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On the practicability of a new bio sorbent: Lasani sawdust and coconut coir for cleanup of oil spilled on water
Authors:Asher Benjamin Daniel  Erum Zahir  Muhammad Asif Asghar
Affiliation:1. Department of Chemistry, University of Karachi, Karachi, Sindh, Pakistan;2. Food and Feed Safety Laboratory, Food and Marine Resources Research Centre, PCSIR Laboratories Complex, Shahrah-e-Salimuzzaman Siddiqui, Karachi, Sindh, Pakistan
Abstract:In this article, two bio-sorbents have been selected: lasani sawdust (LS) (a new bio-based material) and coconut coir (CC) for the removal of used motor oil from the aqueous phase. The physical nature of the materials was characterized using Fourier Transform Infrared Spectroscopy and Constitutional Analysis of lignin and cellulose. The adsorption process was evaluated using various kinetic and adsorption models. The evaluated sorption capacities for coconut coir and lasani sawdust were 12.82?g g?1 and 0.36?g g?1, respectively. Maximum sorption of oil from the aqueous solution conveniently took place in 20?minutes. To ascribe statistically which model describes the adsorption phenomenon best, Root Mean Square Error (RMSE) and Average Relative Error (ARE) were used. The kinetics of the adsorption was best described by Pseudo-second order. Similarly, Langmuir isotherm model had the least value for the two error functions and a higher qmax value for coir than for lasani. It was concluded that the increased absorptive ability of coir over lasani was due to the difference in the composition of lignin and cellulose of the two materials.
Keywords:adsorption  bio-material  coconut coir  Lasani sawdust  used motor oil
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