| 溶胶-凝胶法制备铜锌锡硫材料的研究进展 |
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| 引用本文： | 韩贵,陆金花,王敏,李丹阳.溶胶-凝胶法制备铜锌锡硫材料的研究进展[J].材料导报,2017,31(1):10-17. |
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| 作者姓名： | 韩贵 陆金花 王敏 李丹阳 |
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| 作者单位： | 扬州大学化学化工学院,扬州,225002 |
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| 基金项目： | 科研启动金(5010/137010161)；扬州大学优势学科(081301) |
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| 摘 要： | 四元硫化物铜锌锡硫(CZTS)是一种新型薄膜太阳电池材料,具有锌黄锡矿结构,呈p型导电性,带隙约为1.5eV,光学吸收系数高于10~4cm~(-1),这些特性与太阳光谱相匹配。基于上述原因,CZTS薄膜是一种有望能低成本、可规模化开发利用的新型薄膜太阳电池材料。简要阐述了CZTS性质及其薄膜太阳能电池的器件结构,详细介绍了溶胶-凝胶方法制备CZTS薄膜及其相应器件效率的研究进展。最后,总结了此方法制备CZTS薄膜及其相关电池性能难以突破的关键技术问题,并提出了有效的改进措施,对CZTS薄膜太阳电池未来的研究进行了展望。
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| 关 键 词： | 铜锌锡硫 太阳能电池 溶胶-凝胶法 效率 性能 |
Materials of Cu2ZnSnS4 (CZTS) Prepared by Sol-Gel Method:A Review |
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| HAN Gui,LU Jinhu,WANG Min and LI Danyang.Materials of Cu2ZnSnS4 (CZTS) Prepared by Sol-Gel Method:A Review[J].Materials Review,2017,31(1):10-17. |
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| Authors: | HAN Gui LU Jinhu WANG Min and LI Danyang |
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| Affiliation: | College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002,College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002,College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002 and College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002 |
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| Abstract: | A quaternary chalcogenide-based compound Cu2 ZnSnS4 (CZTS)is a novel material for thin film solar cell,posses-sing kesterite structure,p-type conductivity,a band gap energy of about 1.5 eV and an absorption coefficient of higher than 104 cm-1 ,which match well with the solar spectrum.Based on the above reasons,CZTS thin film is expected to be a new material for thin film solar cell,which can lower the cost and be developed and utilized in large scale.The property and device structure of CZTS thin film solar cell are elaborated.In addition,the preparation of CZTS thin film by sol-gel method and the research progress in the corresponding device performance are also investigated in detail.Finally,the key strategies of this technique,as well as the effective improvement measure are pointed out,and the future study direction of CZTS thin film solar cells is proposed. |
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| Keywords: | Cu2ZnSnS4 solar cells sol-gel method efficiency performance |
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