Thin film yttria-stabilized zirconia electrolyte for intermediate-temperature solid oxide fuel cells (IT-SOFCs) by chemical solution deposition |
| |
Authors: | Eun-Ok Oh Chin-Myung Whang Yu-Ri Lee Jong-Heun Lee Kyung Joong Yoon Byung-Kook Kim Ji-Won Son Jong-Ho Lee Hae-Weon Lee |
| |
Affiliation: | 1. School of Materials Science and Engineering, and Institute of Advanced Materials, Inha University, 253 Youghyun, Incheon 402-751, South Korea;2. Materials Science and Engineering, Korea University, Anam, Seongbuk, Seoul 136-701, South Korea;3. High Temperature Energy Materials Center, Korea Institute of Science and, Technology, 39-1 Hawolgok, Seongbuk, Seoul 136-791, South Korea;1. Department of Energy, CIEMAT, Av. Complutense 40, Madrid 28040, Spain;2. Institute of Catalysis and Petroleochemistry, CSIC, Madrid 28049, Spain;1. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China;2. Research Center of Graphene Applications, Beijing Institute of Aeronautical Materials, Beijing 100095, China;3. School of Engineering and Technology, China University of Geoscience, Beijing 100083, China |
| |
Abstract: | A 500 nm thick thin film YSZ (yttria-stabilized zirconia) electrolyte was successfully fabricated on a conventionally processed anode substrate by spin coating of chemical solution containing slow-sintering YSZ nanoparticles with the particle size of 20 nm and subsequent sintering at 1100 °C. Incorporation of YSZ nanoparticles was effective for suppressing the differential densification of ultrafine precursor powder by mitigating the prevailing bi-axial constraining stress of the rigid substrate with numerous local multi-axial stress fields around them. In particular, adding 5 vol% YSZ nanoparticles resulted in a dense and uniform thin film electrolyte with narrow grain size distribution, and fine residual pores in isolated state. The thin film YSZ electrolyte placed on a rigid anode substrate with the GDC (gadolinia-doped ceria) and LSC (La0.6Sr0.4CoO3?δ) layers deposited by PLD (pulsed laser deposition) processes revealed that it had fairly good gas tightness relevant to a SOFC (solid oxide fuel cell) electrolyte and maintained its structural integrity during fabrication and operation processes. In fact, the open circuit voltage was 1.07 V and maximum power density was 425 mW/cm2 at 600 °C, which demonstrates that the chemical solution route can be a viable means for reducing electrolyte thickness for low- to intermediate-temperature SOFCs. |
| |
Keywords: | |
本文献已被 ScienceDirect 等数据库收录! |
|