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月桂酸-膨胀石墨复合相变材料的制备及性能
引用本文:黄雪,崔英德,尹国强,冯光炷,吴梓敏. 月桂酸-膨胀石墨复合相变材料的制备及性能[J]. 化工学报, 2015, 66(Z1): 370-374. DOI: 10.11949/j.issn.0438-1157.20141134
作者姓名:黄雪  崔英德  尹国强  冯光炷  吴梓敏
作者单位:1.仲恺农业工程学院化学化工学院, 广东 广州 510225;2.广州科技职业技术学院, 广东 广州 510550
基金项目:国家自然科学基金项目(31371880
摘    要:以月桂酸为相变材料, 多孔石墨为骨架基体, 利用多孔石墨的物理吸附特性, 制备月桂酸-膨胀石墨定形复合相变材料。并通过实验对定形复合相变材料的基本性能、表面形貌及耐久性进行了研究。结果表明, 月桂酸被有效地包封在膨胀石墨的孔隙内;m月桂酸:m膨胀石墨=95:5时定形复合相变材料的相变温度45.45℃, 相变潜热125.30 J·g-1;经100次冷热相变循环后, 复合相变材料损失量非常少, 表明月桂酸-膨胀石墨复合相变材料在实践中有良好的稳定性。

关 键 词:月桂酸  膨胀石墨  稳定性  耐久性  
收稿时间:2014-07-29
修稿时间:2015-01-11

Preparation and performance of lauric acid-expanded graphite composite phase change materials
HUANG Xue,CUI Yingde,YIN Guoqiang,FENG Guangzhu,WU Zimin. Preparation and performance of lauric acid-expanded graphite composite phase change materials[J]. Journal of Chemical Industry and Engineering(China), 2015, 66(Z1): 370-374. DOI: 10.11949/j.issn.0438-1157.20141134
Authors:HUANG Xue  CUI Yingde  YIN Guoqiang  FENG Guangzhu  WU Zimin
Affiliation:1.College of Chemistry and Chemical Engineering, Zhongkai University of Agriculture and Engineering, Guangzhou 510550, Guangdong, China;2.Guangzhou Vocational College of Science and Technology, Guangzhou 510225, Guangdong, China
Abstract:The lauric acid-expanded graphite (LA/EG) composite phase change materials was prepared by using adsorption properties of porous graphite with lauric acid as phase change material, porous expanded graphite(EG) as the skeleton carrier; and through the experiment of the basic properties of shape stabilized phase change material, surface morphology, durability were studied. The results showed that lauric acid was effectively encapsulated within the pores of the expanded graphite; phase change temperature and latent heat of LA/EG was 45.45℃and 125.30 J·g-1 respectively when mLA:mEG=95:5. LA/EG loss rate was very small after 100 times of hot and cold cycle phase transitions, which indicated that LA/EG has good stability in practice.
Keywords:lauric acid  expanded graphite  stability  durability
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