s,s) and Cr₃C₂ phases. As brazing temperature increased, lots of Cr₃C₂ phases were generated at the bonding interface, and the thick reaction layer was formed. When brazing temperature was 1120 °C, the shear strength of C/C joint reached the maximum value of 31.5 MPa. The fracture path extended in the C/C matrix close to the bonding interface.     

Interfacial microstructure and mechanical properties of tungsten carbide brazed joints using Ag-Cu-Zn + Ni/Mn filler alloy

WC-Co hard metal was furnace brazed by Ag-Cu-Zn+Ni/Mn filler alloy using a tube furnace under high-purity argon at 730 °C. The influence of brazing time and gap size of joints was studied. The results revealed the maximum shear strength of (156±7) MPa for samples with 150 µm gap size at a holding time 15 min. The characterization and microstructure of the brazed joints were characterized by SEM, EDS and XRD. The results showed that increasing the time from 5 to 15 min could provide a better chance for the liquid interlayer to flow towards the base metal. However, the formation of some metallic phases such as Mn₃W₃C at brazing time longer than 15 min resulted in decreased shear strength of the joint.     

AgCu钎料钎焊TC4钛合金与QCr0.8铬青铜接头界面结构及性能

采用AgCu28钎料实现了TC4钛合金与QCr0.8铬青铜的真空钎焊,利用SEM, EDS以及XRD等分析方法确定TC4/AgCu/QCr0.8接头的典型界面结构为TC4钛合金/CuTi +Cu3Ti2 +CuTi2/Ag(s,s) +Cu4Ti/Ag(s,s)+Cu(s,s)/QCr0.8铬青铜. 研究了工艺参数对接头组织和性能的影响. 结果表明,随着钎焊温度和保温时间的增加,钎缝中银铜共晶组织减少,钛铜化合物增多. 接头抗剪强度随钎焊温度的升高先增加后降低,在钎焊工艺参数为890 ℃/0 min时,获得最大抗剪强度449 MPa.保温时间的延长使得接头脆性钛铜化合物增多,接头性能下降,因此随保温时间延长接头抗剪强度显著降低.     

深冷处理对YG8硬质合金/42CrMo钢钎焊接头残余应力的影响

通过ANSYS仿真软件建立了YG8硬质合金/42CrMo钢钎焊接头的焊接工艺模型和深冷处理工艺模型,分析了接头表面残余应力分布,并与经深冷+回火处理后的焊接接头表面残余应力进行对比。结果表明,深冷处理可使焊接接头42CrMo钢侧形成残余压应力,且深冷温度对残余压应力的影响较深冷次数更明显。最优深冷工艺为-160 ℃深冷3次,且仿真结果与试验测量值相差不大,表明所建立的模型具有一定的可靠性。     

Al-Mg-Zn钎料钎焊镁合金AZ31B接头的显微组织和性能

以Al-Mg-Zn钎料对变形镁合金AZ31B进行了高频感应钎焊,分析了变形镁合金AZ31B钎焊接头的显微组织、钎缝物相和力学性能.采用扫描电镜(SEM)、X射线衍射仪(XRD)、X射线能谱分析仪(EDS)等仪器分析了钎焊接头的界面组织及钎缝生成相,测试了接头的强度及形成相的显微硬度.结果表明,在钎焊接头的钎缝中钎料与母材Az31B发生反应生成离异共晶组织α-Mg+β-Mg_(17)(Al,Zn)_(12),母材AZ31B的显微硬度最低,钎缝中的β-Mg_(17)(Al,Zn)_(12)相显微硬度最高.对接和搭接接头断口的断裂形式为沿晶脆性断裂,断裂产生在离异共晶组织α-Mg+β-Mg_(17)(Al,Zn)_(12)中的β-Mg_(17)(Al,Zn)_(12)硬脆相处.

Abstract：

High-frequency induction brazing of wrought magnesium alloy AZ31B with Al-Mg-Zn fdler metal was investigated. Microscopic structure, the phases and the mechanical properties of brazed joint were studied. The microstructure and formation phases at the interface in the brazed joint were investigated by scanning electron microscopy(SEM), X-ray diffraction instrument(XRD) and energy dispersive spectrometer (EDS). The strength of the brazed joint and the microhardness of the formation phases were also tested. The results show that, Al-Mg-Zn filler metal reacting with the base metal AZ31B, and a-Mg+β-Mg_(17) (Al,Zn)_(12) divorced eutectic structure is formed in the brazed joint. Microhardness of the base metal AZ31B is the smallest and β-Mg_(17) (Al, Zn)_(12) phase of the brazed joint is the hardest. Both the butt joint and the overlap joint exhibit intergranular fracture mode, the fracture comes from hard brittle phase β-Mg_(17) (Al,Zn)_(12) of α-Mg+β-Mg_(17)(Al,Zn)_(12) divorced eutectic structure.     

Ag-Cu-Ti钎料高频感应钎焊TiAl/40Cr

采用高频感应加热的方式 ,在Ar气保护条件下 ,用Ag -Cu -Ti钎料实现了TiAl基合金与 4 0Cr钢的钎焊连接 ;采用扫描电镜、电子探针、X射线衍射分析等手段对断口、界面、生成相进行了分析 ,并且测试了接头的抗拉强度。结果表明 ,在界面上有Ti(CuAl) 2 、Ag[s,s]、TiC等反应相生成 ,典型接头界面结构为TiAl/Ti(CuAl) 2 +Ag[s ,s]/Ag[s,s]/TiC/ 4 0Cr) ;断裂位置及接头的抗拉强度随保温时间而变化 ;当钎焊连接温度为 114 3K ,保温时间 0 .9ks时接头抗拉强度值最高 ,达到 2 98MPa,断裂主要发生在Ti(CuAl) 2 层内部     

颗粒增强复合钎料钎焊TiAl合金接头界面结构及性能

采用纳米Si3N4颗粒增强的AgCuTi复合钎料(AgCuTiC)实现了TiAl合金的钎焊连接.利用SEM,EDS及XRD等分析方法确定了TiAl/AgCuTiC/TiAl接头的典型界面结构为TiAl/AlCu2Ti/Ag(s,s)+TiN+ Al4Cu9+Ti5Si3.结果表明,钎焊过程中从TiAl母材溶入液相钎料的活性钛与复合钎料中纳米Si3N4颗粒发生反应,在钎缝中形成了细小的颗粒状TiN,Ti5Si3及Al4Cu9化合物增强的银基复合材料组织.银基复合材料的形成不仅提高了钎缝自身的强度,而且通过降低钎缝的线膨胀系数缓解了接头残余应力,并最终改善了钎焊接头的性能.当采用增强相含量为3％的AgCuTiC钎料在880℃保温5min条件下钎焊时,接头室温平均抗剪强度最高为278 MPa,比采用AgCuTi钎料提高40％.     

Zn-Al-Ag钎料铜-铝钎焊接头显微组织与力学性能

研究了Ag元素对Zn-Al钎料显微组织的影响,添加Ag元素能够细化Zn-Al钎料显微组织.结合钎焊接头力学性能、钎焊接头显微组织以及断口形貌,分析了Zn-Al-Ag钎料铜-铝钎焊接头的断裂机理.在外力作用下,钎缝显微组织中脆硬的块状CuAl₂相与其周围组织难以实现同步协调变形,在CuAl₂相边缘容易产生应力集中,从而萌生裂纹源,这是Zn-Al-Ag钎料铜-铝钎焊接头发生断裂的主要原因.添加Ag元素后,钎缝中块状CuAl₂相尺寸变小,应力集中倾向降低,对应的钎焊接头强度提高.当Ag元素添加量为3.3%(质量分数)时,钎焊接头强度达到最高,其对应的断口形貌中韧窝状形貌大而深.     

Zn-Al钎料钎焊Cu/Al接头组织和性能(英文)

使用不同成分的Zn-Al钎料对铜铝异种金属进行火焰钎焊,研究其力学性能。利用光学显微镜、扫描电镜和能谱研究不同Zn-Al钎料对Cu/Al钎焊接头钎焊性、力学性能及显微组织的影响。结果表明:随着Al含量的增加,Zn-Al钎料在Cu和Al上的铺展面积逐渐增大。当钎料中Al含量为15%时,Cu/Al接头的抗剪强度达到最大值88MPa;随着组织的变化,钎缝硬度值呈现HV122到HV515不等的分布。另外,钎缝组织的成分主要为富Zn相和富Al相,但是当钎料中Al含量为2%和15%以上时,靠近Cu侧的界面处会分别形成CuZn3和Al2Cu两种完全不同的金属间化合物。研究Zn-Al钎料中铝含量对Cu/Al接头界面化合物类型的影响。     

用非晶钎料加铜层连接Si3N4的界面结构与强度

采用TiZrCuB非晶钎料和铜箔中间层连接Si3N4陶瓷,研究了钎料成分和铜箔厚度对接头界面结构和抗弯强度的影响.结果表明,采用Ti40Zr25CuB0.2非晶钎料和70!m铜箔中间层,在1 323 K×30 min和0.027 MPa压力下连接Si3N4陶瓷,其接头抗弯强度最高为241 MPa;Si3N4陶瓷连接接头界面反应层为TiN,界面微观结构为Si3N4/TiN/Ti-Si+α-Cu+Ti-Zr+Cu-Zr;改变中间层厚度可以调整反应层的结构和厚度;随铜箔厚度增加,Ti-Si化合物层逐渐脱离TiN层被推向钎缝中心并细化呈颗粒状.     

Strength and interfacial microstructure of Si3N4 joint brazed with amorphous Ti-Zr-Ni-Cu filler metal

In this paper, the vacuum brazing of Si3N4 ceramic was carried oat with Ti40Zr25Ni15Cu20 amorphous filler metal. The interfacial microstructure was investigated by scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS) etc. According to the analysis, the interface reaction layer was made up of TiN abut on the ceramic and the Ti-Si, Zr-Si compounds. The influence of brazing temperature and holding time on the joint strength was also studied. The results shows that the joint strength first increased and then decreased with the increasing of halding time and brazing temperature. The joint strength was significantly affected by the thickness of the reaction layer. Under the same experimental conditions, the joint brazed with amorphous filler metal exhibits much higher strength compared with the one brazed with crystalline filler metal with the same composition. To achieve higher joint strength at relatively low temperature, it is favorable to use the amorphous filler metal than the crystalline filler metal.     

AgCuNiLi钎焊TiC金属陶瓷与GH3128界面结构及接头性能

采用AgCuNiLi钎料对TiC金属陶瓷与GH3128镍基高温合金进行钎焊。结果表明:当钎焊温度为840℃,保温10min时,接头典型界面结构可以表示为:TiC金属陶瓷/(Cu,Ni)/Ag(s.s)+Cu(s.s)/(Cu,Ni)/GH3128。随着钎焊温度的升高或保温时间的延长,TiC金属陶瓷附近的(Cu,Ni)固溶体层厚度增大,且向钎料内部呈树枝状长大,钎料内部的Ag-Cu共晶组织逐渐减少。界面机理分析表明:钎料中Li的加入能促进界面上(Cu,Ni)固溶体的形成;但(Cu,Ni)固溶体的继续长大则受钎料中Cu元素的扩散程度控制。当加热温度由810℃升高到960℃,接头抗剪强度呈现先增大,然后缓慢减小的变化趋势。当加热温度为880℃、保温时间为10min时,接头抗剪强度达到最大值204MPa。     

Ni-34Ti钎料钎焊TiAl合金接头界面结构及性能

采用Ni-34Ti共晶钎料实现了TiAl合金的钎焊连接,分析了TiAl合金钎焊接头的界面结构,重点研究了钎焊温度对接头组织及性能的影响规律.结果表明,Ni-34Ti共晶钎料主要由TiNi相和TiNi3相组成,钎料熔点为1 120 ℃.不同钎焊温度下获得的接头界面组织均呈现对称特征,无气孔和裂纹等缺陷,接头中主要形成了TiNiAl2,B2,TiNiAl和TiNi2Al四种物相.Al元素在钎缝中的快速扩散,促进了钎缝中Ti-Ni-Al三元化合物的形成.钎焊温度为1 180 ℃保温10 min条件下,TiAl合金接头获得了最大的室温抗剪强度87 MPa.剪切过程中,裂纹容易在富含TiNi2Al相的区域产生和扩展,大量脆性TiNi2Al相的存在对接头的性能是有害的.     

Interfacial microstructure and mechanical properties of GH99 superalloy and Nb brazed joint using Cu75Pt25 filler

Cu75Pt25 brazing filler was applied to brazing GH99 superalloy to Nb, and the sound joints were obtained by adjusting brazing parameters. The typical interfacial microstructure of the brazed joint was Nb/Nb₇Ni₆+NbNi₃/ Ni(s,s)+Cr-rich NbNi₃+(NbCr₂+NbNi₃)/GH99. The effects of brazing temperature and holding time on the interfacial microstructure of GH99/Cu75Pt25/Nb joints were studied. The results showed that the solution and diffusion of Ni atoms from GH99 substrate into brazing seam played a critical role in the interfacial microstructure evolution. As the brazing temperature rose, the Nb–Ni reaction layer was formed instead of the initial Nb₃Pt layer, and the thickness increased firstly and then remained constant. The highest shear strength of the joint reached 152 MPa when brazed at 1150 °C for 15 min. All of the joints presented a brittle fracture mode during shear test, and the fracture location changed from Nb₃Pt layer to Nb–Ni compounds layer.     

生成相性质及其对TiAl合金/42CrMo钢钎焊接头力学性能影响

在钎焊温度1123~1273 K,保温时间120~1500 s参数范围内对TiAl合金与42CrMo钢进行了真空扩散钎焊.用光学显微镜、扫描电镜和能谱分析等方法对界面组织进行了分析,用图像分析软件工具测量了反应层厚度;采用纳米压痕仪和显微硬度仪对TiAl合金/42CrMo钢钎焊接头的两种母材和接头界面反应相进行了硬度测试,对结果进行了对比,为了确定接头的薄弱环节,进行了扫描电镜原位观察下的接头拉伸试验.结果表明,AlCuTi,Ti₃Al,AlCu₂Ti和TiC的硬度较高,而银的固溶体硬度较低;纳米压痕的硬度结果比显微硬度值略高;扫描电镜下的原位拉伸试验结果表明,Al-Cu-Ti系反应层在受外力作用下容易发生脆性断裂,为接头的薄弱环节.     

生成相性质及其对TiAl合金/42CrMo钢钎焊接头力学性能影响

在钎焊温度1123~1273 K,保温时间120~1500 s参数范围内对TiAl合金与42CrMo钢进行了真空扩散钎焊.用光学显微镜、扫描电镜和能谱分析等方法对界面组织进行了分析,用图像分析软件工具测量了反应层厚度;采用纳米压痕仪和显微硬度仪对TiAl合金/42CrMo钢钎焊接头的两种母材和接头界面反应相进行了硬度测试,对结果进行了对比,为了确定接头的薄弱环节,进行了扫描电镜原位观察下的接头拉伸试验.结果表明,AlCuTi,Ti₃Al,AlCu₂Ti和TiC的硬度较高,而银的固溶体硬度较低;纳米压痕的硬度结果比显微硬度值略高;扫描电镜下的原位拉伸试验结果表明,Al-Cu-Ti系反应层在受外力作用下容易发生脆性断裂,为接头的薄弱环节.