基于不同阳离子条件下硅酸盐水泥氯离子固化性能研究

研究了不同阳离子对硅酸盐水泥氯离子固化性能的影响，采用水溶法测定了净浆试样中自由氯离子的含量并计算出其氯离子固化率，对试样进行了XRD物相分析以及其水溶液的pH值测定。研究得出，随水化龄期的增长，水泥浆体的氯离子固化率增大，其6 h、12 h、1 d和3 d的氯离子固化率分别达到其28 d的50％、70％、80％和90％以上，F盐的生成及氯离子的固化主要发生在水化早期，水化后期氯离子固化主要来自C-S-H凝胶，其氯离子固化量较小。不同阳离子导致了水泥浆体中F盐生成量的差异，其影响硅酸盐水泥氯离子固化率由大到小排列为Ca2＋＞Mg2＋＞K＋＞Na＋，其与对pH值的影响成负相关系，Ca2＋和Mg2＋降低了水泥浆体的pH值，有助于氯离子的固化；K＋和Na＋提高了水泥浆体的pH值而降低了氯离子固化。氯离子浓度一定时，Na＋浓度的增加对水泥浆体中F盐的生成量及氯离子固化率影响不大；而Mg2＋浓度的增加提高了水泥浆体中F盐的生成量及氯离子固化率。

Chloride Binding Capacity of Portland Cement under the Condition of Different Cations

Effect of different cations on the chloride ion binding capability of Portland cement was studied.The chloride ion binding rate of cement pastes were obtained through free chloride ions concentrations testing and analyzed by XRD and pH testing techniques .The results show that the chloride ion binding rate of cement pastes reaches 50, 70, 80 and 90 percent respectively of 28 d at the age of 6 h, 12 h, 1 d and 3 d.The formation of Friedel's salt and binding of chloride ions take place in the early stage of hydration while the chloride binding capability is mainly C-S-H gel dependent and smaller at the later stage ..Different cations cause the difference of amount of formation of Friedel 's salt in cement pastes, with the chloride ion binding capability of Ca 2+>Mg2+>K+>Na+which is negatively related to its influence on the pH value .Na +and K +lead to the rise of the pH value and reduce the chloride ion binding capability, while Ca2+and Mg2+are just the opposite.The increase of the Mg2+concentration promotes the formation of Friedel's salt and chloride ion binding capability , while Na + concentration shows little effect .