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二乙醇胺水溶液的表面张力研究
引用本文:付东,钟智坤,吕建燚,华雪莹.二乙醇胺水溶液的表面张力研究[J].华北电力大学学报,2010,37(6).
作者姓名:付东  钟智坤  吕建燚  华雪莹
基金项目:国家自然科学基金,中央高校基本科研业务费专项资金资助项目
摘    要:二乙醇胺(Diethanolamine,DEA)水溶液的表面张力是二氧化碳醇胺吸收工艺的基础数据。用ZBY-1全自动表面张力仪测定了25~82℃温度范围内,DEA水溶液的表面张力,并用经验公式对实验数据进行了关联,关联结果与实验值吻合良好。应用关联的公式,研究了表面熵和表面焓等热力学性质与温度和溶液浓度之间的关系。

关 键 词:二乙醇胺水溶液  二氧化碳  表面张力

Investigation of the surface tension for diethanolamine aqueous solution
FU Dong,ZHONG Zhi-kun,LU Jian-yi,HUA Xue-ying.Investigation of the surface tension for diethanolamine aqueous solution[J].Journal of North China Electric Power University,2010,37(6).
Authors:FU Dong  ZHONG Zhi-kun  LU Jian-yi  HUA Xue-ying
Abstract:Surface tensions of diethanolamine(DEA)-water mixtures are the basic data for the CO2 absorption technologies by alkanolamine aqueous solutions.The surface tensions of DEA-water mixtures from 25 to 82 ℃ were measured by using an automatic tension-meter.The experimental data were correlated with an empirical equation and the agreement was satisfactory.Using the correlated equations,thermodynamic properties like surface enthalpy and surface entropy were determined and their temperature and concentration dependence was obtained.
Keywords:diethanolamine-water mixtures  CO2  surface tension
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