| Colour Tuning of Single Host Phosphors for White Light by Al Addition |
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| 作者姓名： | 王达健 王继磊 李岚 |
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| 作者单位： | Institute of Materials Physics, Tianjin University of Technology, Tianjin 300191; Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin 300191 |
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| 基金项目： | Supported by the National Natural Science Foundation of China under Grant No 50364002, and the Tianjin Natural Science Foundation （06YFJMJC02300）. |
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| 摘 要： | We report a newly found strong disturbing effect orAl addition to the intensity ratios of blue and green emissions from single host full-colour phosphor of Ba3MgSi2-xAlxO8：0.02Eu^2＋, 0.1Mn^2＋ for near-UV excited white light. The phase-pure silicate phosphor in the size of around 4μm is prepared by salt-assisted spray pyrolysis route, having three-colour emissions at the wavelength peak values of 437nm, 500 nm and 608 nm simultaneously under the excitation of 375 nm. The amount variation orAl ion added to the phosphor host results in a drastic change of the intensity ratio between green and blue emissions, while the intensity of red light keeps unchanged. As a consequence, the combination of three colours lies in the white light region and can be tuned by precisely controlled addition oral content. The Raman spectroscopy verifies the modifying effect oral ion to the tetrahedral network in silicate hosts. We assume that by addition of Al ion, the amount of those two kinds of Eu^2＋ substituting for those two kinds of Ba^2＋ lattice sites with distinct energy levels of blue and green featured emissions can be adjusted to contribute to diversification of the ratios of blue and green emissions.
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| 关 键 词： | 色调整 白光 铝混合料 物理光学 |
| 收稿时间： | 2006-04-03 |
| 修稿时间： | 2006-04-03 |
Colour Tuning of Single Host Phosphors for White Light by Al Addition |
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| WANG Da-Jian,WANG Ji-Lei,LI Lan.Colour Tuning of Single Host Phosphors for White Light by Al Addition[J].Chinese Physics Letters,2006,23(8):2247-2250. |
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| Authors: | WANG Da-Jian WANG Ji-Lei LI Lan |
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| Affiliation: | Institute of Materials Physics, Tianjin University of Technology, Tianjin 300191; Tianjin Key Laboratory for Photoelectric Materials and Devices, Tianjin 300191 |
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| Abstract: | |
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| Keywords: | 78 55 -m 78 30 -j |
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