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Thermodynamic performance assessment of boron based thermochemical water splitting cycle for renewable hydrogen production
Affiliation:1. Faculty of Engineering and Natural Sciences, Bahcesehir University, Ç?ra?an Caddesi No: 4 – 6 34353 Be?ikta?, Istanbul, Turkey;2. Faculty of Engineering and Applied Science, Ontario Tech University, 2000 Simcoe Street North, Oshawa, Ontario, L1G 0C5, Canada;1. Isparta University of Applied Sciences, Vocational School of Technical Science, Cunur West Campus, Isparta, 32200, Turkey;2. Isparta University of Applied Sciences, Faculty of Technology, Department of Mechatronics Engineering, Cunur West Campus, Isparta, 32200, Turkey;1. Department of Mechatronics Engineering, Faculty of Technology, Isparta University of Applied Sciences, 32200, Isparta, Turkey;2. Department of Mechanical Engineering, Faculty of Technology, Isparta University of Applied Sciences, 32200, Isparta, Turkey;1. INVAP SE, Avenida Comandante Luis Piedrabuena 4950, (8400) San Carlos de Bariloche, República Argentina;2. Complejo Tecnológico Pilcaniyeu, Comisión Nacional de Energía Atómica, Avenida Bustillo 9500, (8400) San Carlos de Bariloche, República Argentina;3. Consejo Nacional de Investigaciones Científicas y Técnicas (CONICET), Avenida Bustillo 9500, (8400) San Carlos de Bariloche, República Argentina;1. Faculty of Mechanical Engineering, Yildiz Technical University, Besiktas, Istanbul, Turkey;2. Faculty of Engineering and Applied Science, Ontario Tech. University, Oshawa, Ontario, Canada
Abstract:The present study is related with the thermodynamic performance assessment of renewable hydrogen production through Boron thermochemical water splitting cycle. Therefore, all step efficiencies and overall cycle efficiency are calculated based on complete reaction. Additionally, a parametric study is conducted to determine the effect of the reference environment temperature on the overall cycle efficiency. In this regard, exergy efficiencies, exergy destruction rates and also inlet and outlet exergy rates of the cycle are calculated and presented for various reference temperatures. The exergy efficiency of the cycle is calculated as 0.4393 based on complete reaction and occurs at 298 K. This study has shown that Boron thermochemical water splitting cycle has a great potential due to cycle performance. As a result, Boron based thermochemical water splitting cycle can help achieve better environment and sustainability due to high exergetic efficiency. By the way, economic and technical issues of the storage and transportation of the hydrogen can find a proper solution if the hydrogen production reaction of the Boron thermochemical water splitting cycle takes place on-board of a vehicle.
Keywords:Boron  Exergy  Hydrogen production  Thermochemical water splitting cycle
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