| 烷氧基苯基取代硫代双烯镍配合物近红外吸收材料的制备和表征 |
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| 引用本文： | 周奋国,周涛,何兴权,刘大军,段潜.烷氧基苯基取代硫代双烯镍配合物近红外吸收材料的制备和表征[J].兵工学报,2009,30(9):1227-1231. |
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| 作者姓名： | 周奋国 周涛 何兴权 刘大军 段潜 |
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| 作者单位： | 长春理工大学,化学与环境工程学院,吉林,长春,130022;长春理工大学,化学与环境工程学院,吉林,长春,130022;长春理工大学,化学与环境工程学院,吉林,长春,130022;长春理工大学,化学与环境工程学院,吉林,长春,130022;长春理工大学,化学与环境工程学院,吉林,长春,130022 |
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| 基金项目： | 长春理工大学基金资助项目 |
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| 摘 要： | 本文合成了乙氧基苯基、丁氧基苯基、十六烷氧基苯基取代3种硫代双烯镍配合物，并用红外光谱表征其结构。紫外一可见一近红外光谱测试表明这3种化合物近红外区的最大吸收波长分别为927，929和932 nm且具有较大的摩尔消光系数。在此基础上，将3种配合物用注射成型方法掺入PMMA树脂中制备了近红外吸收复合材料，3种材料在900～1000 nm范围内光密度大于3.7，在可见光区平均透过率大于30%，是很好的近红外吸收材料。
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| 关 键 词： | 有机高分子材料 近红外吸收材料 硫代双烯镍配合物 注射成型 |
Preparation and Characterization of Near Infrared Absorbing Material Containing Dithiolene Metal Complexes Substituted by Alkoxyphenyl |
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| ZHOU Fen-guo,ZHOU Tao,HE Xing-quan,LIU Da-jun,DUAN Qian.Preparation and Characterization of Near Infrared Absorbing Material Containing Dithiolene Metal Complexes Substituted by Alkoxyphenyl[J].Acta Armamentarii,2009,30(9):1227-1231. |
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| Authors: | ZHOU Fen-guo ZHOU Tao HE Xing-quan LIU Da-jun DUAN Qian |
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| Affiliation: | School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, Jilin, China |
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| Abstract: | Three kinds of dithiolene metal complexes substituted by ethoxyphenyl,butoxyphenyl,hexadecyloxyphenyl were synthesized and their structures were characterized by means of Infrared Spectrum and ultraviolet-visible-near-infrared spectrum.Ultraviolet-visible-near-infrared spectrum testings of three compounds show that maximum absorption wavelengths in near infrared range are 927,929 and 932 nm with higher extinction coefficient respectively.Three kinds of near infrared absorbing PMMA material containing the ab... |
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| Keywords: | organic polymer material near infrared absorbing material dithiolene metal complexes injection moulding |
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