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Orthogonal multiple click reactions in synthetic polymer chemistry
Authors:Umit Tunca
Affiliation:Department of Chemistry, Istanbul Technical University, , Maslak, Istanbul, 34469 Turkey
Abstract:This review highlights the concept of multiple click reaction strategy which is utilized for design and synthesis of well‐defined complex macromolecular structures as well as multifunctionalization of well‐defined polymers. This review examines the click combinations mainly from double to quadruple and additionally from the most frequently used to the least. The present review may also be regarded as an update for recent reviews dealing with specifically double and triple click reaction combinations in synthetic polymer chemistry. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2014 , 52, 3147–3165
Keywords:copper catalyzed azide‐alkyne cycloaddition (CuAAC)  Diels‐Alder  living polymerization  Michael thiol‐ene  nitroxide radical coupling (NRC)  nucleophilic substitution  orthogonal multifunctionalization  polymer‐polymer conjugation  post‐functionalization of polymer  strain promoted azide‐alkyne cycloaddition (SPAAC)  thiol‐ene  thiol‐yne
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