氟硅油的结构表征

Fluorosilicone oil is polysiloxane with alkyl side chains containing fluorine, and because of its excellent thermal oxidation stability, cold flow property and cryogenic property, it can be widely used as a high temperature lubricant in the field of military aerospace industry. Two kinds of fluorosilicone oils, FSiO-a and FSiO-b, were synthesized by different pro- cessing means. FTICR MS was used to collect the information on composition and structure of the two polymers, respec- tively. The test results show that the two fluorosilicone oils have different contents of fluorine-containing chain segments (m/ n value), the maximum distribution of m/n value of FSiO-a oil ranges from 0.22 to 0.25, and that of FSiO-b oil ranges from 0.4 to 0.67. Difference in synthesis techniques makes this discrepancy and affects the quality and thermal stability of the fluoro- silicone oils.

Structure Characterization of Fluorosilicone Oils

Fluorosilicone oil is polysiloxane with alkyl side chains containing fluorine, and because of its excellent thermal oxidation stability, cold flow property and cryogenic property, it can be widely used as a high temperature lubricant in the field of military aerospace industry. Two kinds of fluorosilicone oils, FSiO-a and FSiO-b, were synthesized by different pro- cessing means. FTICR MS was used to collect the information on composition and structure of the two polymers, respec- tively. The test results show that the two fluorosilicone oils have different contents of fluorine-containing chain segments (m/ n value), the maximum distribution of m/n value of FSiO-a oil ranges from 0.22 to 0.25, and that of FSiO-b oil ranges from 0.4 to 0.67. Difference in synthesis techniques makes this discrepancy and affects the quality and thermal stability of the fluoro- silicone oils.