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生油煤形成的环境制约
引用本文:孙永革,朱进,徐华,盛国英,傅家谟.生油煤形成的环境制约[J].地球化学,2002,31(1):8-14.
作者姓名:孙永革  朱进  徐华  盛国英  傅家谟
作者单位:1. 中国科学院广州地球化学研究所,广东广州,510640
2. 中国石油天然气股份有限公司吉林分公司采油二厂工艺技术研究所,吉林扶余,138002
3. 吉林石油集团有限责任公司井下作业工程公司工艺技术研究所,吉林扶余,138002
基金项目:中国科学院知识创新工程项目资助(KZCX2-110)
摘    要:通过对不同沉积环境下形成煤系源岩生烃潜力的对比研究,揭示出成煤古环境对煤成烃生成具有控制作用,并根据煤系源岩中赋存大分子有机质裂解产物分子的组成特征,提出了识别有利成烃煤相的分子有机地球化学方法——氢指数-苯酚/辛烷图解判识法。结果表明,沼泽环境覆水越深,煤中有机质富氢程度越高,生油气性能越好,裂解产物表现为正构烷烃和正构烯烃相对含量增加,以低本酚/辛烷值和高氢指数为特征;反之,沼泽环境覆水越浅,煤中有机质氢含量越低,裂解产物以高含量酚类化合物和芳香烃为特征,生油气性能关。由此表明,覆水型沼泽应是煤在烃,特别是煤成油生成的有利相带。

关 键 词:煤沉积相  裂解气相色谱  苯酚  生油煤  沉积环境  生烃潜力
文章编号:0379-1726(2002)01-0008-07

Environmental constraints on oil-generating coals
SUN Yong-ge,ZHU Jin,XU Hua,SHENG Guo ying,FU Jia mo.Environmental constraints on oil-generating coals[J].Geochimica,2002,31(1):8-14.
Authors:SUN Yong-ge  ZHU Jin  XU Hua  SHENG Guo ying  FU Jia mo
Affiliation:SUN Yong-ge1,ZHU Jin2,XU Hua3,SHENG Guo ying1,FU Jia mo1
Abstract:In potentially coal bearing petroliferous basins there is a need in petroleum exploration to predict ahead of drilling whether any coal bearing strata present are oil prone, and where the oil prone coal facies are. Theoretically, the evolution of depositional conditions within coal bearing sequence will result in the changes of biota community and affect the hydrocarbon generating potential of coal measures. In this study, coals from different depositional environments are organic geochemically compared, and beneficial coal facies for hydrocarbon generation have been identified using pyrolysis techniques in a sequence of stratigraphic framework. With the water table rising in swamps, organic matters from coal measures are more enriched in hydrogen. This can be attributed to an increased input of water column biota (e.g. algae) and the good preservation in the relatively anoxic conditions during peat deposition. The result suggests that coal seams deposited in interdistributary bay and lacustrine bog setting may possess the excellent potential to generate and release liquid hydrocarbons and may have general application to hydrocarbon exploration in areas thought to be sourced from coal bearing strata.
Keywords:coal facies  pyrolysis gas chromatography  phenol  oil  generating coal
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