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Adsorption properties of Ag(Ⅰ), Au(Ⅲ), Pd(Ⅱ) and Pt(Ⅳ) ions on commercial 717 anion-exchange resin
引用本文:刘鹏,刘广峰,陈大林,程绍逸,唐宁.Adsorption properties of Ag(Ⅰ), Au(Ⅲ), Pd(Ⅱ) and Pt(Ⅳ) ions on commercial 717 anion-exchange resin[J].中国有色金属学会会刊,2009,19(6):1509-1513.
作者姓名:刘鹏  刘广峰  陈大林  程绍逸  唐宁
摘    要:

关 键 词:强碱性阴离子交换树脂  吸附性能  银(Ⅰ)  金(Ⅲ)  钯(Ⅱ)  商业  金属离子吸附  氯离子浓度
收稿时间:10 August 2009

Adsorption properties of Ag(I), Au(III), Pd(II) and Pt(IV) ions on commercial 717 anion-exchange resin
Peng LIU,Guang-feng LIU,Da-lin CHEN,Shao-yi CHENG,Ning TANG.Adsorption properties of Ag(I), Au(III), Pd(II) and Pt(IV) ions on commercial 717 anion-exchange resin[J].Transactions of Nonferrous Metals Society of China,2009,19(6):1509-1513.
Authors:Peng LIU  Guang-feng LIU  Da-lin CHEN  Shao-yi CHENG  Ning TANG
Affiliation:[1]Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province,College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China [2]Jinchuan Group Limited, Jinchang 737104, China
Abstract:The adsorption properties of the four precious metal ions (Ag(I), Au(II), Pd(III) and Pt(IV)) on the commercial Cl?-form 717 strongly basic anion-exchange resin were studied in detail. The effects of the contact time, solution acidity, and concentrations of Cl? and Pb2+ ions on the adsorption properties were studied by the batch method. Then, the column method was conducted under the optimized adsorption conditions (pH=3.0). The effects of the sample loading flow rate and the length-to-diameter ratios of the columns were investigated. The precious metal ions adsorbed could not be eluted completely after the saturated adsorption because the precious metal ions were found to be reduced to their metallic states during the adsorption process. So, it is recommended that the commercial Cl?-form 717 strongly basic anion-exchange resin should be decomposed directly to recovery the precious metals after the saturated adsorption.
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