| 含硅西佛碱的合成 |
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| 引用本文： | 陆军,高新蕾.含硅西佛碱的合成[J].化学与生物工程,2005,22(2):45-46. |
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| 作者姓名： | 陆军 高新蕾 |
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| 作者单位： | 武汉工业学院教务处,湖北,武汉,430023;武汉工业学院教务处,湖北,武汉,430023 |
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| 摘 要： | 介绍了含硅西佛碱的合成，制备了8种含硅西佛碱。用^1H—NMR、^13C—NMR对合成的化合物进行表征。目标分子为Ph—CH=NCH2CH2CH2Si(OCH2CH3)3；Ph—CH=NCH2CH2NHCH2CH2CH2Si(OCH2CH3)3；o-HO-Ph—CH—NCH2CH2CH2Si(OCH2CH3)3；o-HO-Ph—CH=NCH2CH2NHCH2CH2CH2Si(OCH2CH3)3；2，4-Cl-Ph—CH=NCH2CH2CH2Si(OCH2CH3)3；2，4-Cl-Ph-CH=NCH2CH2NHCH2CH2CH2Si(OCH2CH3)3；p-NO2-Ph-CH=NCH2CH2CH2Si(OCH2CH3)3；P-NO2-Ph-CH=NCH2CH2NHCH2CH2CH2Si(OCH2CH3)3。
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| 关 键 词： | 含硅西佛碱 合成 |
| 文章编号： | 1672-5425(2005)01-0045-02 |
| 修稿时间： | 2004年10月27 |
The Synthesis of Silyl-Schiff Base |
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| LU Jun,GAO Xin-lei.The Synthesis of Silyl-Schiff Base[J].Chemistry & Bioengineering,2005,22(2):45-46. |
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| Authors: | LU Jun GAO Xin-lei |
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| Abstract: | This thesis reported the synthesis of eight new silyl-Schiff base through the reactions of aldehyde and amine.The compounds were identified by ~1H-NMR,~(13)C-NMR. Target compounds:Ph-CH=NCH_2CH_2CH_2Si(OCH_2CH_3)_3;Ph-CH=NCH_2CH_2NHCH_2CH_2CH_2Si(OCH_2CH_3)_3;o-HO-Ph-CH=NCH_2CH_2CH_2Si(OCH_2CH_3)_3;o-HO-Ph-CH=NCH_2CH_2NHCH_2CH_2CH_2Si(OCH_2CH_3)_3;2,4-Cl-Ph-CH=NCH_2CH_2CH_2Si(OCH_2CH_3)_3;2,4-Cl-Ph-CH=NCH_2CH_2NHCH_2CH_2CH_2Si(OCH_2CH_3)_3;p-NO_2-Ph-CH=NCH_2CH_2CH_2Si(OCH_2CH_3)_3;p-NO_2-Ph-CH=NCH_2CH_2NHCH_2CH_2CH_2Si(OCH_2CH_3)_3. |
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| Keywords: | silyl-Schiff base synthesis |
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