Dynamic modelling of a solar hydrogen system for power and ammonia production

A new configuration of solar energy-driven integrated system for ammonia synthesis and power generation is proposed in this study. A detailed dynamic analysis is conducted on the designed system to investigate its performance under different radiation intensities. The solar heliostat field is integrated to generate steam that is provided to the steam Rankine cycle for power generation. The significant amount of power produced is fed to the PEM electrolyser for hydrogen production after covering the system requirements. A pressure swing adsorption system is integrated with the system that separates nitrogen from the air. The produced hydrogen and nitrogen are employed to the cascaded ammonia production system to establish increased fractional conversions. Numerous parametric studies are conducted to investigate the significant parameters namely; incoming beam irradiance, power production using steam Rankine cycle, hydrogen and ammonia production and power production using TEGs and ORC. The maximum hydrogen and ammonia production flowrates are revealed in June for 17th hour as 5.85 mol/s and 1.38 mol/s and the maximum energetic and exergetic efficiencies are depicted by the month of November as 25.4% and 28.6% respectively. Moreover, the key findings using the comprehensive dynamic analysis are presented and discussed.