| 自制新型毛细管柱用于乙醇羰基化催化剂的评价研究 |
| |
| 引用本文： | 寇登民,云希勤,赵维君,吕宪禹,关新新.自制新型毛细管柱用于乙醇羰基化催化剂的评价研究[J].石油化工,1993(4). |
| |
| 作者姓名： | 寇登民 云希勤 赵维君 吕宪禹 关新新 |
| |
| 作者单位： | 南开大学化学系，南开大学化学系，南开大学化学系，南开大学化学系，南开大学化学系 天津 300071，天津 300071，天津 300071，天津 300071，天津 300071 |
| |
| 摘 要： | 较详细地介绍了用硫酸钡层改性的新型玻璃毛细管色谱柱的制备方法,用自制的毛细管色谱柱成功地分离了C_1-C_2脂肪酸,并用此柱研究了乙醇羰基化合成丙酸与丙酸酯的均相与非均相催化剂的活性与选择性。
|
| 关 键 词： | 玻璃毛细管柱 硫酸钡微晶 游离脂肪酸 乙醇羰基化 |
Performance Appraisal of Catalysts for Ethanol—Carbonylation with New Self-made Capillary Column |
| |
| Kou Dengmin,Yun Xiqin,Zhao Weijun,Lu Xianyu and Guan Xinxin.Performance Appraisal of Catalysts for Ethanol—Carbonylation with New Self-made Capillary Column[J].Petrochemical Technology,1993(4). |
| |
| Authors: | Kou Dengmin Yun Xiqin Zhao Weijun Lu Xianyu and Guan Xinxin |
| |
| Abstract: | In this paper, a method for making a new model glass capillary column with a layer of barium sulphate is described. The column is suitable for analyzing C_1-C_4 fatty acids. The activity and selectivity of homogeneous and heterogeneous catalysts for synthesising propionic acid and its ester via ethanol-carbonylation have been investigated with the column. |
| |
| Keywords: | glass capillary column micro crystal of barium sulphate free fatty acid ethanol carbonylation |
| 本文献已被 CNKI 等数据库收录！ |
