Epoxy-activated acrylic particulate polymer-supported Co–Fe–Ru–B catalyst to produce H2 from hydrolysis of NH3BH3 |
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| Affiliation: | 1. Faculty of Engineering and Architecture, Siirt University, 56100, Siirt, Turkey;2. Science Institute, Siirt University, Siirt, Turkey;3. School of Healthy, Siirt University, 56100 Siirt, Turkey;1. Faculty of Science and Letters, Department of Chemistry, Siirt University, Siirt, Turkey;2. Faculty of Engineering, Department of Chemical Engineering, Siirt University, Siirt, Turkey;1. Department of Chemical Engineering, Faculty of Engineering, Siirt University, Siirt, Turkey;2. Department of Chemical Engineering, Faculty of Engineering, Van Yüzüncü Y?l University, Van, Turkey;1. Siirt University, Faculty of Science and Literature, Department of Chemistry, Siirt, Turkey;2. Siirt University, Faculty of Engineering and Architecture, Department of Chemical Engineering, Siirt, Turkey;3. Siirt University, School of Health, Siirt, Turkey;1. College of Chemistry & Chemical Engineering, Taiyuan University of Technology, Taiyuan, 030024, PR China;2. Qing Chuang Ren He Ecological Engineering Technology Co. LTD, Taiyuan, 030032, PR China;3. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan, 030001, PR China |
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| Abstract: | Epoxy-activated acrylic particulate polymer, namely Eupergit CM, supported Co–Fe–Ru–B catalyst (EP/Co–Fe–Ru–B) for the first time was used to produce H2 from hydrolysis of NH3BH3. The EP/Co–Fe–Ru–B showed very effective performance in the production of H2 from the hydrolysis of NH3BH3. Various techniques such as XRD, SEM-EDS, ICP-OES, and TEM have been used to characterize these catalysts. The parameters on the hydrolysis reaction of NH3BH3 such as the effect of metal amount, the effect of Ru percentage, the effect of NH3BH3 concentration, the effect of NaOH concentration, the amount of catalyst, temperature, and catalyst durability were investigated in detail. Eupergit CM based polymer support and Ru particles have been found to be highly effective in H2 production reactions. The hydrogen production rate (HGR) of the EP/Co–Fe–Ru–B catalyst was found to be 36,978 mL/min/gcat, which was quite good compared to the values reported in the literature. In addition, the activation energy (Ea) of the polymer-supported Co–Fe–Ru–B catalyst was determined as 24.91 kJ/mol. |
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| Keywords: | Eupergit CM Support material Co–Fe–Ru–B Hydrogen |
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