| 成核剂对PET结晶行为及形态结构的影响 |
| |
| 引用本文： | 冯凯,胡小明,曹祥薇,郭正波.成核剂对PET结晶行为及形态结构的影响[J].塑料助剂,2011(1):40-44. |
| |
| 作者姓名： | 冯凯 胡小明 曹祥薇 郭正波 |
| |
| 作者单位： | 1. 湖北工业大学化学与环境工程学院,武汉,430068
2. 广州和氏璧化工材料有限公司,武汉,430032 |
| |
| 摘 要： | 系统地研究了四种成核剂:N-A、液晶VectraA950、滑石粉(Talc)、乙撑双硬脂酰胺(EBS)对聚对苯二甲酸乙二醇酯(PET)的结晶行为的影响。采用差式扫描量热仪(DSC)研究了PET/成核剂复合体系的非等温结晶行为,通过小角激光散射(Sals)、X衍射(XRD)对PET/成核剂复合体系的晶体尺寸和晶体结构进行了研究。结果表明,引入成核剂后,PET的结晶行为有较大改善,结晶峰向高温方向移动,且变尖锐,结晶尺寸变小,结晶度提高,除EBS外,均使PET结晶诱导时间减少。在这四种成核剂中,离子聚合物成核剂N-A成核效果最好。
|
| 关 键 词： | 聚对苯二甲酸乙二醇酯 成核剂 结晶行为 晶体结构 |
The Effects of Nucleating Agents on the Crystallization Behaviors and Morphology of PET |
| |
| Feng Kai,Hu Xiaoming,Cao Xiangwei,Guo Zhengbo.The Effects of Nucleating Agents on the Crystallization Behaviors and Morphology of PET[J].Plastic Additives,2011(1):40-44. |
| |
| Authors: | Feng Kai Hu Xiaoming Cao Xiangwei Guo Zhengbo |
| |
| Affiliation: | Feng Kai1 Hu Xiaoming2 Cao Xiangwei1 Guo Zhengbo1 (1.College of Chemistry and Environment,HuBei Universtry of Technology,Wuhan,430068,2.Guangzhou HERSBIT Materials Company,430032) |
| |
| Abstract: | In this paper, the effects of four kinds of nucleating agents: N-A, LCD VectraA950, talc and EBS, on the crystallization behavior were systematic studied. The non-isothermal crystallization behaviors of PET/nucleating agent blends by Differential Scanning Calorimetry (DSC), the crystal size and crystallization structure of PET/nucleating agent composites were investigated by Small Angle Laser Scattering (Sals) and X Ray Diffraction (XRD), respectively. The study indicated that added with nucleation agents, ... |
| |
| Keywords: | ethylene bis-stearamide nucleating agent crystallization behavior crystal structure |
| 本文献已被 CNKI 维普 万方数据 等数据库收录！ |
|
