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| 马来海松酸烯丙酯的合成、表征及性能分析 | |
| 引用本文： | 王基夫,常利丽,俞娟,南静娅,刘玉鹏,林明涛,王春鹏,刘美虹,蔡智慧,储富祥.马来海松酸烯丙酯的合成、表征及性能分析[J].生物质化学工程,2012,46(3):1-4. |
| 作者姓名： | 王基夫 常利丽 俞娟 南静娅 刘玉鹏 林明涛 王春鹏 刘美虹 蔡智慧 储富祥 |
| 作者单位： | 1. 中国林业科学研究院林产化学工业研究所；生物质化学利用国家工程实验室；国家林业局林产化学工程重点开放性实验室；江苏省生物质能源与材料重点实验室,江苏南京210042／中国林业科学研究院林业新技术研究所,北京100091 2. 南京林业大学化学工程学院,江苏南京,210037 3. 中国林业科学研究院林产化学工业研究所；生物质化学利用国家工程实验室；国家林业局林产化学工程重点开放性实验室；江苏省生物质能源与材料重点实验室,江苏南京210042 |
| 基金项目： | 林业公益性行业科研专项，中国林科院林业新技术研究所基本科研业务费专项资金 |
| 摘 要： | 以马来海松酸为原料,先合成马来海松酸酰氯,然后和烯丙醇进行酯化反应,合成马来海松酸烯丙酯,得率为 70 %,质量分数 99.2 %。采用FT-IR、GC-MS、 13C NMR 和DSC对其结构和性能进行分析。研究结果表明,马来海松酸烯丙酯是一种含有酸酐基团的烯丙基类单体,加热到熔点以上可以发生聚合反应,均聚物玻璃化转变温度约为 98 ℃,可作为环氧树脂和不饱和树脂前聚体。 |
| 关 键 词： | 马来海松酸 单体 自由基聚合 马来海松酸烯丙酯 |
Synthesis, Characterization and Properties of AUyl Ester of Maleopimaric Acid |
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| WANG Ji-fu,CHANG LI-li,YU Juan,NAN Jing-ya,LIU Yu-peng,LIN Ming-tao,WANG Chun-peng,LIU Mei-hong,CAI Zhi-hui,CHU Fu-xiang.Synthesis, Characterization and Properties of AUyl Ester of Maleopimaric Acid[J].Biomass Chemical Engineering,2012,46(3):1-4. | |
| Authors: | WANG Ji-fu CHANG LI-li YU Juan NAN Jing-ya LIU Yu-peng LIN Ming-tao WANG Chun-peng LIU Mei-hong CAI Zhi-hui CHU Fu-xiang |
| Affiliation: | 1,2(1.Institute of Chemical Industry of Forestry Products,CAF;National Engineering Lab.for Biomass Chemical Utilization; Key and Open Lab.of Forest Chemical Engineering,SFA;Key Lab.of Biomass Energy and Material,Jiangsu Province, Nanjing 210042,China;2.Institute of New Technology of Forestry,CAF,Beijing 100091,China; 3.College of Chemical Engineering,Nanjing Forest University,Nanjing 210027,China) |
| Abstract: | Allyl ester of maleopimaric acid(MA-BXC) with a purity of 99.2% was prepared by the reaction between maleopimaric acyl chloride and allyl alcohol with the yields near to 70%.The structure and properties of MA-BXC was evaluated by FT-IR spectroscopy,GC-MS,13 C NMR spectroscopy and DSC.The results indicated that MA-BXC was an allyl monomer with anhydride group and can be polymerized while being heated to above the melting point.The glass transition temperature of MA-BXC′s homopolymer is about 98℃.These results showed that MA-BXC had a great potential to be used as a precursor of unsaturated resin and epoxy resin. |
| Keywords: | maleopimaric acid monomer free radical polymerization allyl ester of maleopimaric acid |
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