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TDLAS技术在线分析主流烟气气相物中CO的逐口释放特征
引用本文:杨柯,崔海滨,李慧,范黎,张龙,吴晓松,李志刚,王安,刘勇,计敏.TDLAS技术在线分析主流烟气气相物中CO的逐口释放特征[J].烟草科技,2015,48(10):36-42.
作者姓名:杨柯  崔海滨  李慧  范黎  张龙  吴晓松  李志刚  王安  刘勇  计敏
作者单位:1.1. 中国科学院合肥物质科学研究院, 合肥市蜀山区蜀山湖路350号 230031;2.2. 中国科学技术大学, 合肥市金寨路96号 230026;3.3. 北京市烟草质量监督检测站, 北京市北三环东路樱花西街10号 100029;4.4. 中国烟草总公司郑州烟草研究院中国烟草标准化研究中心, 郑州高新技术产业开发区枫杨街2号 450001
基金项目:国家自然科学基金青年基金项目"用激光诱导荧光和时间分辨红外傅里叶变换光谱研究N-亚硝胺光解动力学"(21203203)
摘    要:为准确分析卷烟主流烟气气相物中CO的逐口释放特征,改造了单孔道吸烟机,建立了一套基于可调谐二极管半导体激光吸收光谱(TDLAS)技术的卷烟主流烟气逐口在线分析系统。利用该系统,分析了管路和滤片夹持器残留对烟气逐口分析结果的影响,对4种不同类型卷烟中CO的逐口释放量进行了检测,探讨了其传递规律。结果表明:①清除残留前后CO的逐口传递规律明显不同;②在清除模式下,主流烟气中CO的释放量先降低后逐口增加,其中第2口的CO释放量最低。与传统检测方法相比,基于TDLAS技术的改造型单孔道吸烟机,能快速完成烟气中CO的检测,并有效避免烟气中其他成分的干扰。 

关 键 词:卷烟    主流烟气    CO    逐口    TDLAS技术    在线分析
收稿时间:2014-10-31

On-line Analysis of Puff-by-Puff Release Characteristics of CO in Gas Phase of Mainstream Cigarette Smoke by TDLAS Technology
YANG Ke,CUI Haibin,LI Hui,FAN Li,ZHANG Long,WU Xiaosong,LI Zhigang,WANG An,LIU Yong,JI Min.On-line Analysis of Puff-by-Puff Release Characteristics of CO in Gas Phase of Mainstream Cigarette Smoke by TDLAS Technology[J].Tobacco Science & Technology,2015,48(10):36-42.
Authors:YANG Ke  CUI Haibin  LI Hui  FAN Li  ZHANG Long  WU Xiaosong  LI Zhigang  WANG An  LIU Yong  JI Min
Affiliation:1.1. Institute of Physical Science, Chinese Academy of Sciences, Hefei 230031, China;2.2. University of Science and Technology of China, Hefei 230026, China;3.3. Beijing Tobacco Quality Supervision and Testing Station, Beijing 100029, China;4.4. China Tobacco Standardization Research Center, Zhengzhou 450001, China
Abstract:In order to accurately analyze the puff-by-puff release characteristics of CO in gas phase of mainstream cigarette smoke,an on-line puff-by-puff analysis system for cigarette smoke was established,which incorporated tunable diode laser absorption spectroscopy(TDLAS) technology with a modified single port smoking machine.The effects of cigarette smoke remained in pipeline and filter pad holder on the results of puff-by-puff analysis were analyzed with the system.The puff-by-puff release and transfer tendency of CO in mainstream smoke of cigarettes of four different types were analyzed.The results showed that:1) The puff-by-puff transfer tendency of CO obviously differed before and after flushing the residual smoke from pipeline and filter pad holder.2) Under the flushing mode,the puff-by-puff release of CO in mainstream smoke decreased at the first and second puffs then increased gradually with the minimum at the second puff.Comparing with traditional analysis methods,the modified single port smoking machine combined with TDLAS technology can complete the analysis of CO in cigarette smoke quickly and avoid the interference from other components in mainstream cigarette smoke effectively. 
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