| 1-氯甲基杂氮硅三环的合成 |
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| 引用本文： | 吴海英,陶春元.1-氯甲基杂氮硅三环的合成[J].南昌大学学报(工科版),2010,32(3):246-249. |
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| 作者姓名： | 吴海英 陶春元 |
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| 作者单位： | 1. 南昌大学化学系,江西,南昌,330031
2. 南昌大学化学系,江西,南昌,330031;九江学院化学化工学院,江西,九江,332005 |
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| 摘 要： | 以甲基三氯硅烷为原料,采用氯化、醇解和酯交换等反应,合成了1-氯甲基杂氮硅三环,并通过单因素实验方法对合成工艺条件进行了优化。在最佳条件下,1-氯甲基杂氮硅三环的总产率可达到54.5%,与文献报道的比较,具有产率高、能耗低等优点。并对反应过程中的副产物氯化氢气体进行了回收,减少了环境污染。
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| 关 键 词： | 甲基三氯硅烷 1-氯甲基杂氮硅三环 合成 工艺改进 |
The Synthesis of 1-chloromethylsilatrane |
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| WU Hai-ying,TAO Chun-yuan.The Synthesis of 1-chloromethylsilatrane[J].Journal of Nanchang University(Engineering & Technology Edition),2010,32(3):246-249. |
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| Authors: | WU Hai-ying TAO Chun-yuan |
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| Affiliation: | 1.Department of Chemistry,Nanchang University,Nanchang 330031,China;2.School of Chemistry and Chemical Engineering,Jiujiang College,Jiujiang 332005,China) |
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| Abstract: | 1-Chloromethylsilatrane was synthesized from methyltrichlorosilane by chlorination reaction,alcoholusis reaction and transesterification.The optimal technical conditions were determined by single-factor experimental method.Under the optimal conditions,the product yield of 1-chloromethylsilatrane reached 54.5%.Compared to those reported in literature,this technique has certain advantages,such as higher yield of 1-chloromethylsilatrane more simple process and lower energy consumption.The by-product producted from the reaction was recovered,which reduces environmental pollution. |
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| Keywords: | methyltrichlorosilane 1-chloromethylsilatrane synthesis process optimization |
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