Enhancement of mechanical strength associated with interfacial tension between barium titanate and acrylonitrile–butadiene rubber with different acrylonitrile contents by surface modification |
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| Authors: | Suoshi Zhu Jiacong Guo Jun Zhang |
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| Affiliation: | 1. College of Materials Science & Engineering, Nanjing Tech University, Nanjing 210009, China;2. Jiangsu Collaborative Innovation Center for Advanced Inorganic Function Composites, Nanjing 210009, China |
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| Abstract: | Acrylonitrile–butadiene rubber (NBR) with different acrylonitrile (ACN) contents was filled with barium titanate (BT) to prepare the polymer dielectrics. The neat NBR, NBR/untreated BT, and NBR/bis‐(γ‐triethoxysilylpropyl)‐tetrasulfide (silane coupling agent KH845‐4) modified BT (MBT) composites were prepared. At low ACN content (ACN content 20 wt %), the tensile strength of the NBR/MBT composites increased by 173.6% from 2.69 to 7.36 MPa compared to the neat NBR. The pleasing results were not found in those composites with high ACN content. Both surface modifications of BT and NBR with low ACN content would result in lower interfacial tension between BT and NBR. A strong interfacial adhesion was observed between MBT and NBR with 20 wt % ACN content. The interfacial adhesion had great contribution to the mechanical strength of composites. Moreover, the dielectric properties of composites were also investigated in detail. The addition of BT enhanced the dielectric constant of composites markedly. This study can be applied in manufacturing electronic devices, which are subjected to oily environments for a long time. At the same time, the study can provide some help for researchers to select the polymer matrix and the appropriate surface modification agent of functional filler. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 45936. |
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| Keywords: | applications dielectric properties mechanical properties surfaces and interfaces |
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