胜利褐煤快速热解特性

为考察热解温度对热解产物品质及挥发分残留的影响,在10 kg/h自制褐煤快速热解提质试验设备上,以胜利褐煤为试验原料,考察了400~900℃热解提质温度对热解产物产率、气体产物组成、半焦微观结构以及残余挥发分的影响。结果表明,随着热解温度的升高,半焦产率逐渐降低,气体产率升高,焦油的产率先升高后降低,700℃时焦油产率最大;热解气体中的CO_2随着热解温度的升高逐渐降低,H_2和CO含量随着热解温度的升高而增加;随着热解温度的升高,挥发分不断释放导致半焦含氧官能团以及高活性的小的缩合芳环减少;热解温度≥700℃,半焦残留的挥发分较低,固定碳较多,基本满足电石用焦的要求。

Characteristics of rapid pyrolysis of Shengli brown coal

To investigate the influence of pyrolysis temperature on pyrolysis product grade and residual volatile,the effect of temperature from 400 ℃ to 900 ℃ on the yield of pyrolysis product,gas composition,micro-structure of char and the residual volatiles were examined in a 10 kg/h self-made experimental equipment for rapid pyrolysis of brown coal using Shengli brown coal as a raw material.Results show that char yield decreases and gas yield increases gradually with temperature.The tar yield increases firstly and then decreases,and reaches a maximum at 700 ℃.The CO2 in pyrolysis gas decreases slowly while H2 and CO increases with temperature.Besides,with rising of temperature,the volatiles release continuously,which leads to a reduction of O-containing functional groups as well as the highly active small aromatic ring matters.Less residual volatiles and more fixed carbon are left in char when it is higher than 700 ℃,which can meet the requirement of calcium carbide coke.