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Critical risk points of nanofiltration and reverse osmosis processes in water recycling applications
Affiliation:1. Faculty of Engineering, University of Technology Sydney (UTS), P.O. Box 123, Broadway, NSW 2007, Australia;2. King Abdullah University of Science and Technology (KAUST), Water Desalination and Reuse Center (WDRC), Biological and Environmental Science & Engineering (BESE), Thuwal 23955-6900, Saudi Arabia;1. Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, PR China;2. Department of Civil Engineering, The University of Hong Kong, Pokfulam HW619B, Hong Kong, PR China;1. CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Membrane Technology Department, Institute of Functional Interfaces (IFG-MT), Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany;1. Interdisciplinary Graduate School, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;2. Residues and Resource Reclamation Centre (R3C), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore;3. Singapore Membrane Technology Centre (SMTC), Nanyang Environment and Water Research Institute, Nanyang Technological University, 1 Cleantech Loop, CleanTech One, Singapore 637141, Singapore;4. School of Chemical and Biomolecular Engineering, The University of Sydney, Sydney, Australia;5. School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;6. Division of Environmental and Water Resources, School of Civil and Environmental Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore;7. Department of Civil Engineering, Monash University, VIC 3800, Australia;8. Department of Civil Engineering, University of Hong Kong, Pokfulam, Hong Kong
Abstract:NF/RO membrane filtration processes have been recognized as an important technology to facilitate water recycling. Those processes are well-proven technologies, which can be used to remove a wide range of contaminants including trace contaminants that are of particular concern in water recycling. However, risk implications in association with brine or concentrate and membrane cleaning wastewater disposal have to date not been adequately understood. This study examines the adsorption and release process of several endocrine-disrupting chemicals (EDCs) during NF/RO filtration processes. Results reported here indicate that the membrane can serve as a large reservoir for EDCs and their release may be possible during membrane cleaning or erratic pH variation during operation. Treatment of membrane cleaning solution should be carefully considered when EDCs are amongst the target contaminants in NF/RO membrane filtration.
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