| 石墨烯改性有机硅手感剂的制备及其在皮革涂饰中的应用 |
| |
| 引用本文： | 姚庆达,王小卓,温会涛,杨义清,梁永贤,但卫华.石墨烯改性有机硅手感剂的制备及其在皮革涂饰中的应用[J].皮革与化工,2019(2):1-7,13. |
| |
| 作者姓名： | 姚庆达 王小卓 温会涛 杨义清 梁永贤 但卫华 |
| |
| 作者单位： | 兴业皮革科技股份有限公司;福建省皮革绿色设计与制造重点实验室;四川大学制革清洁技术国家工程实验室 |
| |
| 基金项目： | 泉州市科技计划项目(编号:2018G001) |
| |
| 摘 要： | 以有机硅为基质,改性氧化石墨烯粉体为填料,采用溶胶-凝胶法制备了石墨烯改性有机硅手感剂。采用单因素法优化了最佳工艺,应用于皮革涂饰并测试其物理机械性能。结果表明,最优制备工艺为:在110℃下反应4h,其中偶联剂KH550用量为4%,封端剂用量为0.4%,催化剂四甲基羟胺用量为0.09%,溶胶凝胶过程三乙胺用量为8%;石墨烯改性有机硅可将耐磨性提升至4级,耐干/湿擦提升至5级,耐曲折度符合基本要求,静态吸水性能降低至102.35%,相比普通有机硅手感剂均有所提高。
|
| 关 键 词： | 有机硅 石墨烯 合成 溶胶-凝胶 涂饰 |
Synthesis Process of Graphene Modified Silicone Feeling Agent and Its Application on Leather Finishing |
| |
| YAO Qing-da,WANG Xiao-zhuo,WEN Hui-tao,YANG Yi-qing,LIANG Yong-xian,DAN Wei-hua.Synthesis Process of Graphene Modified Silicone Feeling Agent and Its Application on Leather Finishing[J].Leather and Chemicals,2019(2):1-7,13. |
| |
| Authors: | YAO Qing-da WANG Xiao-zhuo WEN Hui-tao YANG Yi-qing LIANG Yong-xian DAN Wei-hua |
| |
| Affiliation: | (Xingye Leather Technology Co., Ltd., Jinjiang 362261, China;Fujian Key Laboratory of GreenDesign and Manufacture of Leather, Jinjiang 362271, China;National Engineering Laboratory forClean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China) |
| |
| Abstract: | YAO Qing-da;WANG Xiao-zhuo;WEN Hui-tao;YANG Yi-qing;LIANG Yong-xian;DAN Wei-hua(Xingye Leather Technology Co., Ltd., Jinjiang 362261, China;Fujian Key Laboratory of GreenDesign and Manufacture of Leather, Jinjiang 362271, China;National Engineering Laboratory forClean Technology of Leather Manufacture, Sichuan University, Chengdu 610065, China) |
| |
| Keywords: | silicone graphene synthesis sol-gel finishing |
| 本文献已被 CNKI 维普 等数据库收录！ |
|
