| 二元金属熔体热力学性质按相图的分类 |
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| 引用本文： | 张鉴.二元金属熔体热力学性质按相图的分类[J].金属学报,1998,34(1):75-85. |
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| 作者姓名： | 张鉴 |
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| 作者单位： | 北京科技大学冶金学院!北京，100083 |
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| 摘 要： | 经过对二元金属熔体的热力学性质结合相图进行研究后，发现将其热力学性质按相图分为含化合物，含包晶体，饱和相，等六类制定计算模型时，前五类所得作用浓度符合质量作用定理，第六符合Ｒａｏｕｌｔ定律。
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| 关 键 词： | 金属熔体 相图 共存理论 作用浓度 金属热力学 |
| 收稿时间： | 1998-01-18 |
| 修稿时间： | 1998-01-18 |
CLASSIFICATION OF THERMODYNAMIC PROPERTIES OF BINARY METALLIC MELTS ACCORDING TO THEIR PHASE DIAGRAMS |
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| Zhang Jian.CLASSIFICATION OF THERMODYNAMIC PROPERTIES OF BINARY METALLIC MELTS ACCORDING TO THEIR PHASE DIAGRAMS[J].Acta Metallurgica Sinica,1998,34(1):75-85. |
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| Authors: | Zhang Jian |
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| Affiliation: | Zhang Jian (Institute of Metallurgy,University of Science and Technology Beijing,Beijing ) |
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| Abstract: | After combining investigation of thermodynamic properties of binary metallic melts with their phase diagrams, it has been found that when the calculating models of mass action concentrations of metallic melts are formulated according to their main phase diagrams (i.e.phase diagrams involving compound formation, involving peritectic, involving saturated phase,involving solid solution and involving eutectic), the calculated thermodynamic properties (mass action concentrations) will rigorously obey the mass action law, except for the continuous solid solution obeying Raoult's law. |
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| Keywords: | metallic melt phase diagram coexistence theory mass action concentration |
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