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Techno-economic-environmental evaluation of a combined tri and dry reforming of methane for methanol synthesis with a high efficiency CO2 utilization
Affiliation:1. Faculty of Caspian, College of Engineering, University of Tehran, Tehran, Iran;2. Department of Chemical Engineering, Shiraz University, Shiraz, Fars, Iran
Abstract:Production of methanol, as a green energy, from syngas is coming into focus. However, natural gas based methanol plants, which are used steam reforming of methane for syngas production, have a high CO2 emission resulting in the global warming. In this study, a novel process for methanol synthesis is proposed to reduce CO2 emission. In this regard, natural gas and flue gas are fed to a parallel-series system with tri and dry reforming of methane for syngas production with the optimized stoichiometric number. Then, the produced syngas is converted to methanol in a reactor. Finally, the produced methanol is purified by two distillation towers. The proposed method is compared to a referenced method in the view of technological, economic and environmental metrics. The techno-economic-environmental analysis of the processes reveals that not only the proposed method, as compared to the referenced one, increases CO2 conversion from 20.93% to 99.22%, but also it is more economical and environmentally friendly. In addition, the global warming potential of the proposed method is almost 60% lower than that for the referenced method due to the lower CO2 emission. Therefore, the proposed method can save above MUS$ 8 a year by CO2 capture.
Keywords:Methanol synthesis  Tri-reforming of methane  Dry reforming of methane  Techno-economic-environmental analysis
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