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催化氧化技术处理橡胶干燥尾气VOCs侧线试验
引用本文:李晶蕊,李苗苗,王昆,江岩,谷丽芬.催化氧化技术处理橡胶干燥尾气VOCs侧线试验[J].石化技术与应用,2022,0(3):206-209.
作者姓名:李晶蕊  李苗苗  王昆  江岩  谷丽芬
作者单位:中国石油石油化工研究院 兰州化工研究中心,甘肃 兰州 730060
摘    要:采用纳米涂层技术和活性组分分散技术制备出挥发性有机物(VOCs)催化氧化催化剂。以10万t/a丁苯橡胶装置干燥尾气为研究对象,利用集成的侧线试验评价装置对该催化剂进行了催化性能、工况适应性、非甲烷总烃(NMHC)去除率的评价,以及长周期运行试验。结果表明:在干燥尾气体积空速为16 000 h-1,催化剂入口温度约为260 ℃,反应温度为260~290 ℃,NMHC质量浓度为1 400~1 700 mg/m3的条件下,在2 000 h长周期运行期间,NMHC去除率维持在97.0%以上。

关 键 词:VOCs  催化氧化催化剂  丁苯橡胶  干燥尾气  非甲烷总烃  侧线试验

Side-stream test on treatment of VOCs from rubber drying tail gasby catalytic oxidation technology
LI Jing-rui,LI Miao-miao,WANG Kun,JIANG Yan,GU Li-fen.Side-stream test on treatment of VOCs from rubber drying tail gasby catalytic oxidation technology[J].Petrochemical Technology & Application,2022,0(3):206-209.
Authors:LI Jing-rui  LI Miao-miao  WANG Kun  JIANG Yan  GU Li-fen
Affiliation:Lanzhou Petrochemical Research Center,Petrochemical Research Institute,PetroChina,Lanzhou 730060, China
Abstract:The volatile organic compounds(VOCs) catalytic oxidation catalysts were prepared by adopting nano-coating technology and active component dispersion technology. The catalytic performance, adaptability to operating conditions, non-methane hydrocarbon(NMHC) removal rate and long-period operation tests of the catalyst were evaluated by using the integrated side-stream test evaluation device with the dry tail gas of a 100 kt/a styrene-butadiene rubber unit. The results showed that the NMHC removal rate could be maintained above 97.0% during the 2 000 h long-period operation, under the conditions of dry tail gas volume space velocity of 16 000 h-1, catalyst inlet temperature of about 260 ℃, reaction temperature of 260-290 ℃, and NMHC concentration of 1 400-1 700 mg/m3 .
Keywords:VOCs  catalytic oxidation catalyst  styrene butadiene rubber  dry tail gas  non-methane hydrocarbon  side-stream test
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