| 碱体系中系列羟基苯基卟啉红外光谱和拉曼光谱性质研究 |
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| 引用本文： | 石莹岩,郭红卫.碱体系中系列羟基苯基卟啉红外光谱和拉曼光谱性质研究[J].吉林建筑工程学院学报,2010,27(6):81-84. |
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| 作者姓名： | 石莹岩 郭红卫 |
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| 作者单位： | [1]吉林建筑工程学院基础科学部,长春130118 [2]吉林大学化学学院,长春130021 [3]中国科学院应用化学研究所,长春130021 |
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| 基金项目： | 吉林省教育厅十一五科学技术项目，吉林建筑工程学院博士科研启动基金，吉林建筑工程学院青年科技发展基金 |
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| 摘 要： | 本文继续深入研究该体系中相关物质的红外光谱和拉曼光谱的性质.论文结果说明,在碱体系中,NaOH只与羟基苯基卟啉周边meso-位的羟基反应形成盐,这个性质与紫外可见光谱性质是一致的.同时这一结果也为研究卟啉与金属的相互作用提供了有益的理论支持.
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| 关 键 词： | 羟基苯基卟啉 碱 红外光谱 拉曼光谱 |
The IR Spectrum and Raman Spectroscopy Characterization of a Series of Hydroxyphenyl Porphyrins in the Alkali |
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| SHI Ying-yan,GUO Hong-wei.The IR Spectrum and Raman Spectroscopy Characterization of a Series of Hydroxyphenyl Porphyrins in the Alkali[J].Journal of Jilin Architectural and Civil Engineering,2010,27(6):81-84. |
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| Authors: | SHI Ying-yan GUO Hong-wei |
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| Affiliation: | 1：Department of Basic Sciences,Jilin Institute of Architecture and Civil Engineering,Changchun,China 130118; 2：Chemistry College,Jilin University,Changchun,China 130021; 3：Changchun Institute of Applied Chemistry Chinese Academy of Sciences,Changchun,China 130021) |
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| Abstract: | In DMF＋H2O mixture,we have studied the UV-visible spectrum changed dramatically during the hydroxyphenyl porphyrin reacted with NaOH.In this paper,we continue to discuss the IR spectrum and Raman spectroscopy of a series hydroxyphenyl porphyrin using sodium hydroxide titrated.Raman and infrared spectra show that in the base system,the alkali reacted with hydroxyphenyl on the surrounding porphyrin forming the salt,which consistent with the UV-visible spectrum.This result we have studied provides a theoretical guidance for the reaction between porphyrin and metal ion. |
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| Keywords: | hydroxyphenyl porphyrin alkali IR spectrum Raman spectroscopy |
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