Calcium carbonate and wood reinforced hybrid PVC composites |
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Authors: | Catalin Croitoru Cosmin Spirchez Daniel Cristea Aurel Lunguleasa Mihai Alin Pop Tibor Bedo Ionut Claudiu Roata Mihai Alexandru Luca |
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Affiliation: | 1. Materials Engineering and Welding Department, Transilvania University of Brasov, Eroilor 29 Str, Brasov, Romania;2. Wood Processing and Design of Wooden Products Department, Transilvania University of Brasov, Eroilor 29 Str, Brasov, Romania;3. Materials Science Department, Transilvania University of Brasov, Eroilor 29 Str, Brasov, Romania |
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Abstract: | In this article, poly(vinyl chloride) (PVC) sandwich‐structured hybrid composites with amorphous calcium carbonate and wood‐filled cores were obtained by compression molding. It has been determined that wood addition up to a weight ratio of 33% reported to the total filler amount is beneficial in improving both the inter‐filler and filler‐matrix interfacial adhesion, which alongside with the promoting of the amorphous PVC matrix crystallization is responsible for an increase up to 34% in the flexural strength of the composites, compared to unfilled PVC. The hybrid filled composites present up to 35% lower friction coefficients and up to 20% higher Brinell hardness values than the composites filled with calcium carbonate alone. Subsequently, wood addition determines an increase in the oxidation onset temperature for PVC and an increase with up to 20% in the sound and thermal‐insulative properties of the composites, compared to unfilled PVC. The dominating dispersive part of the composites surface energy aids in improving the mass and dimensional stability of the assembly to both water and dilute hydrochloric acid aqueous solutions. © 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018 , 135, 46317. |
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Keywords: | cellulose and other wood products differential scanning calorimetry poly(vinyl chloride) spectroscopy structure– property relationships |
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