Eu:Lu2O3透明闪烁陶瓷的制备与性能

人工晶体学报 ›› 2021, Vol. 50 ›› Issue (3): 435-440.

Eu:Lu₂O₃透明闪烁陶瓷的制备与性能

王静¹, 葛烨¹, 解伟锋^1,2, 陈昊鸿², 李江²

1.安徽理工大学材料科学与工程学院,淮南 231001;
2.中国科学院上海硅酸盐研究所,透明光功能无机材料重点实验室,上海 200050

收稿日期:2020-12-14 出版日期:2021-03-15 发布日期:2021-04-15
作者简介:王静(1977—),女,安徽省人,博士,教授。E-mail:jingwang@aust.edu.cn
基金资助:
中国科学院透明光功能无机材料重点实验室开放课题(KLTOIM201609)

Preparation and Properties of Transparent Eu:Lu₂O₃ Scintillation Ceramics

WANG Jing¹, GE Ye¹, XIE Weifeng^1,2, CHEN Haohong², LI Jiang²

1. College of Materials Science and Engineering, Anhui University of Science and Technology, Huainan 231001, China;
2. Key Laboratory of Inorganic Materials with Transparent Light Function, Shanghai Institute of Ceramics,Chinese Academy of Sciences, Shanghai 200050, China

Received:2020-12-14 Online:2021-03-15 Published:2021-04-15

摘要/Abstract

摘要： 采用湿化学法合成了Eu原子掺量5%的Lu₂O₃陶瓷前驱体,通过SEM、XRD研究了煅烧前后前驱体和1 100 ℃煅烧4 h后粉体的形貌、结构以及物相。结果表明煅烧后的粉体为纳米类球形、高分散且结晶性良好的颗粒。颗粒尺寸为68.5 nm。使用煅烧后的粉体为原料,在1 650 ℃真空烧结30 h制备了高透过率的Eu:Lu₂O₃陶瓷,晶粒尺寸为46 μm,在611 nm处的直线透过率可以达到66.3%。此外对陶瓷的吸收曲线、光致激发和发射光谱特性以及X射线激发发射光谱进行研究。可观察到,Eu:Lu₂O₃陶瓷存在基质和激活离子两类吸收,光致发光光谱和X射线激发发射光谱均可以看出Eu:Lu₂O₃陶瓷存在极强的⁵D₀→⁷F₂跃迁发光,位于611 nm处。对比商业的BGO单晶的X射线发射光谱,可得本实验中制备的陶瓷的光输出为85 000 ph/MeV。Eu:Lu₂O₃陶瓷本身有着高X射线以及高能粒子的阻止能力,结合高光输出特性,表明Eu:Lu₂O₃陶瓷在X射线成像等领域具有巨大的潜在应用价值。

关键词: Eu:Lu₂O₃;, 闪烁陶瓷, 透明陶瓷, 真空烧结, 光致激发, 发射光谱, 光输出

Abstract: The 5% Eu:Lu₂O₃ ceramic precursor was synthesized by wet chemical method, and the morphologies, microstructures and phases of both Eu:Lu₂O₃ ceramic precursor and the calcined Eu:Lu₂O₃ ceramic powders were studied by SEM and XRD. The results show that the powders are spherical, well-dispersed and good crystalline. The particle size is calculated to be about 68.5 nm. Using the powders calcined at 1 100 ℃ for 4 h as raw material, the highly transparent Eu:Lu₂O₃ ceramics were successfully fabricated by vacuum sintering at 1 650 ℃ for 30 h.The grain size is calculated to be about 46 μm, and in-line transmittance of the Eu:Lu₂O₃ ceramics reaches 66.3% at 611 nm. What's more, the absorption curve, the excitation spectrum, the emission spectrum and the X-ray excited emission spectrum of the Eu:Lu₂O₃ ceramics were studied. It can be observed that the absorption curve of Eu:Lu₂O₃ ceramics is consisted of the matrical absorption and active ion absorption. It can be seen from the photo-luminescence emission spectrum and X-ray excited emission spectrum of the Eu:Lu₂O₃ ceramics that an extremely strong peak is located at 611 nm, corresponding to the ⁵D₀→⁷F₂ transition of Eu³⁺. By comparison with the BGO crystal, the light output of the Eu:Lu₂O₃ ceramics is estimated to be about 85 000 ph/MeV. Eu:Lu₂O₃ ceramics have an excellent X-ray stopping power due to its high density and effective atomic number. It is indicated that Eu:Lu₂O₃ ceramics are a potential ceramic scintillator for the application of X-ray detection imaging combined with the characteristics of high light output.

Key words: Eu:Lu₂O₃, scintillation ceramics, transparent ceramics, vacuum sintering, photo-luminescence, emission spectrum, light output

中图分类号:

TQ174.75⁺8.23

王静, 葛烨, 解伟锋, 陈昊鸿, 李江. Eu:Lu₂O₃透明闪烁陶瓷的制备与性能[J]. 人工晶体学报, 2021, 50(3): 435-440.

WANG Jing, GE Ye, XIE Weifeng, CHEN Haohong, LI Jiang. Preparation and Properties of Transparent Eu:Lu₂O₃ Scintillation Ceramics[J]. JOURNAL OF SYNTHETIC CRYSTALS, 2021, 50(3): 435-440.

参考文献

[1] ZORENKO T, GORBENKO V, SAFRONOVA N, et al.Comparative study of the luminescent properties of oxide compounds under synchrotron radiation excitation: Lu₂O₃:Eu nanopowders, ceramics and films[J]. Journal of Luminescence, 2018, 199: 461-464.
[2] TROJAN-PIEGZA J, ZYCH E.Afterglow luminescence of Lu₂O₃:Eu ceramics synthesized at different atmospheres[J]. The Journal of Physical Chemistry C, 2010, 114(9): 4215-4220.
[3] DUCLOS S J, GRESKOVICH C D, LYONS R J, et al.Development of the hilight TM scintillator for computed tomography medical imaging[J]. Nuclear Inst & Methods in Physics Research A, 2003, 505(1/2): 68-71.
[4] ZHUANG L, ZHANG Z J, WANG Y, et al.Afterglow behavior, energy transfer and trap states in Lu₂ O₃:Eu single crystal scintillator[J]. ECS Journal of Solid State Science and Technology, 2018, 7(3): R17-R20.
[5] 胡亚华,郏曦莹,沈春娥,等.Lu₂O₃:Eu³+纳米荧光粉的制备和发光性能[J].嘉兴学院学报,2017,29(6):94-98.
HU Y H, JIA X Y, SHEN CHUN E, et al.Synthesis and luminescent properties of Lu₂O₃:Eu³+ nano-phosphor[J]. Journal of Jiaxing University, 2017, 29(6): 94-98(in Chinese).
[6] WANG Z F, ZHANG W P, YOU B G, et al.Effects of precipitant on microstructure and luminescent properties of Lu₂O₃:Eu³+ nanopowders and ceramics[J]. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 2008, 70(4): 835-839.
[7] CHEN Q W, SHI Y, AN L Q, et al.Fabrication and photoluminescence characteristics of Eu³+-doped Lu₂O₃ transparent ceramics[J]. Journal of the American Ceramic Society, 2006, 89(6): 2038-2042.
[8] LEMPICKI A, BRECHER C, SZUPRYCZYNSKI P, et al.A new Lutetia-based ceramic scintillator for X-ray imaging[J]. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, 2002, 488(3): 579-590.
[9] ZYCH E, TROJAN-PIEGZA J.Low-temperature luminescence of Lu₂O₃:Eu ceramics upon excitation with synchrotron radiation in the vicinity of band gap energy[J]. Chemistry of Materials, 2006, 18(8): 2194-2199.
[10] 赵曼. Eu³+掺杂Lu₂O₃纳米粉体发光与微结构研究[D].烟台:烟台大学,2014.
ZHAO M.Luminescence and microstructure of Eu³+ doped Lu₂O₃ nanopowders[D]. Yantai: Yantai University, 2014
(in Chinese).[11] 张琳,马畅,李晓东.(Gd_0.95-_xLu_xEu_0.05)₂O₃纳米粉体合成、透明陶瓷的制备及其荧光性能研究[J].人工晶体学报,2017,46(4):609-615+633.
11 ZHANG L, MA C, LI X D. Synthesis of (Gd_0.95-_xLu_xEu_0.05)₂O₃ nano-powders,fabrication and fluorescent properties of transparent ceramics[J]. Journal of Synthetic Crystals, 2017, 46(4): 609-615+633(in Chinese).
[12] 王林香,祝恒江,尹民.Lu₂O₃:Eu³+纳米粉末及透明陶瓷的制备及其发光性能[J].发光学报,2011,32(9):913-919.
WANG L X, ZHU H J, YIN M.Fabrication and luminescent properties of Eu³+-doped Lu₂O₃ nanopowders and transparent ceramics[J]. Chinese Journal of Luminescence, 2011, 32(9): 913-919(in Chinese).
[13] MENDELSON M I.Average grain size in polycrystalline ceramics[J]. Journal of the American Ceramic Society, 1969, 52(8): 443-446.
[14] BLASSE G, BRIL A.Photoluminescent efficiency of phosphors with electronic transitions in localized centers[J]. Journal of the Electrochemical Society, 1968, 115: 1067-75.
[15] SHI Y, CHEN Q W, SHI J L.Processing and scintillation properties of Eu³+ doped Lu₂O₃ transparent ceramics[J]. Optical Materials, 2009, 31(5): 729-733.

Eu:Lu₂O₃透明闪烁陶瓷的制备与性能

Preparation and Properties of Transparent Eu:Lu₂O₃ Scintillation Ceramics

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	张明荣. 非氟卤化物闪烁晶体的研究现状和发展趋势[J]. 人工晶体学报, 2020, 49(5): 753-770.
[2]	刘强;刘阳;韦家蓓;谢腾飞;李江. Yb:CaF2透明陶瓷的制备与性能研究[J]. 人工晶体学报, 2020, 49(5): 799-803.
[3]	孟猛;祁强;丁栋舟;赫崇君;施俊杰;任国浩. 新型闪烁晶体Gd3(Al,Ga)5O12:Ce3+的研究进展[J]. 人工晶体学报, 2019, 48(8): 1386-1394.
[4]	李春霄;郭扬武;李壮;姚吉勇;吴以成. 新型可实用化红外非线性光学晶体研究进展[J]. 人工晶体学报, 2019, 48(10): 1799-1813.
[5]	薛学刚;张芳;赵海泉. 掺钕钇铝石榴石(Nd∶YAG)激光棒激光诱导色心吸收对1064nm激光输出的影响[J]. 人工晶体学报, 2018, 47(5): 1083-1088.
[6]	张笑;梁森. Al2O3透明陶瓷烧结动力学分析研究[J]. 人工晶体学报, 2018, 47(12): 2555-2560.
[7]	张琳;马畅;李晓东. (Gd0.95-xLuxEu0.05)2O3纳米粉体合成、透明陶瓷的制备及其荧光性能研究[J]. 人工晶体学报, 2017, 46(4): 609-615.
[8]	冯建宇;董丽芳;魏领燕. 自组织等离子体光子晶体的光谱研究[J]. 人工晶体学报, 2016, 45(2): 328-332.
[9]	宋贵宏;孟雪;杨明川;胡方;乔瑞庆;陈立佳. Bi掺杂量对Mg-Si-Sn-Bi材料热电性能的影响[J]. 人工晶体学报, 2016, 45(12): 2790-2794.
[10]	宋立业;张振东;屈晓莉;姚冰双;陈华;韩彩芹;徐晓东;章健. Ce∶YAG透明陶瓷的制备和光学性能[J]. 人工晶体学报, 2016, 45(11): 2661-2665.
[11]	马雷;李强;曹江涛;吴超;张鹏瑞;马伟民. Eu2Zr2O7纳米晶体的制备及其烧结致密化[J]. 人工晶体学报, 2015, 44(8): 2158-2163.
[12]	李敏;王磊;黄平;郝虎在;田跃;崔彩娥. 掺杂Pb2对YAG∶ Ce3+,Pr3+黄色荧光粉中红光发射的影响[J]. 人工晶体学报, 2015, 44(4): 902-907.
[13]	刘佳男;马伟民;马雷;纪连永;吴影;王花蕾. Gd2Ti2O7/ZrO2(3Y)陶瓷制备及力学性能研究[J]. 人工晶体学报, 2015, 44(4): 1077-1083.
[14]	任国浩;陈晓峰;李焕英;吴云涛;张卫东;樊加荣. φ300mm碘化铯晶体发光非均匀性与生长界面的关系[J]. 人工晶体学报, 2015, 44(12): 3375-3378.
[15]	吴超;马志斌;高攀;黄宏伟;付秋明;王传新. MPCVD生长单晶金刚石及发射光谱分析[J]. 人工晶体学报, 2015, 44(10): 2734-2738.