| 尖晶石型无钴黑色陶瓷颜料的研究进展 |
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| 引用本文： | 张翔,李治桥,马国军,王强,刘孟珂. 尖晶石型无钴黑色陶瓷颜料的研究进展[J]. 硅酸盐通报, 2021, 40(4): 1318-1329 |
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| 作者姓名： | 张翔 李治桥 马国军 王强 刘孟珂 |
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| 作者单位： | 武汉科技大学,钢铁冶金与资源利用省部共建教育部重点实验室,武汉 430081;武汉科技大学,钢铁冶金新工艺湖北省重点实验室,武汉 430081 |
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| 基金项目： | 国家自然科学基金青年科学基金(51904212);湖北省教育厅科学研究计划指导性项目(B2019001) |
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| 摘 要： | 黑色陶瓷颜料目前被广泛应用于陶瓷装饰领域,其传统制备工艺需加入氧化钴,但氧化钴的高价限制了黑色陶瓷颜料的发展,因此开发无钴黑色陶瓷颜料成为陶瓷颜料研究领域的热点之一,而尖晶石型无钴黑色陶瓷颜料因其出色的耐高温性、气氛适应性和化学稳定性受到众多研究者的青睐.本文基于尖晶石型无钴黑色陶瓷颜料的相关研究进展,围绕其呈色机理、...
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| 关 键 词： | 黑色陶瓷颜料 尖晶石 呈色机理 过渡金属元素 铬铁矿 工业固废 |
| 收稿时间： | 2021-01-11 |
Research Progress of Spinel-Type Cobalt-Free Black Ceramic Pigments |
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| ZHANG Xiang,LI Zhiqiao,MA Guojun,WANG Qiang,LIU Mengke. Research Progress of Spinel-Type Cobalt-Free Black Ceramic Pigments[J]. Bulletin of the Chinese Ceramic Society, 2021, 40(4): 1318-1329 |
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| Authors: | ZHANG Xiang LI Zhiqiao MA Guojun WANG Qiang LIU Mengke |
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| Affiliation: | 1. Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education, Wuhan University of Science and Technology,Wuhan 430081, China;2. Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steelmaking,Wuhan University of Science and Technology, Wuhan 430081, China |
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| Abstract: | Black ceramic pigments are currently widely used in the field of ceramic decoration. The traditional processes to produce black ceramic pigments require the addition of cobalt oxide, but the high price of cobalt oxide limits the development of black ceramic pigments. Therefore, the development of cobalt-free black ceramic pigments has become one of the hot spots in the research field of ceramic pigments and the spinel-type cobalt-free black ceramic pigments are favored by many researchers for their excellent high-temperature resistance, atmospheric adaptability and chemical stability. Based on the research progress of spinel-type cobalt-free black ceramic pigments, coloration mechanism, raw material types and preparation technologies of the above ceramic pigments were described and analyzed detailedly in this paper. At present, the raw materials for preparing the spinel-type cobalt-free black ceramic pigments can be mainly divided into chemical raw materials, mineral raw materials and industrial solid wastes. The preparation technologies mainly include the traditional high-temperature solid-state method, the microwave roasting method, the chemical precipitation method, the sol-gel method, the microemulsion method, the solution combustion method, etc. The coloring properties of prepared pigments are mainly affected by the mole ratio among transition metal elements in raw materials, the roasting temperature and the holding time. In comparison, microwave roasting of industrial solid wastes to prepare the above ceramic pigments has a good application prospect, but the formation and evolution mechanism of spinel in the preparation process and the influence of impurity components introduced by industrial solid wastes on the properties of pigments still need to be further studied. |
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| Keywords: | black ceramic pigment spinel coloring mechanism transition metal element chromite industrial solid waste |
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