| 新型咪唑啉酮衍生物的合成研究 |
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| 引用本文： | 王勇,冯菊红,巨修练.新型咪唑啉酮衍生物的合成研究[J].武汉化工学院学报,2010(3):37-39. |
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| 作者姓名： | 王勇 冯菊红 巨修练 |
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| 作者单位： | 武汉工程大学化工与制药学院湖北省新型反应器与绿色化学工艺重点实验室; |
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| 摘 要： | 由芳醛经Staudinger反应制备得到的膦亚胺，与芳杂环伯胺通过串联的Aza—wittig反应，得到八个未见文献报道的咪唑啉酮衍生物．目标化合物的结构经HRMS、^1HNMR确证；并发现碳二亚胺与芳杂环伯胺加成后再关环得到咪唑啉酮环时有一定的选择性．
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| 关 键 词： | 咪唑啉酮衍生物 合成 Aza—Wittig反应 |
Synthesis of novel 2-arylheterocyclicamino-3-aryl-5-arylidene-4H-imidazolin-4-one Derivatives |
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| WANG Yong,FENG Ju-hong,JU Xiu-lian.Synthesis of novel 2-arylheterocyclicamino-3-aryl-5-arylidene-4H-imidazolin-4-one Derivatives[J].Journal of Wuhan Institute of Chemical Technology,2010(3):37-39. |
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| Authors: | WANG Yong FENG Ju-hong JU Xiu-lian |
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| Affiliation: | WANG Yong,FENG Ju-hong,JU Xiu-lian(Hubei Key Laboratory of Novel Chemical Reactor , Green Chemical Technology,School of Chemical Engineering , Pharmacy,Wuhan Institute of Technology,Wuhan 430074,China) |
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| Abstract: | The standinger reaction of aromatic aldehyde provided iminophoshorane.The eight novel imidazolinone derivatives were synthesized by a tandem aza-Wittig reaction of iminophosphorane with heteroatom primary arylamine.The structures of the compounds were confirmed by HRMS and 1H NMR.The cyclizing reaction of imidazolinones has a certain selectivity. |
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| Keywords: | imidazolinone derivatives synthesis Aza-Wittig raection |
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