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STUDY ON PROPERTIES OF PULSE ELECTRODEPOSITED RE-Ni-W-P-SiC COMPOSITE COATINGS
作者姓名:Z.C.  Guo  X.Y.  Zhu  R.D.  Xu
作者单位:Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology, Kunming 650093, China
基金项目:Acknowledgements This work was supported by the National Excellent Doctoral Dissertation of China (No. 2005053).
摘    要:The effects of pulse frequency f and duty cycle r on the deposition rate, composition, morphology, and hardness of pulse electrodeposited RE (rare earth)-Ni-W-P-SiC composite coatings have been studied. The results indicate that pulse current can improve the deposition rate of RE-Ni-W-P-SiC composite coatings; W, P, and SiC contents in the coating decrease with the increase of pulse frequency and reach the lowest value at f = 33Hz, whereas the RE content in the composite coatings increases with the increase of pulse frequency. SiC content decreases with the increase of duty cycle, W content reaches the lowest value, and P content reaches the highest value at r = 0.4; pulse current and RE can lead to smaller size of the crystalline grains; however, the effects of different pulse frequency and duty cycle on the morphologies of RE-Ni-W-P-SiC composite coatings are not obvious. The hardness of RE-Ni-W-P-SiC composite coatings is the highest when the duty cycle is at 0.6 and 0.8 and pulse frequency is at 50Hz. At the same pulse frequency, the hardness of RE-Ni-W-P-SiC composite coatings at r= 0.8 is higher than that at r= 0.6.

关 键 词:RE-Ni-W-P-SiC复合镀层  性质  脉冲电沉积  脉冲频率
收稿时间:2006-04-10
修稿时间:2006-09-19

Study on Properties of Pulse Electrodeposited RE-Ni-W-P-SiC Composite Coatings
Z.C. Guo X.Y. Zhu R.D. Xu.STUDY ON PROPERTIES OF PULSE ELECTRODEPOSITED RE-Ni-W-P-SiC COMPOSITE COATINGS[J].Acta Metallurgica Sinica(English Letters),2007,20(2):111-116.
Authors:ZC Guo  XY Zhu  RD Xu
Affiliation:Faculty of Materials and Metallurgical Engineering, Kunming University of Science and Technology,Kunming 650093, China
Abstract:The effects of pulse frequency f and duty cycle r on the deposition rate, composition, morphology,and hardness of pulse electrodeposited RE (rare earth)-Ni-W-P-SiC composite coatings have been studied. The results indicate that pulse current can improve the deposition rate of RE-Ni-W-P-SiC composite coatings; W, P, and SiC contents in the coating decrease with the increase of pulse frequency and reach the lowest value at f =33Hz, whereas the RE content in the composite coatings increases with the increase of pulse frequency. SiC content decreases with the increase of duty cycle, W content reaches the lowest value, and P content reaches the highest value at r=0.4; pulse current and RE can lend to smaller size of the crystalline grains; however, the effects of different pulse frequency and duty cycle on the morphologies of RE-Ni-W-P-SiC composite coatings are not obvious. The hardness of RE-Ni-W-P-SiC composite coatings is the highest when the duty cycle is at 0.6 and 0.8 and pulse frequency is at 50Hz. At the same pulse frequency, the hardness of RE-Ni-W-P-SiC composite coatings at r=0.8 is higher than that at r=0.6.
Keywords:pulse frequency  duty cycle  electrodeposition  RE-Ni-W-P-SiC composite coating  COMPOSITE COATINGS  PULSE  PROPERTIES  different  however  pulse current  size  crystalline  decreases  contents  composite coatings  increase  reach  value  results  improve  rare  earth  hardness  morphology
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