MnZn功率铁氧体的研究进展及发展趋势

介绍了宽温超低损耗、高频低损耗和高温高饱和磁感应强度(Bs)MnZn功率铁氧体材料的研究现状,以及添加剂的种类和制备方法的研究,世界上主要软磁铁氧体公司近几年的最新产品情况,指出了MnZn功率铁氧体的发展趋势.从目前的发展状况来看,应用在中低频的功率MnZn铁氧体材料不但要求在较宽的温度范围内具有较低的损耗,同时要求具有高的起始磁导率和饱和磁感应强度.而对于高频功率MnZn铁氧体材料则继续向高频低损耗发展.     

宽频低THD高μi铁氧体材料的制备

高磁导率Mn—Zn铁氧体材料是为适应电子通信、新型电子照明设备的高电感量和小型轻薄化的需求而发展起来的，其应用十分广泛，尤其在当今通信领域里，数字网络通信、光纤通信技术及设备以飞快的速度发展，迫切需要高磁导率Mn—Zn铁氧体磁心制作的滤波器、宽带变压器和脉冲变压器等电子器件。     

掺杂对高导MnZn铁氧体微结构和性能的影响

采用传统陶瓷工艺制备了高磁导率MnZn铁氧体材料。从分析材料微观结构入手,研究了P2O5和Nb2O5的掺入,组以适配的工艺条件和不同的比例掺入,来研究对高磁导率MnZn铁氧体材料性能的影响。少量P2O5掺杂可使铁氧体晶粒尺寸增大,均匀性改善,起始磁导率提高。但若掺杂过量,晶粒中气孔率增加,起始磁导率下降,损耗也大为增加。在配方为Zn0.15Mn0.78Fe2.07O4的材料中,当P2O5掺杂量为0.16%(wt)时,起始磁导率可达10697。Nb2O5的添加起到细化晶粒的作用,可以改善材料的频率特性,降低材料损耗,磁导率稍有降低,但当Nb2O5的质量分数>0.005%时,会显著降低材料的起始磁导率。     

原材料杂质对镍锌软磁铁氧体绝缘电阻率的影响

软磁铁氧体材料广泛应用于民用和工业领域,随着近年来信息技术和新型绿色照明的发展,软磁铁氧体产品的结构将向数字化、平板化、集成化和节能型发展[1]。在品种繁多的软磁铁氧体材料中,镍锌铁氧体具有电阻率高、化学稳定性好和高频损耗小等优     

低损耗Mn-Zn铁氧体电磁参数与烧结温度的关系研究

本文研究了在不同烧结温度下 ,低损耗Mn Zn铁氧体材料的功耗、起始磁导率、饱和磁通密度、居里温度、电阻率、Zn挥发情况及微观结构等因素的变化 ,结果表明 :随着烧结温度的升高 ,功耗先下降 ,后上升 ;样品的烧结密度、起始磁导率都升高 ;Zn的挥发严重 :饱和磁通密度和居里温度基本上没有什么变化 ;晶粒的微观结构也受烧结温度的直接影响。由此说明烧结温度是决定Mn Zn铁氧体材料性能的关键因素之一     

东磁5项磁性材料新成果通过评审

近日，金华市科学技术局在东磁大厦组织召开了横店集团东磁股份有限公司承担的5项科技成果评审会。这5项科技成果分别是“Mn—Zn铁氧体DMR25材料”、“高Bs超低功耗MnZn功率铁氧体DMR46材料”、“HDD粘结钕铁硼磁体”、“LCD、PDP电源变压器用高Bs、低损耗DMR90磁心材料”、“高速宽带网用高稳低损耗磁心材料DMR71”。     

电子材料

<正>日立金属开发出新型磁芯材料日立金属公司开发出了高频特性出色的锰锌(Mn-Zn)类铁氧体磁芯材料"ML95S"和"ML90S"。新材料在几兆赫兹高频范围内的磁芯损耗较小,可使网络设备、汽车以及智能手机配备的部件实现小型化和节能化。此前也有过在0.5~5MHz的高频范围采用镍锌(Ni-Zn)类铁氧体材料的讨论,日立金属此次通过组合使用粉末控制技术和热处理技术,实现了与Ni-Zn类铁氧体材料相比饱和磁通密度更高、磁芯损耗更小的Mn-Zn类铁氧     

热压铁氧体的制备和磁性

本文从实验上研究了起始粉料的制备方法和热压条件对磁头用的Mn—Zn及Ni—Zn热压铁氧体的密度和磁性的影响。实验结果表明,化学共沉淀法制备的铁氧体粉料比氧化物法及硫酸盐法制备的要好。适当选择热压条件,可以获得μ_0=7420以及Bm=4950高斯的高密度Mn—Zn铁氧体和μ_0等于100—2500的高密度Ni—Zn铁氧体。     

Gd3+掺杂对Mn-Zn铁氧体结构、磁性能和磁热效应的影响

采用化学共沉淀法制备了Gd^3＋掺杂的Mn—Zn铁氧体微粒，并通过XRD、FTIR、VSM等研究了掺杂量对基体材料结构、磁性能及在外磁场作用下磁热效应的影响．结果表明，适量Gd^3＋的掺杂可以有效改善Mn—Zn铁氧体的磁性能和磁热效应，成分为Mn0．4Zn0．6Gd0．06Fe1．94O4的铁氧体粉体的粒径约为20nm，具有最高的饱和磁化强度和矫顽力，50mg的该样品与1mL水形成的悬浮液，在频率为60kHz的外磁场诱导下，升温可达31℃，显示出较高的磁热性能，有望作为肿瘤热疗的内加热材料．     

聚苯胺-钴铬锌铁氧体复合材料的微波吸收性能和磁性能

用聚丙烯酰胺凝胶法和原位聚合法分别制备了钴铬锌铁氧体(Co0.7Cr0.1Zn0.2Fe2O4)和聚苯胺-钴铬锌铁氧体复合材料(PANI-Co0.7Cr0.1Zn0.2Fe2O4),用XRD和FT-IR对材料的结构进行了表征。结果表明,制备的Co0.7Cr0.1Zn0.2Fe2O4铁氧体为尖晶石结构,少量Cr3+离子替代了铁氧体八面体位置上的Co2+离子,导致铁氧体的晶格常数从0.8409 nm减小到0.8377 nm。用振动样品磁强计(VSM)测量了材料的磁性能,结果表明,PANI-Co0.7Cr0.1Zn0.2Fe2O4复合材料的饱和磁化强度(Ms)、剩余磁化强度(Mr)和矫顽力(Hc)分别为8.80 emu/g、14 emu/g和37.22 k A/m,小于铁氧体的相应数值;用波导法研究了PANICo0.7Cr0.1Zn0.2Fe2O4复合材料的微波吸收性能,在5-20 GHz频率范围内14.1 GHz和17.9 GHz处出现两个极大反射损耗,分别为-13.17 d B和-15.36 d B,大于铁氧体的反射损耗。     

用精矿粉和Mn3O4制备高性能功率软磁MnZn铁氧体

用精矿粉代替Fe2O3、用Mn3O4代替MnCO3作为原材料，因为减少了Mn离子在反应中的变价机率，提高了配方中Mn离子的准确性，精矿粉的主要成分Fe3O4相变为α-Fe2O3的温度与Mn铁氧体生成温度接近，所以使固相反应更安全，能制备出高性能功率软磁MnZn铁氧体。适量的掺杂CaCO3、V2O5及Bi2O3可以进一步降低样品功耗；制备过程中，采取一些特殊工艺措施及适当烧结温度能进一步提高样品磁性能，使其综合性能基本达到日本TDK的PC30水平。     

MnZn功率铁氧体研究进展

简要介绍了MnZn功率铁氧体的研究现状,分析了各种制粉方法,讨论了添加剂和不同烧结方式对MnZn功率铁氧体磁性能的影响.     

Effect of dopants on the magnetic properties of MnZn ferrites forhigh frequency power supplies

The effect of additions on the magnetic properties of MnZn ferrites for high frequency power supplies was studied. The investigation revealed that various combinations of dopants added to the ferrite modify the grain boundary resistivity and the magnetic permeability spectra at constant microstructure. Particularly, the combined effect of Sn⁴⁺, Ti⁴⁺ and Ta⁵⁺ was found to increase the grain boundary resistivity in the ferrites studied and remarkably decrease the power loss at higher frequencies     

MnZn铁氧体制备工艺研究进展

MnZn铁氧体是软磁材料的主要组成部分。首先介绍了MnZn铁氧体的最新研究动态，其制备工艺的好坏将直接影响到产品的优劣，然后综述了近年来制备MnZn铁氧体的新工艺和新技术，以及其结构特征和性能方面的突破，最后对MnZn铁氧体的发展进行了展望。     

High-frequency MnZn soft magnetic ferrite by engineering grain boundaries with multiple-ion doping

MnZn soft magnetic ferrites have been widely utilized in power electronics,owing to the combined merits of high permeability and low energy loss.However,their deployment would result in a drastic increase in power dissipation at ＞3 MHz,thus limiting the scope extent of miniaturization,together with their efficiency.Here,we report a high-performance MnZn ferrite by doping multiple ions (La,Ti,Si,Ca) at grain boundaries,achieving the most optimized power loss of 267 kW/m3 at 5 MHz (10 m T,100 ℃) and initial permeability of 644,which is much better than the previously reported results and commercial products.Such an improvement is attributed to weakened magnetic exchange coupling at grain-boundary regions,associated with a significant transition from the multi-to mono-domain structures,originating physi-cally from large crystallographic mis-orientations (＞25°).The present study bears important significance in understanding the intrinsic correlation between the crystallographic mis-orientation and magnetic domain structure,and provides an alternative way for optimizing high-frequency soft magnetic ferrites.     

自蔓延高温合成软磁铁氧体粉的研究进展

简要介绍了自蔓延高温合成技术和热力学判据,评论了此合成技术的新进展和存在的问题,综述了利用此方法制备MnZn、NiZn和MgZn铁氧体材料的制备工艺及其应用研究现状,重点分析讨论了软磁铁氧体的原料配方、合成工艺和磁特性.研究表明,通过控制工艺参数和添加剂的合理使用,SHS法制备铁氧体粉体具有更好的烧结活性和纯度,适合于大规模的工业生产.     

High-Frequency Tunneling Magnetic Loss in Soft Ferrites

This paper considers high-frequency (200 kHz-1.0 MHz) losses in MnZn power ferrites and shows that none of the three well-known magnetic loss mechanisms (namely, hysteresis, classical eddy-current loss, and excess eddy-current loss) can account for the experimentally observed dependence of the loss on the frequency and flux density. In order to investigate the origin of this discrepancy, the electric field that is induced in the typical core when the material is driven at high frequencies and flux densities was estimated. The estimates show that these electric fields can be quite large. The paper presents experimental data on the electrical conductivity for such large electric fields, which shows a highly nonlinear behavior that can give rise to a modified eddy-current loss mechanism. By a simple curve fit to the nonlinear conductivity, the experimentally observed flux density dependence of the high-frequency loss, which previously could not be explained, can be reproduced by using this modified eddy-current loss mechanism. A modified ferrite structure can eliminate most of these extra losses by reducing the electric field generated at the grain boundaries due to high frequencies and flux densities     

Development of low-power loss Mn-Zn ferrites using microwave sintering method

Microwave sintering (MS) method has been successfully used for densifying Mn- Zn ferrites used for high frequency applications. This method needs only a short time to obtain high density when compared to conventionally sintered (CS) Mn- Zn ferrites. The lowest power loss was also achieved at 100 kHz and 200 mT condition for the microwave sintered samples. Conductor- embedded ferrite transformers were constructed using CS and MS samples and output power, efficiency, and surface rise of temperature were measured at sinusoidal voltage of 25 V with frequency, 1 MHz. The efficiency and surface rise of temperature of transformer were found to be high and low, respectively.     

掺杂对锶铁氧体基复合材料吸波特性的影响

将锶铁氧体、铁砂、混合稀土加工成基础材料,通过掺入一系列的不同类型的吸收介质制成复合电波吸收材料,在8-18GHz频段内测其吸波特性.实验结果表明,在基础材料中掺入Cu粉,使吸收峰移向低频,匹配厚度变大.在基础材料中同时加入MnZn铁氧体,最大衰减量明显增加,-10dB带宽无明显变化.同时掺入几种不同类型的吸收介质,产生了部分的累积效果.     

Pressure sintering of MnZn and NiZn ferrites

Polycrystalline MnZn and NiZn ferrites suitable for recording-head applications have been prepared by pressure sintering (hotpressing). General conditions for pressure sintering and details of the apparatus are described. Also discussed are the effects of grain size and temperature, in the normal range of glass bonding, on the magnetic and physical properties of pressure-sintered MnZn ferrite. It was observed that the strength of the ferrite increased with decreasing grain size in the range studied (15 to 500 μm). An opposite effect was noted for resistance to material wear. Increases in permeability up to 30 percent were obtained by relieving residual machining stresses with anneals in the 500 to 900°C range. Similar increases in strength were observed for low-temperature anneals. However, at temperatures higher than 500°C, the strength was reduced strongly, with the amount of the reduction being dependent upon the surface finish of the ferrite and its geometry. In general, strength was reduced with coarser surface finish and increasing surface-to-volume ratios. Data on material wear and hardness as functions of grain size and composition are presented. Improvement in performance of video recording heads fabricated of pressure-sintered MnZn ferrite as compared to Alfesil and single-crystal MnZn ferrite is also demonstrated.