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土壤对苯系物的吸附行为研究
引用本文:童玲,郑西来,李梅,胡志峰.土壤对苯系物的吸附行为研究[J].西安建筑科技大学学报(自然科学版),2007,39(6):856-861.
作者姓名:童玲  郑西来  李梅  胡志峰
作者单位:中国海洋大学海洋环境与生态教育部重点实验室,山东,青岛,266100
基金项目:国家自然科学基金;高等学校博士学科点专项科研项目;山东省水利厅专项资金资助项目
摘    要:为保护石化工业区重要的地下水源地,选取淄博市代表性土壤,采用静态吸附平衡法,研究了苯系物在天然土壤中的吸附行为.以吸附理论为基础,考察了混合苯系物在土壤中的吸附动力学过程、吸附-解吸等温线和不同因素对吸附的影响.结果表明,Henry直线型吸附模型较好地拟合了土壤中苯系物的吸附-解吸等温线,解吸过程存在明显滞后现象,且有机质仍然是影响吸附的主要因素.由于土壤体系自身具有较强的缓冲能力,pH值和盐度对吸附过程的影响不显著.另外,温度升高,土壤对混合苯系物的吸附量增大,这可能与苯系物溶解度随温度变化的规律有关.

关 键 词:苯系物  土壤  吸附-解吸
文章编号:1006-7930(2007)06-0856-06
收稿时间:2007-07-03
修稿时间:2007年7月3日

Adsorptive behavior of BTEX Mixtures on soils
TONG Ling,ZHENG Xi-lai,LI Mei,HU Zhi-feng.Adsorptive behavior of BTEX Mixtures on soils[J].Journal of Xi'an University of Architecture & Technology,2007,39(6):856-861.
Authors:TONG Ling  ZHENG Xi-lai  LI Mei  HU Zhi-feng
Abstract:In order to protect the important groundwater resources in petrochemical industrial area in Northern China,the experiments took the typical soils of Zibo city as samples and studied the adsorption/desorption process of BTEX mixtures on soils.The laboratory testing programs were carried out to investigate the effects of organic matters,pH value,salt content and temperature on the adsorption/desorption process of BTEX mixtures on soils.The results indicated that adsorption isotherm of BTEX mixtures on soils was linear and fitted well to the Henry model.Adorption-desorption hystersis was also found.In addition,organic matters continue to be the main factor in the adsorption process,but pH value and salt content had no obvious influence.Furthermore,the solubility of BTEX mixtures varying with temperature may be a critical factor for the remarkable influence of temperature in the process.
Keywords:BTEX mixtures  soils  adsorption-desorption
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