| AP/KP混合氧化剂的热分解特性研究 |
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| 引用本文： | 张炜,朱慧,薛金根.AP/KP混合氧化剂的热分解特性研究[J].含能材料,2000,8(1):9-12. |
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| 作者姓名： | 张炜 朱慧 薛金根 |
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| 作者单位： | 国防科技大学航天与材料工程学院!湖南长沙410073 |
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| 基金项目： | 国家自然科学基金!资助项目 (596 0 6 0 10 ) |
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| 摘 要： | 用ＤＳＣ方法研究了高氯酸铵（ＡＰ）、高氯酸钾（ＫＰ）、ＡＰ／ＫＰ（质量比分别为１／１和３／１）体系的热分解特性和一些过渡金属氧化物对上述体系热分解反应的催化作用。
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| 关 键 词： | 高氯酸铵 高氯酸钾 热分解 氧化剂 固体推进剂 |
| 收稿时间： | 1999/7/12 0:00:00 |
Study on Thermal Decomposition Characteristics of AP/KP Mixture |
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| ZHANG Wei,ZHU Hui and XUE Jin-gen.Study on Thermal Decomposition Characteristics of AP/KP Mixture[J].Chinese Journal of Energetic Materials,2000,8(1):9-12. |
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| Authors: | ZHANG Wei ZHU Hui and XUE Jin-gen |
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| Affiliation: | National University of Defense Technology, Changsha 410073, China;National University of Defense Technology, Changsha 410073, China;National University of Defense Technology, Changsha 410073, China |
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| Abstract: | The thermal decomposition characteristics of ammonium perchlorate (AP),potassium perchlorate (KP) and their mixtures of AP/KP 1/1 and 3/1 were respectively studied by DSC,and the influence of some transition metal oxides on the thermal decomposition of the said oxidizers were studied as well. The experimental results show that the DSC curves of AP/KP mixture are the overlap of those of AP and KP. The exothermic decomposition of AP in AP/KP mixture moves up the onset of KP decomposition at lower temperature. Both CoO/Co 2O 3 and CuO catalyze the thermal decomposition of AP,KP and their mixture. |
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| Keywords: | ammonium perchlorate (AP) potassium perchlorate (KP) thermal decomposition oxidizer catalyst |
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